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A new method for deaggregation of nanodiamond from explosive detonation: Graphitization-oxidation method

Kang Xu、Qunji Xue2004-04-01Physics of the Solid State

In this communication, a new method for the deaggregation of detonation nanodiamond (ND) and some preliminary results using this method are presented. ND is firstly graphitized in nitrogen at 1000°C and then oxidized by air at 450°C to remove the surface graphite layer formed. The sample after such treatment was suspe…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchEnergetic Materials and Combustion

Incorporating fluorescent dyes and quantum dots into magnetic microbeads for immunoassays

Shawn P. Mulvaney、Hedi Mattoussi、L. J. Whitman2004-04-01BioTechniques

Microbeads that are both paramagnetic and fluorescently labeled are commercially available in colors spanning the visible spectrum. Although these commercial beads can be bright, polydispersity in both size and fluorescent intensity limit their use in quantitative assays. Very recently, more monodisperse beads have be…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesAdvanced Biosensing Techniques and Applications

Plugged Hexagonal Templated Silica (PHTS): An In-Depth Study of the Structural Characteristics

E. Van Bavel、Pegie Cool、Katrien Aerts 等 4 位作者2004-04-01The Journal of Physical Chemistry B

Hexagonal mesoporous silica materials (PHTS) are synthesized with a high TEOS/EO 20 PO 70 EO 20 ratio containing microporous nanocapsules or plugs inside the mesoporous channels. This PHTS material exhibits a tunable amount of open and plugged pores, has a high micropore volume (up to 0.24 mL/g), and is more stable th…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisAerogels and thermal insulation

Recent research and development in synthetic polymer-based drug delivery systems

Samaresh Ghosh2004-04-01Journal of Chemical Research

In recent years, there has been increasing recognition that a number of synthetic polymers which have excellent biodegradability and biocompatibility are materials of pharmaceutical importance in the area of drug delivery technology. The aim of this review is to take a closer look at a few synthetic polymer-based drug…

Advanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Commingled and Air Jet-textured Hybrid Yarns for Thermoplastic Composites

R. Alagirusamy、Vinayak Ogale2004-04-01Journal of Industrial Textiles

Hybrid yarns have reinforcing and matrix-forming filaments combined together in order to reduce the problems associated with high melt viscosity of thermoplastic matrices. Among hybrid yarns, commingled and air-textured yarns, which are produced with air jets have demonstrated high flexibility and good mixing of const…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesTextile materials and evaluations

Infrared-to-visible upconversion of Er^3+ ions in GeO_2–PbO–Nb_2O_5 glasses

R. Balda、Ángel J. García-Adeva、J.F. Fernández 等 4 位作者2004-04-01Journal of the Optical Society of America B

We report the infrared-to-visible upconversion luminescence of Er3+-doped lead–niobium–germanate glasses (GeO2–PbO–Nb2O5) with different Er2O3 concentrations (0.5, 1, 2, and 3 wt.%) under continuous-wave and pulsed-laser excitation in the near-infrared region inside the 4I9/2 level. Intense green emission due to the (…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhotorefractive and Nonlinear Optics

Effects of Iron Content on Microstructure and Crevice Corrosion of Grade-2 Titanium

X. He、James J. Noël、D.W. Shoesmith2004-04-01CORROSION

The effects of iron content on the microstructure and crevice corrosion of Grade-2 titanium (Ti-2) were studied using a galvanic coupling technique combined with optical microscopy and secondary ion mass spectrometry (SIMS) imaging. This study reveals that iron content has a significant effect on the microstructure an…

Metal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

Quantitative XPS Analysis of PEG-Modified Silicon Surfaces

Ketul C. Popat、Sadhana Sharma、Tejal A. Desai2004-04-01The Journal of Physical Chemistry B

Poly(ethylene glycol) (PEG) films were covalently coupled to silicon surfaces using a solution phase and a vapor phase technique. These methods are targeted for creating nonfouling PEG films on silicon bio-microsystems. We used X-ray photoelectron spectroscopy (XPS) to better understand and analyze PEG functionalized…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Sedimentation and multi-phase equilibria in mixtures of platelets and ideal polymer

H. H. Wensink、H. N. W. Lekkerkerker2004-04-01Europhysics Letters (EPL)

The role of gravity in the phase behaviour of mixtures of hard colloidal plates without and with non-adsorbing ideal polymer is explored theoretically. By analyzing the (macroscopic) osmotic equilibrium conditions, we show that sedimentation of the colloidal platelets is significant on a height range of even a centime…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Optical properties and applications of dendrimer–metal nanocomposites

Theodore Goodson、Oleg Varnavski、Y. Wang2004-04-01International Reviews in Physical Chemistry

The use of novel nanostructured materials for optical applications continues to be an important issue for the creation of new devices. New materials including metal nanoparticles have played an important role for applications in photonics, biology, as well as medicine. This review primarily concerns the use of one par…

Gold and Silver Nanoparticles Synthesis and ApplicationsDendrimers and Hyperbranched PolymersNanocluster Synthesis and Applications

Chemical Bonding in Polyethylene−Nanotube Composites: A Quantum Mechanics Prediction

Kausala Mylvaganam、L. C. Zhang2004-04-01The Journal of Physical Chemistry B

To make full use of the strength of carbon nanotubes in a composite, it is important to have a high-stress transfer at the matrix−nanotube interface via strong chemical bonding. This paper investigates the possible polyethylene−nanotube bonding with the aid of a quantum mechanics analysis. The polyethylene chains were…

