Materials Literature
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The dynamic interaction of a quantum rotor with its crystalline environment has been studied by measurement of the thermal conductivity of solid Kr1_c(CH4)_c solutions at c = 0.05-0.75 in the temperature region from 2 up to 40K. The thermal resistance of the solutions was mainly determined by the resonance scattering…
We show that when the magnetizations on opposite sides of a junction are not collinear, the magnetization current is not conserved as the junction is crossed. Thus the usual treatment of this problem needs to be modified. We argue that this is due to an implicit assumption of an external torque that is required to cla…
In this paper, we analyze the upper critical field of four MgB2 thin films, with different resistivity (between 5 to 50 mWcm) and critical temperature (between 29.5 to 38.8 K), measured up to 28 Tesla. In the perpendicular direction the critical fields vary from 13 to 24 T and we can estimate 42-57 T range in other di…
The thermal conductivity of solid SF6, CHCI3, C6H6, and CCl4 was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples.The contributions of the phonon -phonon and ph…
The biological formation of inorganic materials with complex form (biominerals) is a widespread phenomenon in nature, yet the molecular mechanisms underlying biomineral morphogenesis are not well understood. Among the most fascinating examples of biomineral structures are the intricately patterned, silicified cell wal…
Enhancement of the photoluminescence (PL) of colloidal CdSe and (core)shell (CdSe)ZnS quantum dots has been observed when the dots are illuminated above the band-gap energy. The effect occurs in dots suspended in a variety of organic or aqueous environments. During periods of constant illumination, the exciton PL quan…
Predicting and characterizing the crystal structure of materials is a key problem in materials research and development. It is typically addressed with highly accurate quantum mechanical computations on a small set of candidate structures, or with empirical rules that have been extracted from a large amount of experim…
In this study, air-drying experiments in thin layers of mulberry grown in Istanbul, Turkey, were conducted. The effect of ethyl oleate solution on drying time of mulberry samples was investigated in a pilot air-dryer. When ethyl oleate was used as pretreatment solution, the drying time of samples was decreased. Drying…
The scaling properties of the soft-sphere potential allow the derivation of an exact expression for the pressure of a frozen liquid, i.e., the pressure corresponding to configurations which are local minima in its multidimensional potential energy landscape. The existence of such a relation offers the unique possibili…
${\mathrm{SnO}}_{2}$ nanoparticles having an average particle size of 5 nm were precipitated in transparent glasses by irradiation with an 800-nm femtosecond laser pulse. Glasses, prepared to codope ${\mathrm{Sn}}^{4+}$ and ${\mathrm{Eu}}^{3+}$ ions by a sol-gel method, were heated in a ${\mathrm{H}}_{2}$ gas atmosphe…
Popular numerical techniques for solving the Boltzmann transport equation (BTE) for sub-micron thermal conduction include the discrete ordinates method and the finite volume method. However, the finite wave speed associated with the BTE can cause large errors in the prediction of the equivalent temperature unless fine…
Here we employ both Fe K and L 2,3 edge X-ray absorption near-edge structure (XANES) spectroscopy techniques to clarify that in the B -site ordered double-perovskite halfmetal, Sr 2 FeMoO 6.0, iron possesses a mixed-valence state, Fe II/III, and accordingly, molybdenum a mixed Mo V/VI valence state. A reliable interpr…
A mechanism of direct benzene hydroxylation over Fe−ZSM-5 zeolite is discussed from B3LYP density functional theory computations. We demonstrate using a mononuclear iron model supported at the AlO 4 - site of zeolite that Fe−ZSM-5 zeolite reasonably catalyzes the conversion of benzene to phenol with N 2 O. A key in th…
The microscopic infrared dichroism measurement is made on a quenched iPP thin film during the stepwise elongation to obtain the molecular orientation functions, f am and f c, in the amorphous and the crystalline phases, respectively. Results reveal that the pseudo-affine deformation of the amorphous phase occurs for f…
Abstract The thermal degradation of isotactic and atactic polypropylene was investigated in bulk and in solution. The degradation in bulk was studied with thermogravimetric analysis, and the degradation in solution was studied by the dissolution of the polymer in paraffin oil. The degradation in solution was investiga…
Abstract Novel positive‐working aqueous‐base developable photosensitive polyimide (PSPI) precursors based on partially diazonaphthoquinone (DNQ)‐capped polyamic esters bearing phenolic hydroxyl groups and a DNQ photosensitive compound (PIC‐3) were developed. The partially DNQ capped polyamic esters were prepared from…
Formaldehyde is a carcinogen compound and one of the most important pollutants contained in wastewaters. Three different treatments were evaluated in a high-pressure batch reactor for the total organic carbon (TOC) degradation of formaldehyde solutions: thermolysis, noncatalytic wet oxidation, and catalytic wet oxidat…
In this study, we provide a strategy to electrodeposit polypyrrole (PPy) on roughened silver substrates, which was accomplished by a triangular-wave oxidation−reduction cycle (ORC) for three scans in an aqueous solution containing 0.1 N KCl. This method overcomes the conventional limitation that silver, oxidizing more…
Abstract Epoxy nanocomposites were prepared from the different organoclays with aerospace epoxy resin. A series of organoclays treated with alkylammonium chloride with different alkyl groups of different carbon chains were prepared, including SC4, SC6, SC8, SC10, SC12, SC16, SC18, and NC8, NC12, NC18. All of these org…
In compact transistors, large electric fields near the drain side create hot spots whose dimensions are smaller than the phonon mean free path in the medium. In this paper, we present a study of unsteady hot spot behavior. The unsteady gray phonon Boltzmann transport equation (BTE) is solved in the relaxation time app…