Materials Literature
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Abstract Natural antioxidant additives were compounded into linear low‐density polyethylene (LLDPE) using a twin‐screw counter‐rotating mixer and compression molded into films. Manufactured LLDPE films contained 2715 mg kg −1 α‐tocopherol in its free and β‐cyclodextrin complexed form and 1950 mg kg −1 quercetin in its…
We report the preparation of a reversible photoresponsive ultrathin film containing a photoactive azobenzene polymer poly{1-4[4-(3-carboxy-4-hydroxyphenylazo)benzenesulfonamido]-1,2-ethanediyl sodium salt} (PAZO) and exfoliated layered double hydroxide (LDH) nanosheets using a layer-by-layer (LBL) self-assembly techni…
A series of novel waterborne hyperbranched polyurethane-urea (WHBPU) were prepared with different chain extenders (diamine, diol, and siloxane) by a systematic reaction process. Initially, the hyperbranched polyester polyol was prepared by reacting polytetramethyleneglycol (PTMG)-1000 with 2,2-bis(hydroxymethyl) propi…
Abstract A series of epoxidized‐soybean oil (ESO) with different epoxyl content were synthesized by in situ epoxidation of soybean oil (SBO). The acrylated epoxidized‐soybean oil (AESO) was obtained by the reaction of ring opening of ESO using acrylic acid as ring opener. The acrylated expoxidized‐soybean oil‐based th…
A detailed study of the photophysical properties of several chromium-related color centers produced within chemical vapor deposition diamond is presented. These emitters show narrow luminescence lines in the range of $740\ensuremath{-}770$ nm. Single-photon emission was verified with continuous and pulsed excitation w…
Organic electronic devices have demonstrated tremendous versatility in a wide range of applications including consumer electronics, photovoltaics, and biotechnology. The traditional interface of organic electronics with biology, biotechnology, and medicine occurs in the general field of sensing biological phenomena. F…
Sonogashira cross-coupling of bromophenylethenyl-terminated cubic, double four-ring, siloxane cages with di-/triethynyl compounds results in microporous poly(ethynylene aryleneethenylene silsesquioxane) networks, simply termed as polyorganosiloxane networks (PSNs). In comparison with porous organic polymers reported p…
We study the phase behavior of bowl-shaped (nano)particles using confocal microscopy and computer simulations. Experimentally, we find the formation of a wormlike fluid phase in which the bowl-shaped particles have a strong tendency to stack on top of each other. However, using free energy calculations in computer sim…
We show theoretically that flexoelectricity stabilizes blue phases in chiral liquid crystals. Induced internal polarization reduces the elastic energy cost of splay and bend deformations surrounding singular lines in the director field. The energy of regions of double twist is unchanged. This in turn reduces the free…
Three dichloro Sn(IV) porphyrins, trans -dichloro[5,10,15,20-tetra-[2 or 3 or 4-(3-phenoxy)-propoxy]phenyl porphyrin]tin(IV) and the corresponding dihydroxo Sn(IV) porphyrins trans -dihydroxo[5,10,15,20-tetra-[2 or 3 or 4-(3-phenoxy)-propoxy]phenyl porphyrin]tin(IV) were synthesized and characterized spectroscopically…
The thermoelectric characteristics of commercial polycrystalline Mg2Si doped with Bi, Al + Bi, Ag, and Cu were examined. The samples for the thermoelectric measurements were prepared using the plasma-activated sintering (PAS) technique. The measured values of the Seebeck coefficient were compared with values calculate…
Dinuclear acetylide-type complexes bridged by a photochromic dithienylethene unit (DTE), [Y-C[triple bond]C-DTE-C[triple bond]C-Y] 1 (Y={MCp*(dppe)}; Cp*=pentamethylcyclopentadienyl, M=Fe (1(Fe)), Ru (1(Ru))), have been prepared, and their wirelike and switching behavior, as well as their oxidation chemistry has been…
We observe a strong peak in the capacitive photocurrent of a MDMO-PPV / PCBM bulk heterojunction solar cell for excitation below the absorbance threshold energy. Illumination at the peak energy blocks charge capture at other wavelengths, and causes the photovoltage to drop dramatically. These results suggest that the…
The self-healing diffusion Monte Carlo algorithm (SHDMC) [Phys. Rev. B {\bf 79}, 195117 (2009), {\it ibid.} {\bf 80}, 125110 (2009)] is shown to be an accurate and robust method for calculating the ground state of atoms and molecules. By direct comparison with accurate configuration interaction results for the oxygen…
The thermal dynamics induced by ultrashort laser pulses in nanoscale systems, i.e., all-optical time-resolved nanocalorimetry is theoretically investigated from 300 to 1.5 K. We report ab initio calculations describing the temperature dependence of the electron-phonon interactions for Cu nanodisks supported on Si. The…
A continuously operated tubular crystallizer system with an inner diameter of 2.0 mm has been successfully operated. It allows the crystallization of active pharmaceutical ingredients (APIs) under controlled conditions. Acetylsalicylic acid (ASA) which was crystallized from ethanol (EtOH) was used as the model substan…
Highly uniform and well-dispersed CaF(2) hollow spheres with tunable particle size (300-930 nm) have been synthesized by a facile hydrothermal process. Their shells are composed of numerous nanocrystals (about 40 nm in diameter). The morphology and size of the CaF(2) products are strongly dependent on experimental par…
We report colloidal quantum dot solar cells fabricated under ambient atmosphere with an active area of 2.9 mm(2) that exhibit 3.6% solar power conversion efficiency. The devices are based on PbS tuned via the quantum size effect to have a first excitonic peak at 950 nm. Because the formation of native oxides and sulfa…
Ein positives (oder negatives) Chamäleon: Ein bei physiologischen pH-Werten negativ und bei den pH-Werten im extrazellulären Bereich von Tumoren positiv geladenes Nanogel wurde durch die Tumorzellen in vitro wie in vivo effizient internalisiert (siehe Bild). Auch die Wirkstoff-Freisetzung in der Zelle war verstärkt, v…
Spin-dependent coherent tunneling has been experimentally observed in high-quality sputtered-deposited ${\text{Co}}_{2}\text{FeAl}/\text{MgO}/\text{CoFe}$ epitaxial magnetic tunneling junctions (MTJs). Consequently, the microfabricated MTJs manifest a very large tunnel magnetoresistance (TMR) at room temperature and a…