Carbon Nanotubes in CompositesGraphene research and applicationsPolymer crystallization and properties

Cofactor Hydrogen Bonding onto the Protein Main Chain Is Conserved in the Short Chain Dehydrogenase/Reductase Family and Contributes to Nicotinamide Orientation

Rong Shi、Sheng‐Xiang Lin2004-04-01Journal of Biological Chemistry

Human estrogenic 17beta-hydroxysteroid dehydrogenase (17beta-HSD1), a member of the short chain dehydrogenase/reductase (SDR) family, is responsible for the biosynthesis of all active estrogens. The crystal structures of two C19-steroid ternary complexes (17beta-HSD1-androstanedione-NADP and 17beta-HSD1-androstenedion…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Molecular Research

Effect of Substitution on the Change of Refractive Index in Dithienylethenes: An Ellipsometric Study

Chiara Bertarelli、Andrea Bianco、F. D’Amore 等 5 位作者2004-04-01Advanced Functional Materials

Abstract An ellipsometric study was carried out in order to investigate the photoinduced change of the refractive index (Δ n ) of a series of diarylethenes across the entire spectral range 260–1700 nm. This technique allowed examination of the influence of the resonance conditions on the refractive index. Changing the…

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryOrganic Chemistry Cycloaddition Reactions

An evaluation of radiation damage to solid state components flown in low earth orbit satellites

M.-W. Shin2004-04-01Radiation Protection Dosimetry

The effects of total ionising radiation dose upon commercial off-the-shelf semiconductors fitted to satellites operating in low Earth orbit (LEO) conditions was evaluated. The evaluation was performed for the Korea Institute of Technology SATellite-1, (KITSAT-1) which was equipped with commercial solid state component…

Radiation Effects in ElectronicsSpacecraft Design and TechnologyGraphite, nuclear technology, radiation studies

Bifurcation of the Kirkendall plane and patterning in reactive diffusion

Alexander Kodentsov、Aloke Paul、F.J.J. van Loo2004-04-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

The formation of reaction zone morphologies periodic in time and space can be considered as a manifestation of the Kirkendall effect accompanying interdiffusion in the solid state. In a diffusion-controlled interaction, the Kirkendall marker plane can bifurcate, which is attributed to diverging vacancy fluxes in the r…

Intermetallics and Advanced Alloy PropertiesSemiconductor materials and interfacesMetallurgical and Alloy Processes

Influence of ZnO on optical properties and dc conductivity of vanadyl-doped alkali bismuthate glasses

Pardeep Gahlot、V. P. Seth、Ashish Agarwal 等 7 位作者2004-04-01Radiation effects and defects in solids

A new family of glasses based on Bi2O3 was found in the systems xZnO · (0.30 − x)M2O · 0.70Bi2O3 (M = Li, Na) in the range 0.00 ≤ x ≤ 0.20 containing 2.0 mol% of V2O5. Density, molar volume, optical band gap and dc conductivity of these glasses have been investigated. The position of the absorption edge and hence the…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhase-change materials and chalcogenides

Variations in mixed-layer illite/smectite diagenesis in the rift and post-rift sediments of the Jeanne d'Arc Basin, Grand Banks offshore Newfoundland, Canada

Iftikhar Abid、Reinhard Hesse、John Harper2004-04-01Canadian Journal of Earth Sciences

Mixed-layer illite/smectite (I/S) clays were analyzed from 22 deep exploration wells from the Jeanne d'Arc Basin on the Grand Banks offshore Newfoundland, the host of large commercial hydrocarbon accumulations discovered in the last two and a half decades. The fine fraction of the clays (<0.1 µm) consists mainly of…

Geological and Geochemical AnalysisClay minerals and soil interactionsGeological and Geophysical Studies Worldwide

Synthesis and Analysis of Triphenylamine: A Review

Touraj Manifar、Sohrab Rohani2004-04-01The Canadian Journal of Chemical Engineering

Abstract In this paper, synthesis and characteristic of arylamine‐type molecules, particularly triphenylamine are discussed. An overview of the physical properties and chemical characteristics of these types of molecules is provided. Different synthesis methods and mechanisms involved for the production of these molec…

Molecular Sensors and Ion DetectionChemical Synthesis and AnalysisLuminescence and Fluorescent Materials

Electron emission properties of detonation nanodiamonds

V.V. Zhirnov、Olga Shenderova、David L. Jaeger 等 7 位作者2004-04-01Physics of the Solid State

This paper summarizes the results of systematic studies of field electron emission from detonation nanodiamond coatings corresponding to nanodiamond powders of different modifications. The role of the chemical composition of the surface of detonation nanodiamond particles in field emission mechanisms is discussed. Fie…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Short-range order, large-scale potential fluctuations, and photoluminescence in amorphous SiNx

V. A. Gritsenko、D. V. Gritsenko、Yu. N. Novikov 等 5 位作者2004-04-01Journal of Experimental and Theoretical Physics

The short-range order and electron structure of amorphous silicon nitride SiNx (x<4/3) have been studied by a combination of methods including high-resolution X-ray photoelectron spectroscopy. Neither random bonding nor random mixture models can adequately describe the structure of this compound. An intermediate model…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceIon-surface interactions and analysis