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Catalytic oxidation of water and alcohols by a robust iron( iii ) complex bearing a cross-bridged cyclam ligand

Peng Tan、Hoi‐Ki Kwong、Tai‐Chu Lau2015-01-01Chemical Communications

An iron(iii) complex bearing a cross-bridged cyclam ligand (4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane) is an efficient catalyst for the oxidation of both water and alcohols using sodium periodate as the oxidant. In catalytic water oxidation a maximum turnover number (TON) of 1030 is achieved, while in ca…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Heterostructured g-C 3 N 4 /Ag–TiO 2 composites with efficient photocatalytic performance under visible-light irradiation

Mengqiao Zang、Lei Shi、Lin Liang 等 5 位作者2015-01-01RSC Advances

The heterostructured g-C 3 N 4 /Ag–TiO 2 composites exhibited high photocatalytic activity, which was attributed to the synergistic effects of the enhanced absorption of visible light and the efficient separation rates for photogenerated electrons-holes.

Advanced Photocatalysis TechniquesPerovskite Materials and ApplicationsAdvanced Nanomaterials in Catalysis

Concave or convex π-dimers: the role of the pancake bond in substituted phenalenyl radical dimers

Zhong‐hua Cui、Abhinav Gupta、Hans Lischka 等 4 位作者2015-01-01Physical Chemistry Chemical Physics

π-stacking in dimers of phenalenyl represents the prototypical pancake bonding between radicals. This type of π-stacking aggregate is a key structural motif in conducting organic and multifunctional materials. It is driven by the bonding combination of the singly occupied molecular orbitals (SOMOs) of the monomers res…

Metal-Organic Frameworks: Synthesis and ApplicationsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry

Synthesis of GO supported Fe 2 O 3 –TiO 2 nanocomposites for enhanced visible-light photocatalytic applications

Wan‐Kuen Jo、N. Clament Sagaya Selvam2015-01-01Dalton Transactions

This article reports novel ternary composites consisting of Fe2O3 nanorods, TiO2 nanoparticles, and graphene oxide (GO) flakes that provide enhanced photocatalytic performance and stability. Fe2O3 nanorods grow evenly and embed themselves on the agglomerated TiO2/GO surface, which facilitate the formation of heterojun…

Advanced Photocatalysis TechniquesIron oxide chemistry and applicationsCopper-based nanomaterials and applications

Synthesis of Ag 2 CO 3 /Bi 2 WO 6 heterojunctions with enhanced photocatalytic activity and cycling stability

Jianxing Bao、Shenghui Guo、Jiyun Gao 等 8 位作者2015-01-01RSC Advances

Novel hierarchical Ag 2 CO 3 /Bi 2 WO 6 heterojunction photocatalysts were prepared and they exhibited excellent photocatalytic activity and outstanding cycling performance for the degradation of rhodamine B (RhB) dye under visible light irradiation.

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Label-free photoelectrochemical cytosensing via resonance energy transfer using gold nanoparticle-enhanced carbon dots

Shanshan Liu、Huijuan Cao、Zhaoyin Wang 等 5 位作者2015-01-01Chemical Communications

A universal and label-free photoelectrochemical cytosensing strategy was designed based on resonance energy transfer (RET) between carbon dots and cysteamine capped gold nanoparticles. RET promoted photo-to-current conversion efficiency and enhanced detection sensitivity. This proposed photoelectrochemical cytosensing…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Poly(vinylidene fluoride) nanofibrous mats with covalently attached SiO 2 nanoparticles as an ionic liquid host: enhanced ion transport for electrochromic devices and lithium-ion batteries

Rui Zhou、Wanshuang Liu、Xiayin Yao 等 5 位作者2015-01-01Journal of Materials Chemistry A

Using ionic liquid-loaded SiO 2 -on-P(VDF–HFP) nanofibrous mats as electrolytes, both electrochromic devices and Li/LiCoO 2 batteries exhibit significantly improved performance.

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

The effect of structural dimensionality on the electrocatalytic properties of the nickel selenide phase

Suresh Kukunuri、M. R. V. Krishnan、S. Sampath2015-01-01Physical Chemistry Chemical Physics

Nickel selenide (NiSe) nanostructures possessing different morphologies of wires, spheres and hexagons are synthesized by varying the selenium precursors, selenourea, selenium dioxide (SeO2) and potassium selenocyanate (KSeCN), respectively, and are characterized using X-ray diffraction, X-ray photoelectron spectrosco…

Electrocatalysts for Energy ConversionQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Highly flexible, conductive and catalytic Pt networks as transparent counter electrodes for wearable dye-sensitized solar cells

Ranran Zhou、Wenxi Guo、Ruomeng Yu 等 4 位作者2015-01-01Journal of Materials Chemistry A

We present a highly flexible dye-sensitized solar cell composed of TiO 2 nanotube arrays (TNARs) as the photoanode and a transparent Pt network electrode as the counter electrode (CE).

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesConducting polymers and applications

Electrodeposition of ZnCo 2 O 4 nanoparticles for biosensing applications

Kusha Kumar Naik、Chandra Sekhar Rout2015-01-01RSC Advances

Electrochemical sensing properties of electrodeposited ZnCo 2 O 4 nanoparticles towards glucose and dopamine are investigated.

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Porous barium–organic frameworks with highly efficient catalytic capacity and fluorescence sensing ability

Fuling Liu、Yuwen Xu、Lianming Zhao 等 7 位作者2015-01-01Journal of Materials Chemistry A

Through single-crystal-to-single-crystal transformation, highly active Ba 2+ open metal sites are achieved in porous MOFs, which exhibit efficient catalytic capacity for the cyanosilylation of aldehydes and ketones and show excellent fluorescence sensing of DMSO molecules.

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

Nickel embedded in N-doped porous carbon for the hydrogenation of nitrobenzene to p-aminophenol in sulphuric acid

Tao Wang、Zhen Dong、Teng Fu 等 9 位作者2015-01-01Chemical Communications

An acid-resistant catalyst composed of nickel embedded in N-doped porous carbon is developed for the catalytic hydrogenation of nitrobenzene (NB) to p-aminophenol (PAP). The catalyst, due to a special electron donation from nickel to the N-doped porous carbon, shows an excellent catalytic performance and stability in…

Advanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Fabrication of nanocellulose–hydroxyapatite composites and their application as water-resistant transparent coatings

Mai Ishikawa、Yuya Oaki、Yoshihisa Tanaka 等 6 位作者2015-01-01Journal of Materials Chemistry B

Nanosized composite rods ∼300 nm in length and ∼20 nm in width were produced by deposition of 22-77 wt% of a c-axis-oriented hydroxyapatite (HA) on cellulose nanocrystals (CNCs). The CNCs functionalized with sulphonic groups were covered with the HA nanocrystals through controlled nucleation and growth under a moderat…

Bone Tissue Engineering MaterialsAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

A new targeting agent for the selective drug delivery of nanocarriers for treating neuroblastoma

Gonzalo Villaverde、Alejandro Baeza、Gustavo J. Melen 等 6 位作者2015-01-01Journal of Materials Chemistry B

Novel targeting agents against neuroblastoma based on the meta-iodobenzylguanidine (MIBG) moiety were synthesized and biologically evaluated for nanocarrier vectorization. These compounds have been anchored on the surface of drug loaded mesoporous silica nanocarriers, resulting in the improved cellular uptake in tumor…

Nanoparticle-Based Drug DeliveryNeuroblastoma Research and TreatmentsGraphene and Nanomaterials Applications

Self-assembled light-harvesting supercomplexes from fluorescent surface-cross-linked micelles

Geetika Chadha、Qing‐Zheng Yang、Yan Zhao2015-01-01Chemical Communications

Fluorescent nanoparticles made of cross-linked dansylated surfactants allowed efficient donor-donor energy migration within and beyond the nanoparticles when the nanoparticles aggregated in the presence of oppositely charged energy acceptors. The light-harvesting system enabled a single acceptor to quench the emission…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical Studies