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Nanoscale Imaging and Spectroscopy of Plasmonic Modes with the PTIR Technique

Aaron M. Katzenmeyer、Jungseok Chae、Richard Kasica 等 6 位作者2014-05-02Advanced Optical Materials

The photothermal induced resonance (PTIR) method measures the near-field absorption in gold plasmonic structures. PTIR absorption images show the interference between the bright and dark modes of asymmetric split ring resonators (ASRRs). The plasmonic absorption spectra of the ASRRs individual arcs are obtained locall…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotoacoustic and Ultrasonic Imaging

Design and Optimization of an Innovative Solid Oxide Fuel Cell–Gas Turbine Hybrid Cycle for Small Scale Distributed Generation

Emanuele Facchinetti、Daniel Favrat、François Maréchal2014-05-02Fuel Cells

Abstract Distributed power generation and cogeneration is an attractive way toward a more rational conversion of fuel and biofuel. The fuel cell‐gas turbine hybrid cycles are emerging as the most promising candidates to achieve distributed generation with comparable or higher efficiency than large‐scale power plants.…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Real-Time Raman Monitoring and Control of the Catalytic Acetalization of Glycerol with Acetone over Modified Mesoporous Cellular Foams

Vanesa Calvino Casilda、Katarzyna Stawicka、Maciej Trejda 等 5 位作者2014-05-02The Journal of Physical Chemistry C

The acetalization of glycerol with acetone over modified mesoporous cellular foam materials has been widely investigated using in situ Raman spectroscopy during reaction. Mesoporous cellular foams (MCFs) modified by niobium or tantalum and (3-mercaptopropyl)trimethoxysilane (MP) followed by H 2 O 2 treatment were used…

Mesoporous Materials and CatalysisCatalysis for Biomass ConversionCatalysis and Hydrodesulfurization Studies

A study of the phase transition and magnetocaloric effect in multiferroic La2MnNiO6 single crystals

M. Ballı、P. Fournier、S. Jandl 等 4 位作者2014-05-02Journal of Applied Physics

Magnetic and magnetocaloric properties of single crystal double perovskite La2MnNiO6 have been investigated in details. Its ordered phase with a high Curie temperature (TC = 280 K) exhibits a significant refrigerant capacity around room temperature. A model based on the mean field theory approximation has been used in…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Rice husk flour biocomposites based on recycled high-density polyethylene/polyethylene terephthalate blend: effect of high filler loading on physical, mechanical and thermal properties

Shan Chen、Mohd Hafizuddin Ab Ghani、Sahrim Ahmad 等 5 位作者2014-05-02Journal of Composite Materials

Biocomposites of recycled high-density polyethylene (rHDPE)/recycled polyethylene terephthalate (rPET) matrices with a high loading of rice husk flour (RHF) were fabricated through a two-step extrusion. The use of ethylene-glycidyl methacrylate (E-GMA) copolymer improved the compatibility of the immiscible rHDPE/rPET…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Chitosan‐coated Gold Nanorods for Cancer Therapy Combining Chemical and Photothermal Effects

Ruiping Duan、Zhimin Zhou、Guanghao Su 等 7 位作者2014-05-02Macromolecular Bioscience

To develop a novel type of nanoparticle for cancer therapy, gold nanorods (GNRs) are coated with chitosan (CS) derivatives to combine chemical and photothermal effects. Thiol-modified chitosan derivatives chemically conjugated to doxorubicin (DOX) are successfully synthesized and their in vitro effect is evaluated. Fu…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

A Closer Look on the Polyhydroxybutyrate- (PHB-) Negative Phenotype of Ralstonia eutropha PHB-4

Matthias Raberg、Birgit Voigt、Michael Hecker 等 4 位作者2014-05-02PLoS ONE

The undefined poly(3-hydroxybutyrate)- (PHB-) negative mutant R. eutropha PHB-4 was generated in 1970 by 1-nitroso-3-nitro-1-methylguanidine (NMG) treatment. Although being scientific relevant, its genotype remained unknown since its isolation except a recent first investigation. In this study, the mutation causing th…

biodegradable polymer synthesis and propertiesPolyamine Metabolism and ApplicationsAmino Acid Enzymes and Metabolism

Highly Stable Carbon Nanotube Top‐Gate Transistors with Tunable Threshold Voltage

Huiliang Wang、Brian Cobb、Albert J. J. M. van Breemen 等 5 位作者2014-05-02Advanced Materials

Carbon-nanotube top-gate transistors with fluorinated dielectrics are presented. With PTrFE as the dielectric, the devices have absent or small hysteresis at different sweep rates and excellent bias-stress stability under ambient conditions. Ambipolar single-walled carbon nanotube (SWNT) transistors are observed when…

Carbon Nanotubes in CompositesNanowire Synthesis and ApplicationsMechanical and Optical Resonators

Multidentate Block-Copolymer-Stabilized Ultrasmall Superparamagnetic Iron Oxide Nanoparticles with Enhanced Colloidal Stability for Magnetic Resonance Imaging

Nicky Chan、Myriam Laprise‐Pelletier、Pascale Chevallier 等 6 位作者2014-05-02Biomacromolecules

Ultrasmall superparamagnetic iron oxide nanoparticles (USPIOs) with diameters <5 nm hold great promise as T1-positive contrast agents for in vivo magnetic resonance imaging. However, control of the surface chemistry of USPIOs to ensure individual colloidal USPIOs with a ligand monolayer and to impart biocompatibility…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Design and simulation of omnidirectional reflective color filters based on metal-dielectric-metal structure

Chenying Yang、Weidong Shen、Yueguang Zhang 等 6 位作者2014-05-02Optics Express

We propose omnidirectional reflective color filters based on metal-dielectric-metal subwavelength grating structure. By particle swarm optimization, the structural parameters of three color filters (yellow, magenta, cyan) are obtained. The optimized filters can present the same perceived specular color at unpolarized…

Plasmonic and Surface Plasmon ResearchPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Planar High Temperature Heat Pipes for SOFC/SOEC Stack Applications

M. Dillig、Jonas M. Leimert、Jürgen Karl2014-05-02Fuel Cells

Abstract Targeting transient operation of high temperature solid oxide cell (SOC) systems this paper proposes an enhanced heat management mechanism using planar high temperature heat pipes that can be integrated into the SOC‐stack structure. Flat heat pipes with thicknesses down to 4 mm filled with liquid alkali metal…

Advancements in Solid Oxide Fuel CellsHeat Transfer and Boiling StudiesElectronic and Structural Properties of Oxides

Deterministic Cold Cathode Electron Emission from Carbon Nanofibre Arrays

Matthew T. Cole、Kenneth B. K. Teo、Oliver Groening 等 6 位作者2014-05-02Scientific Reports

The ability to accurately design carbon nanofibre (CN) field emitters with predictable electron emission characteristics will enable their use as electron sources in various applications such as microwave amplifiers, electron microscopy, parallel beam electron lithography and advanced Xray sources. Here, highly unifor…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Label-Free Aptasensor Based on Ultrathin-Linker-Mediated Hot-Spot Assembly To Induce Strong Directional Fluorescence

Shuo‐Hui Cao、Wei‐Peng Cai、Qian Liu 等 8 位作者2014-05-02Journal of the American Chemical Society

We have demonstrated the proof-of-concept of a label-free biosensor based on emission induced by an extreme hot-spot plasmonic assembly. In this work, an ultrathin linking layer composed of cationic polymers and aptamers was fabricated to mediate the assembly of a silver nanoparticles (AgNPs)-dyes-gold film with a str…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Director/barycentric rotation in cholesteric droplets under temperature gradient

Jun Yoshioka、Fumiya Ito、Yuto Suzuki 等 6 位作者2014-05-02Soft Matter

When a chiral liquid crystal is given a transport current, a unidirectional molecular motion is known to take place, which is called the Lehmann effect. In this paper, we study the mysterious heat-current-driven Lehmann effect using two types of hemispherical cholesteric droplets using polarizing, reflecting, confocal…

Liquid Crystal Research AdvancementsSpectroscopy and Quantum Chemical StudiesNonlinear Dynamics and Pattern Formation

Configurable Three‐Dimensional Boron Nitride–Carbon Architecture and Its Tunable Electronic Behavior with Stable Thermal Performances

Manuela Loeblein、Roland Yingjie Tay、Siu Hon Tsang 等 5 位作者2014-05-02Small

Recent developments of 3D-graphene and 3D-boron-nitride have become of great interest owing to their potential for ultra-light flexible electronics. Here we demonstrate the first synthesis of novel 3D-BNC hybrids. By specifically controlling the compositions of C and BN, new fascinating properties are observed, such a…

Graphene research and applications2D Materials and ApplicationsThermal properties of materials

Size-Selective Catalytic Growth of Nearly 100% Pure Carbon Nanocoils with Copper Nanoparticles Produced by Atomic Layer Deposition

Guizhen Wang、Gu Ran、Gengping Wan 等 8 位作者2014-05-02ACS Nano

In this paper, Cu nanoparticles with narrow size distribution are synthesized by reduction of CuO films produced by atomic layer deposition (ALD), which are used as catalysts for the catalytic growth of carbon nanostructures. By properly adjusting the ALD cycle numbers, the size of produced Cu nanoparticles can be wel…

Carbon Nanotubes in CompositesGraphene research and applicationsCatalytic Processes in Materials Science

Solubility of Bioactive Compound Hesperidin in Six Pure Solvents at (298.15 to 333.15) K

Md. Khalid Anwer、Ramadan Al‐Shdefat、Shahid Jamil 等 6 位作者2014-05-02Journal of Chemical & Engineering Data

Temperature-dependent solubility data of bioactive compound hesperidin has not been reported in any solvent in the literature so far. Therefore, the aim of the current study was to measure the solubility of bioactive compound hesperidin in six different pure solvents namely water, ethanol, isopropyl alcohol (IPA), pro…

Crystallization and Solubility StudiesPharmacological Effects of Natural CompoundsChromatography in Natural Products

See-Through <inline-formula><tex-math>$\hbox{Ga}_{2}\hbox{O}_{3}$</tex-math></inline-formula> Solar-Blind Photodetectors for Use in Harsh Environments

Tzu‐Chiao Wei、Dung‐Sheng Tsai、Parvaneh Ravadgar 等 9 位作者2014-05-02IEEE Journal of Selected Topics in Quantum Electronics

This paper demonstrates the high-temperature operation of fully transparent solar-blind deep ultraviolet (DUV) metal-semiconductor-metal (MSM) photodetectors (PDs) employing β-Ga2O3thin films with transmittance up to 80% from 400 to 900 nm without image blurring. Even at a bias up to 200 V, the β-Ga2O3MSM PDs show dar…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Synthesis of ZnO decorated graphene nanocomposite for enhanced photocatalytic properties

S. Gayathri、P. Jayabal、M. Kottaisamy 等 4 位作者2014-05-02Journal of Applied Physics

Zinc oxide/Graphene (GZ) composites with different concentrations of ZnO were successfully synthesized through simple chemical precipitation method. The X-ray diffraction pattern and the micro-Raman spectroscopic technique revealed the formation of GZ composite, and the energy dispersive X-ray spectrometry analysis sh…

Advanced Photocatalysis TechniquesZnO doping and propertiesGas Sensing Nanomaterials and Sensors

Electro-Optical Modulation Processes in Si-PMOSFET LEDs Operating in the Avalanche Light Emission Mode

Kaikai Xu2014-05-02IEEE Transactions on Electron Devices

In this paper, the switching characteristics as associated with p + n gated MOSFET silicon LED are reviewed. By employing the insulated-gate terminal, which allows the adjustment of P+source/drain to N-substrate junction breakdown voltage, it is demonstrated that the electro-optical modulation in the Si-PMOSFET device…

Photonic and Optical DevicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence