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Methylene‐ and ether‐linked liquid crystal dimers II. Effects of mesogenic linking unit and terminal chain length

Peter A. Henderson、John M. Seddon、Corrie T. Imrie2005-11-01Liquid Crystals

Four series of liquid crystal dimers have been prepared containing either ether‐linked or methylene‐linked spacers. Changing the spacer from being ether‐linked, i.e. O(CH2) n O, to methylene‐linked, i.e. (CH2) n +2, results in decreased nematic–isotropic transition temperatures, and this reduction is more pronounced f…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPlant Reproductive Biology

Phenotype of ENAM Mutations is Dosage-dependent

Didem Özdemır、P. Suzanne Hart、Erhan Fıratlı 等 6 位作者2005-11-01Journal of Dental Research

Five mutations in the ENAM gene have been found to cause hypoplastic amelogenesis imperfecta (AI), with phenotypes ranging from localized enamel pitting in carriers to severe hypoplastic AI. To determine the generality of ENAM mutations in hypoplastic AI, we sequenced the ENAM gene in ten Turkish families segregating…

Corrosion Behavior and InhibitionRNA Interference and Gene DeliveryBone and Dental Protein Studies

Selective oxidation of CO in the presence of H 2 , H 2 O and CO 2 utilising Au/α-Fe 2 O 3 catalysts for use in fuel cells

Philip Landon、J. W. Ferguson、Benjamín Solsona 等 13 位作者2005-11-01Journal of Materials Chemistry

Au/Fe2O3 catalysts prepared using co-precipitation are described and discussed for the preferential oxidation of CO in the presence of H2, H2O and CO2. A catalyst prepared using a two-stage calcination procedure (400 °C followed by 550 °C) achieves target conversion and selectivity (>99.5% CO conversion and >50% selec…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Soluble Nylon-Functionalized Carbon Nanotubes from Anionic Ring-Opening Polymerization from Nanotube Surface

Liangwei Qu、L. Monica Veca、Yi Lin 等 8 位作者2005-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTSoluble Nylon-Functionalized Carbon Nanotubes from Anionic Ring-Opening Polymerization from Nanotube SurfaceLiangwei Qu, L. Monica Veca, Yi Lin, Alex Kitaygorodskiy, Bailin Chen, Alecia M. McCall, John W. Connell, and Ya-Ping SunView Author Information Department of Chemistry a…

Carbon Nanotubes in CompositesGraphene research and applicationsForce Microscopy Techniques and Applications

Synthesis of Diethylamine-Functionalized Soybean Oil

Atanu Biswas、Atanu Adhvaryu、Sherald H. Gordon 等 5 位作者2005-11-01Journal of Agricultural and Food Chemistry

Specialty chemicals based on renewable resources are desirable commodities due to their eco-friendly nature and "green" product characteristics. These chemicals can demonstrate physical and chemical properties comparable to those of conventional petroleum-based products. Suitably functionalized amines in the triacylgl…

Polymer composites and self-healingCarbon dioxide utilization in catalysis

Synthesis and Bio-adsorptive Properties of Large-Pore Periodic Mesoporous Organosilica Rods

Shi‐Zhang Qiao、Chengzhong Yu、Wei Xing 等 6 位作者2005-11-01Chemistry of Materials

Highly ordered large-pore periodic mesoporous organosilica (PMO) with a rodlike morphology was successfully synthesized at low acid concentrations and in the presence of inorganic salt using triblock copolymer P123 as a template. The inorganic salt can not only promote the formation of highly ordered mesoporous struct…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsDiatoms and Algae Research

Nanocapsules as Drug Delivery Systems

Christian Mayer2005-11-01The International Journal of Artificial Organs

Dispersed polymer nanocapsules can serve as nano-sized drug carriers to achieve controlled release as well as efficient drug targeting. The dispersion stability and the primary physiological response are mainly determined by the type of the surfactant and the nature of the outer coating. Their release and degradation…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Electrooptical Responses of Carbon Nanotube-Doped Liquid Crystal Devices

Chi-Yen Huang、Chao-Yuan Hu、Hung-Chih Pan 等 4 位作者2005-11-01Japanese Journal of Applied Physics

The electrooptical characteristics of carbon nanotube-doped liquid crystal (LC) devices were investigated. Two complementary operation modes of the liquid crystal cells were fabricated. The measured results reveal that anisotropic carbon nanosolids modify the dielectric anisotropy and the viscosity of the liquid cryst…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsMechanical and Optical Resonators

Application of a parallel particle swarm optimization scheme to the design of electromagnetic absorbers

Shuang Cui、Daniel S. Weile2005-11-01IEEE Transactions on Antennas and Propagation

The application of parallel (synchronous) particle swarm optimization (PSO) to electromagnetic absorber design is described. Synchronous PSO is a version of PSO that allows for parallelization and hence faster optimization. The velocity updating rule is empirically determined, and a simple approach is presented to imp…

Metamaterials and Metasurfaces ApplicationsEnergy Harvesting in Wireless NetworksAntenna Design and Optimization

Cellular MR imaging.

Michel Modo、Mathias Hoehn、Jeff W. M. Bulte2005-11-01PubMed

Cellular MR imaging is a young field that aims to visualize targeted cells in living organisms. In order to provide a different signal intensity of the targeted cell, they are either labeled with MR contrast agents in vivo or prelabeled in vitro. Either (ultrasmall) superparamagnetic iron oxide [(U)SPIO] particles or…

Nanoparticle-Based Drug DeliveryLanthanide and Transition Metal ComplexesCancer Research and Treatments

Dithiocarbamate ligand stabilised gold nanoparticles

Matthew S. Vickers、James Cookson、Paul D. Beer 等 5 位作者2005-11-01Journal of Materials Chemistry

Dithiocarbamates are used as adsorbates for the preparation of gold nanoparticles. A range of mono- and tetrakis-functionalised dithiocarbamate ligands containing alkyl, benzyl and resorcinarene cavitand substituents are synthesised. Nanoparticles are prepared by a two-phase synthesis and are characterised by 1H NMR s…

Gold and Silver Nanoparticles Synthesis and ApplicationsDendrimers and Hyperbranched PolymersNanocluster Synthesis and Applications

In situ synthesis and assembly of copper oxide nanocrystals on copper foil via a mild hydrothermal process

Yang Liu、Ying Chu、Meiye Li 等 5 位作者2005-11-01Journal of Materials Chemistry

Different dimensional cupric oxide (CuO) nanocrystals and their architectures have been prepared on copper foil via a mild hydrothermal process with the introduction of different types of surfactants. The X-ray powder diffraction (XRD) and energy dispersive X-ray (EDX) patterns indicate that the products are pure CuO…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Raman scattering of polar modes of ZnO crystallites

Leah Bergman、Xiang‐Bai Chen、Jesse Huso 等 5 位作者2005-11-01Journal of Applied Physics

One of the key issues of phonon dynamics of nano- and micrometer-scale crystals is the identification of the observed Raman modes. Due to the tilted orientation of small crystallites, the usual Raman selection rules pertaining to the symmetry axes no longer hold, and mixed-symmetry modes need to be considered in order…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsAcoustic Wave Resonator Technologies

Dependence of electrical properties of epitaxial Pb(Zr,Ti)O3 thick films on crystal orientation and Zr∕(Zr+Ti) ratio

Shintaro Yokoyama、Yoshihisa Honda、Hitoshi Morioka 等 12 位作者2005-11-01Journal of Applied Physics

Epitaxial Pb(Zr,Ti)O3(PZT) films, 1.5–2.0μm in thickness, with a Zr∕(Zr+Ti) ratio ranging from 0.20 to 0.75 were grown on (100)c-,(110)c-, and (111)c-oriented SrRuO3∕∕SrTiO3 substrates at 600 °C by metal-organic chemical vapor deposition (MOCVD). The effects the Zr∕(Zr+Ti) ratio had on the crystal structure, dielectri…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O

Kang Min Ok、P. Shiv Halasyamani2005-11-01Inorganic Chemistry

Four new metal iodates, beta-Cs2I4O11, Rb2I6O15(OH)2.H2O, La(IO3)3, and NaYI4O12, have been synthesized hydrothermally, and the structures were determined by single-crystal X-ray diffraction techniques. All of the reported materials contain I5+ cations that are in asymmetric coordination environments attributable to t…

Crystal structures of chemical compoundsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Novel Biphasic Elastomeric Scaffold for Small-Diameter Blood Vessel Tissue Engineering

Jian Yang、Delara Motlagh、Antonio R. Webb 等 4 位作者2005-11-01Tissue Engineering

Compliance mismatch, thrombosis, and long culture times in vitro remain important challenges to the clinical implementation of a tissue-engineered small-diameter blood vessel (SDBV). To address these issues, we are developing an implantable elastomeric and biodegradable biphasic tubular scaffold. The scaffold design u…

Electrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative MedicineInfectious Aortic and Vascular Conditions

Worldwide SOFC Technology Overview and Benchmark

L. Blum、Wilhelm Albert Meulenberg、H. Nabielek 等 4 位作者2005-11-01International Journal of Applied Ceramic Technology

Solid oxide fuel cells (SOFC) are generally considered to be a promising future electricity‐generation technology due to their high electrical efficiency. They also display a multi‐fuel capability (hydrogen, carbon monoxide, methane, etc.), may play a role in carbon sequestration strategies, and may render the highest…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Structure and Thermodynamics of Weakly Segregated Rod−Coil Block Copolymers

Bradley D. Olsen、Rachel A. Segalman2005-11-01Macromolecules

The self-assembly of a series of monodisperse rod−coil block copolymers is studied in the weak segregation limit. This unusual weakly segregated system consists of polyisoprene (PI) coil blocks and poly(alkoxyphenylene vinylene) (PPV) rod blocks solubilized with alkoxy side groups. The order to microphase disorder tra…

Organic Electronics and PhotovoltaicsLiquid Crystal Research AdvancementsBlock Copolymer Self-Assembly

Synthesis of Mesoporous BN and BCN Exhibiting Large Surface Areas via Templating Methods

Ajayan Vinu、Mauricio Terrones、Dmitri Golberg 等 6 位作者2005-11-01Chemistry of Materials

Mesoporous BN and BCxN have been prepared using mesoporous carbon as a template and characterized by HRTEM, EELS, HRSEM, and N2 adsorption. These materials possess high surface area and well-ordered pore systems and could now be applied in the fabrication of oxidation-resistant composites, gas storage devices, and mol…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisBoron and Carbon Nanomaterials Research

Use of novel adaptive digital feedback for magnetic measurements under controlled magnetizing conditions

Stan Zurek、P. Marketos、T. Meydan 等 4 位作者2005-11-01IEEE Transactions on Magnetics

There are increasing calls to employ conventional magnetic testers, such as the Epstein frame and single sheet tester, for the accurate measurements of magnetic properties of soft magnetic materials under fully controlled nonsinusoidal flux density waveforms. This paper presents a computerized automated adaptive digit…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesMagnetic Field Sensors Techniques