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Designing one dimensional Co-Ni/Co3O4-NiO core/shell nano-heterostructure electrodes for high-performance pseudocapacitor

Ashutosh K. Singh、Debasish Sarkar、Gobinda Gopal Khan 等 4 位作者2014-03-31Applied Physics Letters

A high-performance supercapacitor electrode based on unique 1D Co-Ni/Co3O4-NiO core/shell nano-heterostructures is designed and fabricated. The nano-heterostructures exhibit high specific capacitance (2013 F g−1 at 2.5 A g−1), high energy and power density (23 Wh kg−1 and 5.5 kW kg−1, at the discharge current density…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Sign inversion in the superconducting order parameter of LiFeAs inferred from Bogoliubov quasiparticle interference

Shun Chi、Steven Johnston、G. Levy 等 13 位作者2014-03-31Physical Review B

Quasiparticle interference (QPI), by means of scanning tunneling microscopy/spectroscopy (STM/STS), angle-resolved photoemission spectroscopy (ARPES), and multiorbital tight-binding calculations, is used to investigate the band structure and superconducting order parameter of LiFeAs. Using this combination of techniqu…

Physics of Superconductivity and MagnetismIron-based superconductors researchSuperconductivity in MgB2 and Alloys

In Situ TEM Observations on the Sulfur-Assisted Catalytic Growth of Single-Wall Carbon Nanotubes

Lili Zhang、Peng‐Xiang Hou、Shisheng Li 等 7 位作者2014-03-31The Journal of Physical Chemistry Letters

The effect of sulfur on the catalytic nucleation and growth of single-wall carbon nanotubes (SWCNTs) from an iron catalyst was investigated in situ by transmission electron microscopy (TEM). The catalyst precursor of ferrocene and growth promoter of sulfur were selectively loaded inside of the hollow core of multiwall…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Defects in Chemically Synthesized and Thermally Processed ZnO Nanorods: Implications for Active Layer Properties in Dye-Sensitized Solar Cells

Partha Pratim Das、Shruti Agarkar、Soumita Mukhopadhyay 等 6 位作者2014-03-31Inorganic Chemistry

We have carried out the effect of post annealing temperatures on the performance of solution-grown ZnO rods as photoanodes in dye-sensitized solar cells. Keeping our basic objective of exploring the effect of native defects on the performance of DSSC, we have synthesized ZnO rods having length in the range of 2-5 μm b…

TiO2 Photocatalysis and Solar CellsZnO doping and propertiesQuantum Dots Synthesis And Properties

Effects of zeolite and vermicompost applications on potassium release from calcareous soils

Mahdi Najafi‐Ghiri2014-03-31Soil and Water Research

Zeolite and vermicompost applications to soil may improve K fertility of soils. For this purpose, these materials were added to five representative calcareous soils collected from southern Iran. The treatments included (1) control, (2) 20 g/kg zeolite, (3) 20 g/kg vermicompost, and (4) 20 g/kg vermicompost + zeolite (…

Soil and Unsaturated FlowClay minerals and soil interactionsPhosphorus and nutrient management

Macroporous Ceramics by Gelation–Freezing Route Using Gelatin

Manabu Fukushima、Yu‐ichi Yoshizawa、Tatsuki Ohji2014-03-31Advanced Engineering Materials

Abstract This paper reviews an advanced methodology for macroporous ceramic components, that can create nearly honeycomb shaped pore channels, unlike either ellipsoidal or dendritic or lamellar structures obtained via conventional freeze casting. Three main technological features have been discussed in terms of (i) ho…

Advanced ceramic materials synthesisCellular and Composite StructuresAerogels and thermal insulation

Molecular Dynamics Simulations: Insight into Molecular Phenomena at Interfaces

Sepideh Razavi、Joel Koplik、Ilona Kretzschmar2014-03-31Langmuir

Molecular dynamics simulations, when aptly devised, can enhance our fundamental understanding of a system, set up a platform for testing theoretical predictions, and provide insight and a framework for further experimental studies. This feature article highlights the importance of molecular dynamics simulations in und…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

High perpendicular magnetic anisotropy in D22-Mn3+xGe tetragonal Heusler alloy films

Atsushi Sugihara、Shigemi Mizukami、Yoko Yamada 等 5 位作者2014-03-31Applied Physics Letters

We prepared D022-Mn3+xGe (−0.67 ≤ x ≤ 0.35) epitaxial thin films on MgO(001) substrates with Cr(001) buffer layers and systematically investigated the dependence of their perpendicular magnetic anisotropy constant, saturation magnetization, coercivity, and tetragonal axial ratio (c/a) on their composition and substrat…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsHeusler alloys: electronic and magnetic properties

SERS Enhancement and Field Confinement in Nanosensors Based on Self-Organized Gold Nanowires Produced by Ion-Beam Sputtering

Cristiano D’Andrea、Barbara Fazio、P. G. Gucciardi 等 12 位作者2014-03-31The Journal of Physical Chemistry C

Since its discovery, surface-enhanced Raman spectroscopy (SERS) has pushed researchers’ interest to develop different kinds of active substrates for high sensitivity molecular detection. Defocused ion beam sputtering (IBS) represents a viable route for the production of large scale, highly reproducible SERS-active sub…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNear-Field Optical Microscopy

Magnetically coupled electromagnetically induced transparency analogy of dielectric metamaterial

Fuli Zhang、Qian Zhao、Chuwen Lan 等 7 位作者2014-03-31Applied Physics Letters

In this manuscript, we experimentally demonstrate magnetically coupled electromagnetically induced transparency (EIT) analogy effect inside dielectric metamaterial. In contrast to previous studies employed different metallic topological microstructures to introduce dissipation loss change, barium strontium titanate, a…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchQuantum optics and atomic interactions

Persistent conductive footprints of 109° domain walls in bismuth ferrite films

Igor Stolichnov、Monika Iwanowska、Enrico Colla 等 9 位作者2014-03-31Applied Physics Letters

Using conductive and piezoforce microscopy, we reveal a complex picture of electronic transport at weakly conductive 109° domain walls in bismuth ferrite films. Even once initial ferroelectric stripe domains are changed/erased, persistent conductive paths signal the original domain wall position. The conduction at suc…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Investigation of Coarse-Grained Mappings via an Iterative Generalized Yvon–Born–Green Method

Joseph F. Rudzinski、W. G. Noid2014-03-31The Journal of Physical Chemistry B

Low resolution coarse-grained (CG) models enable highly efficient simulations of complex systems. The interactions in CG models are often iteratively refined over multiple simulations until they reproduce the one-dimensional (1-D) distribution functions, e.g., radial distribution functions (rdfs), of an all-atom (AA)…

Protein Structure and DynamicsTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Directed Energy Transfer in Films of CdSe Quantum Dots: Beyond the Point Dipole Approximation

Kaibo Zheng、Karel Žídek、Mohamed Abdellah 等 8 位作者2014-03-31Journal of the American Chemical Society

Understanding of Förster resonance energy transfer (FRET) in thin films composed of quantum dots (QDs) is of fundamental and technological significance in optimal design of QD based optoelectronic devices. The separation between QDs in the densely packed films is usually smaller than the size of QDs, so that the simpl…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Solid-Phase Synthesis of Mesoporous ZnO Using Lignin-Amine Template and Its Photocatalytic Properties

Xiaohong Wang、Yike Zhang、Chen Hao 等 6 位作者2014-03-31Industrial & Engineering Chemistry Research

Nanoparticles of zinc oxide (ZnO) with high sunlight photocatalytic activity were synthesized by a solid-phase method using lignin-amine (LA) template. The prepared ZnO was characterized using UV–visible diffuse reflectance spectroscopy (UV–vis/DRS), thermogravimetric analysis/differential scanning calorimetry (TGA/DS…

ZnO doping and propertiesCatalytic Processes in Materials ScienceAerogels and thermal insulation

Deterministic Electrical Charge-State Initialization of Single Nitrogen-Vacancy Center in Diamond

Yuki Doi、Toshiharu Makino、Hiromitsu Kato 等 14 位作者2014-03-31Physical Review X

Use of nitrogen-vacancy (NV) centers in diamond for quantum applications requires fast switching between their two different charge states. Using a diamond diode, scientists now demonstrate for the first time deterministic, purely electrical, and room-temperature charge-state control of single NV centers on the time s…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Photoanode Current of Large–Area MoS2 Ultrathin Nanosheets with Vertically Mesh–Shaped Structure on Indium Tin Oxide

Xiaoyong Xu、Jingguo Hu、Zongyou Yin 等 4 位作者2014-03-31ACS Applied Materials & Interfaces

A large area of hydrothermally grown MoS2 ultrathin nanosheets (NSs) with a vertically mesh-shaped structure on indium tin oxide (ITO) substrate was directly used as the photoanode of a potoelectrochemical (PEC) cell. The photoelectrocatalytic capacity of ultrathin MoS2 NSs was demonstrated, which was attributed not o…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMXene and MAX Phase Materials

Mechanical Properties of Self-Assembled Fmoc-Diphenylalanine Molecular Gels

Nikola A. Dudukovic、Charles F. Zukoski2014-03-31Langmuir

We explore the phase diagram and mechanical properties of molecular gels produced from mixing water with a dimethyl sulfoxide (DMSO) solution of the aromatic dipeptide derivative fluorenylmethoxycarbonyl-diphenylalanine (Fmoc-FF). Highly soluble in DMSO, Fmoc-FF assembles into fibrous networks that form gels upon addi…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Stacking-dependent electronic structure of bilayer silicene

Huixia Fu、Jin Zhang、Zijing Ding 等 5 位作者2014-03-31Applied Physics Letters

Bilayer silicene (BLS) is a class of material that possibly holds both topological and superconducting properties; however, its structure is not fully understood. By scanning stacking modes and lattice constants using first principles calculations, several meta-stable configurations are identified, including a slightl…

Carbon Nanotubes in CompositesGraphene research and applicationsTopological Materials and Phenomena

Control of work function of graphene by plasma assisted nitrogen doping

Keishi Akada、Tomo‐o Terasawa、Gaku Imamura 等 5 位作者2014-03-31Applied Physics Letters

Nitrogen doping is expected to provide several intriguing properties to graphene. Nitrogen plasma treatment to defect-free and defective highly oriented pyrolytic graphite (HOPG) samples causes doping of nitrogen atom into the graphene layer. Nitrogen atoms are initially doped at a graphitic site (inside the graphene)…

Advancements in Battery MaterialsGraphene research and applicationsDiamond and Carbon-based Materials Research

RETRACTED: Potential Impact of Multi-Walled Carbon Nanotubes Exposure to the Seedling Stage of Selected Plant Species

Parvin Begum、Refi Ikhtiari、Bunshi Fugetsu2014-03-31Nanomaterials

Phytotoxicity is a significant consideration in understanding the potential environmental impact of nanoparticles. Abundant experimental data have shown that multi-walled carbon nanotubes (MWNTs) are toxic to plants, but the potential impacts of exposure remain unclear. The objective of the present study was to evalua…

Carbon Nanotubes in CompositesNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications