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Heterogeneity in Epoxy Nanocomposites Initiates Crazing: Significant Improvements in Fatigue Resistance and Toughening

Wei Zhang、Iti Srivastava、Yuefeng Zhu 等 5 位作者2009-03-19Small

Amido-amine-functionalized multiwalled carbon-nanotube fillers fundamentally alter the fracture and fatigue behavior of a thermosetting epoxy by initiating crazing in the material (see image). The crazing results in over an order of magnitude reduction in fatigue crack growth rates and significant improvements in frac…

Mechanical Behavior of CompositesPolymer composites and self-healingEpoxy Resin Curing Processes

Nuclear Magnetism and Electronic Order inC13Nanotubes

Bernd Braunecker、Pascal Simon、Daniel Loss2009-03-19Physical Review Letters

Single wall carbon nanotubes grown entirely from 13C form an ideal system to study the effect of electron interaction on nuclear magnetism in one dimension. If the electrons are in the metallic, Luttinger liquid regime, we show that even a very weak hyperfine coupling to the 13C nuclear spins has a striking effect: Th…

Quantum and electron transport phenomenaDiamond and Carbon-based Materials ResearchChemical and Physical Properties of Materials

Uniform Ferrite-Loaded Open Waveguide Structure With CRLH Response and Its Application to a Novel Backfire-to-Endfire Leaky-Wave Antenna

Toshiro Kodera、Christophe Caloz2009-03-19IEEE Transactions on Microwave Theory and Techniques

A uniform ferrite-loaded open waveguide structure with composite right/left-handed (CRLH) response and its application to a novel backfire-to-endfire leaky-wave antenna are presented. The structure consists of a ferrite-filled rectangular waveguide open to free space at one of its small sides and biased perpendicularl…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Prediction of Remarkably Large Second-Order Nonlinear Optical Properties of Organoimido-Substituted Hexamolybdates

Muhammad Ramzan Saeed Ashraf Janjua、Chun-Guan Liu、Wei Guan 等 7 位作者2009-03-19The Journal of Physical Chemistry A

The dipole polarizabilities, dipole moments, density of states, and second-order nonlinear optical (NLO) properties of organoimido derivatives of hexamolybdates have been investigated by using time-dependent density functional response theory. This class of organic-inorganic hybrid compounds possesses remarkably large…

Porphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and ApplicationsOrganometallic Compounds Synthesis and Characterization

Possible origin of ferromagnetism in undoped anataseTiO2

Haowei Peng、Jingbo Li、Shu‐Shen Li 等 4 位作者2009-03-19Physical Review B

Using first-principles electronic structure calculations we find that the titanium vacancy and divacancy may be responsible for the unexpected ferromagnetism in undoped anatase ${\text{TiO}}_{2}$. An isolated titanium vacancy produces a magnetic moment of $3.5{\ensuremath{\mu}}_{B}$, and an isolated titanium divacancy…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Highly Uniform Gd(OH)3 and Gd2O3:Eu3+ Nanotubes: Facile Synthesis and Luminescence Properties

Guang Jia、Kai Liu、Yuhua Zheng 等 6 位作者2009-03-19The Journal of Physical Chemistry C

Uniform Gd(OH) 3 nanotubes have been prepared via a simple wet-chemical route at ambient pressure and low temperature, without any catalysts, templates, or substrates, in which Gd(NO 3 ) 3 was used as the gallium source and ammonia as the alkali. SEM and TEM images indicate that the as-obtained Gd(OH) 3 entirely consi…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsGas Sensing Nanomaterials and Sensors

Magnetic, transport, and thermal properties of single crystals of the layered arsenideBaMn2As2

Yogesh Singh、Arkady Ellern、D. C. Johnston2009-03-19Physical Review B

Growth of ${\text{BaMn}}_{2}{\text{As}}_{2}$ crystals using both MnAs and Sn fluxes is reported. Room-temperature crystallography, anisotropic isothermal magnetization $M$ versus field $H$ and magnetic susceptibility $\ensuremath{\chi}$ versus temperature $T$, electrical resistivity in the $ab$ plane $\ensuremath{\rho…

Rare-earth and actinide compoundsIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Higher-order effects and ultrashort solitons in left-handed metamaterials

Nikolaos L. Tsitsas、N. Rompotis、I. Kourakis 等 5 位作者2009-03-19Physical Review E

Starting from Maxwell's equations, we use the reductive perturbation method to derive a second-order and a third-order nonlinear Schrödinger equation, describing ultrashort solitons in nonlinear left-handed metamaterials. We find necessary conditions and derive exact bright and dark soliton solutions of these equation…

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsNonlinear Photonic Systems

Atomically Monodispersed and Fluorescent Sub‐Nanometer Gold Clusters Created by Biomolecule‐Assisted Etching of Nanometer‐Sized Gold Particles and Rods

Renjia Zhou、Minmin Shi、Xiaoqiang Chen 等 5 位作者2009-03-19Chemistry - A European Journal

Abstract From nanocrystals to atomic clusters : Fluorescent gold clusters (Au 8 ) are synthesized by etching gold nanocrystals with the assistance of biomolecules, such as amino acids, peptides, proteins, and DNA (see picture). The gold clusters exhibit strong blue fluorescence as well as solvent‐dependent emission pr…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Model for the Particle Size, Overpotential, and Strain Dependence of Phase Transition Pathways in Storage Electrodes: Application to Nanoscale Olivines

Ming Tang、Hsiao‐Ying Shadow Huang、Nonglak Meethong 等 6 位作者2009-03-19Chemistry of Materials

In the drive toward improved electrical energy storage for applications ranging from wireless devices to electric vehicles to grid stabilization, nanoscale materials are of growing interest as ion storage electrodes. Nanoscale olivines based on Li M PO 4 ( M = Fe, Mn, Co, Ni) are one class of compounds for which recen…

Advanced Battery Materials and TechnologiesAdvanced Thermoelectric Materials and DevicesTransition Metal Oxide Nanomaterials

Reentrant-spin-glass state inNi2Mn1.36Sn0.64shape-memory alloy

S. Chatterjee、S. Giri、S. K. De 等 4 位作者2009-03-19Physical Review B

The ground-state properties of the ferromagnetic shape-memory alloy of nominal composition ${\text{Ni}}_{2}{\text{Mn}}_{1.36}{\text{Sn}}_{0.64}$ have been studied by dc magnetization and ac susceptibility measurements. Like few other Ni-Mn based alloys, this sample exhibits exchange bias phenomenon. The observed excha…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsMagnetic Properties and Applications

Circulation and distribution of gold nanoparticles and induced alterations of tissue morphology at intravenous particle delivery

Georgy S. Terentyuk、Galina N. Maslyakova、Leyla V. Suleymanova 等 10 位作者2009-03-19Journal of Biophotonics

Kinetics, biodistribution, and histological studies were performed to evaluate the particle-size effects on the distribution of 15 nm and 50 nm PEG-coated colloidal gold (CG) particles and 160 nm silica/gold nanoshells (NSs) in rats and rabbits. The above nanoparticles (NPs) were used as a model because of their impor…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and Applications

Detection of Hydrogen Spillover in Palladium-Modified Activated Carbon Fibers during Hydrogen Adsorption

Cristian I. Contescu、Craig M. Brown、Yun Liu 等 5 位作者2009-03-19The Journal of Physical Chemistry C

Palladium-modified activated carbon fibers (Pd-ACF) are being evaluated for adsorptive hydrogen storage at near-ambient conditions because of their enhanced hydrogen uptake in comparison to Pd-free ACF. The net uptake enhancement (at room temperature and 2 MPa) is in excess of the amount corresponding to formation of…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionMuon and positron interactions and applications

Porous Alumina with Shaped Pore Geometries and Complex Pore Architectures Fabricated by Cyclic Anodization

Dušan Lošić、Dušan Lošić、Mickael Lillo 等 5 位作者2009-03-19Small

A new anodization method, termed cyclic anodization, is presented for the controlled modulation of AAO pores structures with shaped geometries and complex architectures (see figure). By applying periodic oscillatory current signals with different profiles, amplitudes, and periods, to combine mild and hard anodization,…

Photonic Crystals and ApplicationsAnodic Oxide Films and NanostructuresSmart Materials for Construction

Magnetic Anisotropy and Magnetization Dynamics of Individual Atoms and Clusters of Fe and Co on Pt(111)

T. Balashov、T. Schuh、A. F. Takacs 等 11 位作者2009-03-19arXiv

The recently discovered giant magnetic anisotropy of single magnetic Co atoms raises the hope of magnetic storage in small clusters. We present a joint experimental and theoretical study of the magnetic anisotropy and the spin dynamics of Fe and Co atoms, dimers, and trimers on Pt(111). Giant anisotropies of individua…

Materials Science

Quantum Monte Carlo study on speckle variation due to photorelaxation of ferroelectric clusters in paraelectric barium titanate

Kai Ji、Kazumichi Namikawa、Hang Zheng 等 4 位作者2009-03-19arXiv

Time-dependent speckle pattern of paraelectric barium titanate observed in a soft x-ray laser pump-probe measurement is theoretically investigated as a correlated optical response to the pump and probe pulses. The scattering probability is calculated based on a model with coupled soft x-ray photon and ferroelectric ph…

Materials Science

Upper critical field and fluctuation conductivity in the critical regime of doped SmFeAsO

I. Pallecchi、Carlo Fanciulli、M. Tropeano 等 10 位作者2009-03-19Physical Review B

We measure magnetotransport of F-doped SmFeAsO samples up to 28 T and we extract the upper critical fields, using different criteria. In order to circumvent the problem of criterion-dependent ${H}_{c2}$ values, we suggest a thermodynamic estimation of the upper critical field slope $d{H}_{c2}/dT$ based on the analysis…

Physics of Superconductivity and MagnetismCorporate Taxation and AvoidanceIron-based superconductors research

Toughening of poly(L‐lactide) by melt blending with rubbers

Sachiko Ishida、Reiko Nagasaki、Keisuke Chino 等 5 位作者2009-03-19Journal of Applied Polymer Science

Abstract Poly( L ‐lactide) (PLA) was melt‐blended with four rubber components—ethylene–propylene copolymer, ethylene–acrylic rubber, acrylonitrile–butadiene rubber (NBR), and isoprene rubber (IR)—in an effort to toughen PLA. All the blend samples exhibited distinct phase separation. Amorphous PLA constituted a topolog…

Polymer crystallization and propertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Ordered Poly(p‐phenylene)/Layered Double Hydroxide Ultrathin Films with Blue Luminescence by Layer‐by‐Layer Assembly

Dongpeng Yan、Jun Lu、Min Wei 等 8 位作者2009-03-19Angewandte Chemie International Edition

Lavender layers: A poly(p-phenylene) anionic derivate and exfoliated Mg-Al layered double hydroxide monolayers were assembled into ultrathin films with well-defined blue fluorescence (see picture; the numbers indicate the number of bilayers), long-range order, and high photostability. These films work as multiple quan…

Supercapacitor Materials and FabricationLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications