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Thermal-insulating effect in a quantum harmonic chain with alternating masses

Leonardo Miranda Santana、Emmanuel Pereira2012-09-24Physical Review E

We present an analytical study of the heat conduction in a quantum harmonic chain of oscillators with alternate particle masses. We find that a thermal-insulating effect already observed in some classical models consisting of chains with alternate masses also holds in the quantum version of the one-dimensional harmoni…

Thermal properties of materialsQuantum, superfluid, helium dynamicsThermal Radiation and Cooling Technologies

Magnetic nanoparticles for tunable microwave metamaterials

Н. Ногинова、Quincy Williams、Panagiotis Dallas 等 4 位作者2012-09-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Commonly, metamaterials are electrically engineered systems with optimized spatial arrangement of subwavelength sized metal and dielectric components. We explore alternative methods based on use of magnetic inclusions, such as magnetic nanoparticles, which can allow permeability of a composite to be tuned from negativ…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Heterobinuclear Zn‐Ln (Ln = La, Nd, Eu, Gd, Tb, Er and Yb) complexes based on asymmetric Schiff‐base ligand: synthesis, characterization and photophysical properties

Shunsheng Zhao、Xiangrong Liu、Xingqiang Lü 等 4 位作者2012-09-24Luminescence

With a novel asymmetric Schiff-base zinc complex ZnL (H2 L = N-(3-methoxysalicylidene)-N'-(5-bromo-3-methoxysalicylidene)phenylene-1,2-diamine), obtained from phenylene-1,2-diamine, 3-methoxysalicylaldehyde and 5-bromo-3-methoxysalicylaldehyde, as the precursor, a series of heterobinuclear Zn-Ln complexes [ZnLnL(NO3 )…

Magnetism in coordination complexesRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Hydrogen Assisted Cracking Failures of Girth Welds in Oil and Gas Pipelines

W.E. Amend、G. T. Quickel、W.A. Bruce 等 4 位作者2012-09-24OpenAlex

There are more than 2.5 million miles of oil and gas pipelines in the United States, totaling over 330 million girth welds below ground. During construction, girth welds are susceptible to the formation of various defects, one of which is hydrogen-assisted cracks. The synergistic impact of tensile stress, a susceptibl…

Hydrogen embrittlement and corrosion behaviors in metalsStructural Integrity and Reliability AnalysisMaterial Properties and Failure Mechanisms

Experimental Study of Electromagnetic Heating of Gold Nanoparticle Dispersions at 200 Khz

Hui‐Jiuan Chen、Dongsheng Wen2012-09-24Nanomedicine

AIM: Remote heating of gold nanoparticles (GNPs) by low frequency electromagnetic field has been recently proposed as a potential thermal treatment for deep-seated tumors - almost all the studies were conducted on a commercial device at 13.56 MHz. This work investigates the electromagnetic heating of GNP dispersions a…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsUltrasound and Hyperthermia Applications

First principle evaluation of the chiroptical activity of the di-phenyl-diazene derivatives

Enrico Benassi、Stefano Corni2012-09-24The Journal of Chemical Physics

Azobenzene (di-phenyl-diazene) is well-known as a photoisomerisable molecule and has been widely studied as a molecular photoswitcher. Molecular rods, where di-phenyl arms are bound to the diazene moiety, have been also synthesized. In this article we explore by first principle density functional theory calculations t…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Supramolecular Networks Extended by N–H···O Interactions between Cu‐Benzimidazole Subunits and Keggin Anions

Guo‐Cheng Liu、Yufei Wang、Ai‐Xiang Tian 等 7 位作者2012-09-24Zeitschrift für anorganische und allgemeine Chemie

Abstract Three new 2D/3D supramolecular architectures derived from Cu‐organic subunits and Keggin anions, [Cu II 2 (biz) 8 (HPMo VI 10 Mo V 2 O 40 )(H 2 O) 2 ] · 2H 2 O ( 1 ), [Cu I 4 (biz) 8 (SiW 12 O 40 )] · 2H 2 O ( 2 ) and [Cu I 2 (dmbiz) 4 (Hdmbiz) 2 (SiW 12 O 40 )] ( 3 ) (biz = benzimidazole, dmbiz = 5, 6‐dimeth…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Surface Modification of Sisal Fibers Using Cellulase and Microwave-Assisted Grafting: A Study of Morphology, Crystallinity, and Thermal Stability

Susheel Kalia、Shalu Vashistha2012-09-24International Journal of Polymeric Materials

Surface modification of sisal fibers (Agave sisalana) using microwave-radiation-induced grafting and cellulase has been carried out in this paper. The modified fibers were characterized by various techniques to determine their morphology, crystallinity, and thermal stability. It has also been found that microwave-radi…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

A Model of Hydrogen Assisted Cold Cracking in Weld Metal

Andrei Kotousov、Krzysztof Borkowski、Leigh Fletcher 等 4 位作者2012-09-24OpenAlex

Due to significant cost and productivity advantages, low heat inputs, high welding speeds, severe loading conditions and the use of cellulosic electrodes in the construction of oil and gas pipelines are unavoidable in Australia. Another significant cost reduction directly related to the tonnage of steel pipe dictates…

Hydrogen embrittlement and corrosion behaviors in metalsStructural Integrity and Reliability AnalysisMaterial Properties and Failure Mechanisms

High Electromagnetic Conductance Media

R. Kästner2012-09-24IEEE Transactions on Antennas and Propagation

Conceptual doubly lossy thin layers with high electric and magnetic conductances (HEMCs) are shown to exhibit perfect absorbing properties for a normally incident plane wave. In contrast to conventional absorbers and perfectly matched layers (PMLs), this absorber can be made infinitely thin in the limit of perfect ele…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Tapered and aperiodic silicon nanostructures with very low reflectance for solar hydrogen evolution

Siah Hong Tan、Chew Beng Soh、Wei Wang 等 5 位作者2012-09-24Applied Physics Letters

We introduce a facile method to generate silicon nanostructures with superior anti-reflectance (AR) properties. These nanostructures possess the ideal tapered structure and aperiodic distribution required for low reflectance over a broad range of wavelengths. Consideration of effective medium theories might explain th…

Nanowire Synthesis and ApplicationsCopper-based nanomaterials and applicationsGa2O3 and related materials

Study on Encapsulation of Diethyl Phenyl Acetamide in Calcium-Alginate Microsphere for Enhanced Repellent Efficacy

C. Rakkiyappan、Rajbala Singh、Arpita Bhattacharya2012-09-24International Journal of Polymeric Materials

In this present study, diethyl phenyl acetamide (DEPA), a multi-insect repellent, was entrapped in a hydrophilic biodegradable polymer calcium alginate to increase its efficacy. For encapsulation, an emulsion technique followed by gelation method was adopted. Various characterizations of the formed DEPA-containing alg…

Flame retardant materials and propertiesMicroencapsulation and Drying ProcessesPlant Surface Properties and Treatments

Continued Microstructure and Mechanical Property Performance Evaluation of Commercial Grade API Pipeline Steels in High Pressure Gaseous Hydrogen

Douglas Stalheim、Todd Boggess、Darren Michael Bromley 等 5 位作者2012-09-24OpenAlex

In spite of current world economic climates, recognition that alternative energy sources to the traditional fossil fuels has to be explored and understood. One potential energy source being researched and developed is hydrogen gas. Currently the most economical method of transporting large quantities of hydrogen gas i…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsMechanical Failure Analysis and Simulation

Photoconductivity studies on amorphous and crystalline TiO2and TiO2:Eu3+thin films synthesized by sol-gel

P. Francisco-Santiago、Jorge A. García-Macedo、Guadalupe Valverde-Aguilar2012-09-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Amorphous and crystalline TiO<sub>2</sub> and TiO<sub>2</sub>:Eu<sub>3+</sub> thin films were synthesized by the sol–gel process at room temperature. The films were spin-coated on glass substrates. The samples were calcined at 400°C, 500°C for 2h to produce crystalline films. The films were characterized using X-ray d…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsTransition Metal Oxide Nanomaterials

CORROSION BEHAVIOR OF 18% Ni M250 GRADE MARAGING STEEL UNDER WELD-AGED CONDITION IN SULFURIC ACID MEDIUM

B. S. Sanatkumar、Jagannath Nayak、A. Nityananda Shetty2012-09-24Chemical Engineering Communications

The corrosion behavior of 18% Ni M250 grade maraging steel under weld-aged condition was investigated in sulfuric acid medium of different concentrations (0.1–2 M) at different temperatures (30°–60°C). Electrochemical measurements were carried out using the potentiodynamic polarization technique and electrochemical im…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Synthesis, Structure, Physical Properties, and Displacement Current Measurement of an n-Type Organic Semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone

Jinchong Xiao、Yasuo Azuma、Yi Liu 等 10 位作者2012-09-24Australian Journal of Chemistry

An n-type organic semiconductor 2:3,5:6-bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone (BDQ) has been successfully synthesised and characterised. The single crystal structure of BDQ, determined by single-crystal X-ray crystallography, indicated that BDQ is a planar molecule with strong face-to-face p-p stacking (3.40…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsOrganic and Molecular Conductors Research

Effect of Polyvinyl Alcohol on the Growth, Structure, Morphology, and Electrical Conductivity of Polypyrrole Nanoparticles Synthesized via Microemulsion Polymerization

Anurag Krishna、Amit Kumar、Rajiv K. Singh2012-09-24ISRN Nanomaterials

Polypyrrole (PPy) nanoparticles were synthesized via microemulsion polymerization technique using sodium dodecyl sulfate as surfactant. Polyvinyl alcohol (PVA) was added as soft template during polymerization to modify the structure and properties of PPy nanoparticles. The synthesized materials namely, PVA-free and PV…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Self-assembled NaNbO3-Nb2O5 (ferroelectric-semiconductor) heterostructures grown on LaAlO3 substrates

Zhiguang Wang、Yanxi Li、Bo Chen 等 6 位作者2012-09-24Applied Physics Letters

We deposited NaNbO3 (NNO)-Nb2O5 (NO) self-assembled heterostructures on LaAlO3 (LAO) to form ferroelectric-semiconductor vertically integrated nanostructures. The NNO component formed as nanorods embedded in a NO matrix. X-ray diffraction confirmed epitaxial growth of both NNO and NO phases. Phase distribution was det…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Crystal chemistry of Bi- and Mn-bearing vesuvianite from Langban, Sweden

Lee A. Groat、R. J. Evans2012-09-24American Mineralogist

Red vesuvianite crystals occur with hausmanite and calcite in a hand specimen from Långban, Sweden. Backscattered electron imaging revealed that a very few of the vesuvianite crystals exhibit cores of higher average atomic number (vesuvianite I) than the bulk (vesuvianite II). Average electron microprobe compositions…

Crystal Structures and PropertiesClay minerals and soil interactionsChemical Synthesis and Characterization

Ion Transfer Mechanisms Accompanying p-Doping of Poly(3,4-Ethylenedioxythiophene) Films in Deep Eutectic Solvents

A. Robert Hillman、Karl S. Ryder、Christopher Zaleski 等 5 位作者2012-09-24Zeitschrift für Physikalische Chemie

Abstract Redox-driven ion transfer processes accompanying p-doping and undoping were investigated for poly(3,4-ethylenedioxythiophene) (PEDOT) films. The PEDOT films were potentiostatically grown from acetonitrile solutions of monomer onto the Au electrodes of 10 MHz AT-cut quartz crystal resonators. The films were th…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors