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Poly(ethylene terephthalate) Nanofibers Made by Sea–Island‐Type Conjugated Melt Spinning and Laser‐Heated Flow Drawing

Kazuhiro Nakata、Kenji Fujii、Yutaka Ohkoshi 等 7 位作者2007-03-16Macromolecular Rapid Communications

Abstract Nylon‐6/poly(ethylene terephthalate) (PET) ultra‐multi‐island sea–island conjugated melt‐spun fibers are flow‐drawn at a draw ratio of 174 with heating by CO 2 laser irradiation. Continuous PET nanofibers that have a diameter of 39 nm could be obtained from the flow‐drawn fiber with further drawing and remova…

Electrospun Nanofibers in Biomedical ApplicationsAdvanced Sensor and Energy Harvesting MaterialsSurface Modification and Superhydrophobicity

Order and disorder among the layered double hydroxides: combined Rietveld and DIFFaX approach

A.V. Radha、P. Vishnu Kamath、C. Shivakumara2007-03-16Acta Crystallographica Section B Structural Science

A combined approach using the Rietveld technique of structure refinement and DIFFaX simulations of the powder patterns enables us to not only arrive at the complete structure of the layered double hydroxides (LDHs), but also classify and quantify the nature of structural disorder. Hydrolysis of urea dissolved in mixed…

Layered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic ConductivityInorganic Chemistry and Materials

Ferroelectric and ferromagnetic properties of (x)BaTiO3+ (1 −x)Ni0.94Co0.01Cu0.05Fe2O4composite

Rupesh S. Devan、S B Deshpande、B.K. Chougule2007-03-16Journal of Physics D Applied Physics

A group of elastically coupled ferroelectric and ferrite composites with the general formula (x)BaTiO3 + (1−x)Ni0.94Co0.01Cu0.05Fe2 O4 (where x = 0.85, 0.70 and 0.55) was prepared by the standard ceramic reaction method. The x-ray diffraction pattern of the composite reveals a spinel phase formation for the ferrite an…

Magnetic Properties and Synthesis of FerritesFerroelectric and Piezoelectric MaterialsMultiferroics and related materials

Numerical analysis of Rayleigh–Plesset equation for cavitating water jets

Habib Alehossein、Johnny Qin2007-03-16International Journal for Numerical Methods in Engineering

Abstract High‐pressure water jets are used to cut and drill into rocks by generating cavitating water bubbles in the jet which collapse on the surface of the rock target material. The dynamics of submerged bubbles depends strongly on the surrounding pressure, temperature and liquid surface tension. The Rayleigh–Plesse…

Ultrasound and Cavitation PhenomenaCoal Combustion and Slurry ProcessingCavitation Phenomena in Pumps

Experimental and simulation investigations of acoustic cavitation in megasonic cleaning

Krishna Muralidharan、Manish Keswani、Hrishikesh Shende 等 7 位作者2007-03-16Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Extreme ultra-violet (EUV) lithography has become the technique of choice to print the ever-shrinking nanoscale features on the silicon wafer. For successful transfer of patterns on to the wafer, the EUV photomask cannot contain defects greater than 30 nm. Megasonic cleaning is a very successful cleaning technique for…

Ion-surface interactions and analysisMicrofluidic and Bio-sensing TechnologiesUltrasound and Cavitation Phenomena

Structures of three dehydration products of bischofite from in situ synchrotron powder diffraction data (MgCl2·nH2O; n = 1, 2, 4)

Kunihisa Sugimoto、Robert E. Dinnebier、Jonathan C. Hanson2007-03-16Acta Crystallographica Section B Structural Science

High-quality in situ synchrotron powder diffraction data have been used to investigate the decomposition products of bischofite in the temperature range 298 </= T </= 873 K. At least eight phases could be identified: MgCl(2).nH(2)O (n = 1, 2, 4 and 6), MgOHCl.nH(2)O (0 </= n </= 1.0), MgCl(2) and MgO. The crystal stru…

X-ray Diffraction in CrystallographyMagnesium Oxide Properties and ApplicationsMicrowave Dielectric Ceramics Synthesis

Theoretical study of electronic transport through a small quantum dot with a magnetic impurity

Mugurel Tolea、Bogdan R. Bulka2007-03-16arXiv

We model a small quantum dot with a magnetic impurity by the Anderson Hamiltonian with a supplementary exchange interaction term. The transport calculations are performed by means of the Green functions within the equation of motion scheme, in which two decoupling procedures are proposed, for high and low temperatures…

Mesoscale and Nanoscale PhysicsMaterials Science

Van der Waals density functional: Self-consistent potential and the nature of the van der Waals bond

T. Thonhauser、Valentino R. Cooper、Shen Li 等 6 位作者2007-03-16arXiv

We derive the exchange-correlation potential corresponding to the nonlocal van der Waals density functional [M. Dion, H. Rydberg, E. Schroder, D. C. Langreth, and B. I. Lundqvist, Phys. Rev. Lett. 92, 246401 (2004)]. We use this potential for a self-consistent calculation of the ground state properties of a number of…

Materials Science

Spatial Determination of Magnetic Avalanche Ignition Points

Reem Jaafar、S. McHugh、Yoko Suzuki 等 9 位作者2007-03-16arXiv

Using time-resolved measurements of local magnetization in the molecular magnet Mn12-ac, we report studies of the propagation of magnetic avalanches (fast magnetization reversals) that originate from points inside the crystals rather than at the edges. The curved nature of the fronts produced by avalanches is reflecte…

Materials Science

Comment on "Prediction of lattice constant in cubic perovskites"

Roberto L. Moreira、Anderson Dias2007-03-16arXiv

In a recent work by Jiang et al. [J. Phys. Chem. Solids 67 (2006) 1531-1536], the interrelationship between lattice constant, ionic radii and tolerance factor of cubic perovskites has been established and an empirical equation was obtained. However, the assumption of incorrect ionic coordination led to an incorrect ma…

Materials Science

Nature of the Perpendicular-to-Parallel Spin Reorientation in a Mn-doped GaAs Quantum Well: Canting or Phase Separation?

Randy S. Fishman、Fernando A. Reboredo、Alex Brandt 等 4 位作者2007-03-16arXiv

It is well known that the magnetic anisotropy in a compressively-strained Mn-doped GaAs film changes from perpendicular to parallel with increasing hole concentration $p$. We study this reorientation transition at T=0 in a quantum well with Mn impurities confined to a single plane. With increasing $p$, the angle $θ$ t…

Materials Science

Depth profile high-energy spectroscopic study of Mn-doped GaN prepared by thermal diffusion

J. I. Hwang、Y. Osafune、M. Kobayashi 等 12 位作者2007-03-16arXiv

We have performed an $in$-$situ$ depth profile study of Mn-doped GaN prepared by a low temperature thermal diffusion method using photoemission and x-ray absorption spectroscopy. It was revealed from the core-level photoemission measurements that Mn ions are diffused into a deep ($\sim$ 70 Å) region of the GaN substra…

Materials Science

Determination of optical parameters ofa-(As2Se3)90Ge10thin film

Pankaj Sharma、S. C. Katyal2007-03-16Journal of Physics D Applied Physics

A thin film of the ternary chalcogenide glassy alloy (As 2 Se 3 ) 90 Ge 10 has been deposited on a glass substrate by the thermal evaporation technique under vacuum. The optical parameters, refractive index ( n ) and extinction coefficient ( k ), have been calculated in the wavelength range 400–1500 nm by analysing th…

Phase-change materials and chalcogenidesNonlinear Optical Materials StudiesChalcogenide Semiconductor Thin Films

Automated search-model discovery and preparation for structure solution by molecular replacement

Ronan M. Keegan、Martyn Winn2007-03-16Acta Crystallographica Section D Biological Crystallography

A novel automation pipeline for macromolecular structure solution by molecular replacement is described. There is a special emphasis on the discovery and preparation of a large number of search models, all of which can be passed to the core molecular-replacement programs. For routine molecular-replacement problems, th…

Machine Learning in Materials ScienceEnzyme Structure and FunctionProtein Structure and Dynamics

Controlling Photoreactions with Restricted Spaces and Weak Intermolecular Forces: Exquisite Selectivity during Oxidation of Olefins by Singlet Oxygen

Arunkumar Natarajan、Lakshmi S. Kaanumalle、Steffen Jockusch 等 7 位作者2007-03-16Journal of the American Chemical Society

Highly regioselective photooxidation of methyl cycloalkenes has been performed in an aqueous medium by selectively blocking two of the three allylic hydrogens through supramolecular steric effect. Hydrophobic, steric, and weak intermolecular C−H−π interactions are suggested to be responsible for the specific orientati…

Porphyrin and Phthalocyanine ChemistrySupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Large inverse magnetocaloric effect in Ni50Mn34In16

V. K. Sharma、M. K. Chattopadhyay、Sthitadhi Roy2007-03-16Journal of Physics D Applied Physics

We report a study of the magnetocaloric effect in the ternary alloy system Ni 50 Mn 34 In 16 . This system undergoes an austenite–martensite phase transition, and the change in magnetic entropy is found to be quite large across this martensitic transition. This entropy change is due to an increase in entropy induced b…

Thermal Expansion and Ionic ConductivityMagnetic and transport properties of perovskites and related materialsShape Memory Alloy Transformations

Yttrium Complexes as Catalysts for Living and Immortal Polymerization of Lactide to Highly Heterotactic PLA

Abderrahmane Amgoune、C.M. Thomas、Jean‐François Carpentier2007-03-16Macromolecular Rapid Communications

Abstract Amino‐alkoxy‐bis(phenolate) yttrium complexes act in the presence of an excess of alcohol (up to 50 equiv. vs. Y) as highly active and stereoselective catalysts for rac ‐lactide and rac ‐ β ‐butyrolactone polymerizations. These versatile systems enable the production of large quantities of polymer with small…

Organometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisbiodegradable polymer synthesis and properties

Pressure on charged domain walls and additional imprint mechanism in ferroelectrics

Pavel Mokrý、A. K. Tagantsev、Jan Fousek2007-03-16Physical Review B

The impact of free charges on the local pressure on a charged ferroelectric domain wall produced by an electric field has been analyzed. A general formula for the local pressure on a charged domain wall is derived considering full or partial compensation of bound polarization charges by free charges. It is shown that…

Acoustic Wave Resonator TechnologiesFerroelectric and Piezoelectric MaterialsDielectric materials and actuators

Gadolinium Iron Garnet as a Solid State Material for an Electron Electric Dipole Moment Search

Steve K. Lamoreaux2007-03-16arXiv

The possibility of a solid state electron electric dipole moment (EDM) experiment based on Gadolinium Iron Garnet (GdIG) is investigated. GdIG appears to exhibit superparamagnetism and this effect can be used to enhance the electric-field-induced EDM signal at relatively a high temperatures, as compared to a simple pa…

physics.atom-phMaterials Sciencehep-ex

An automated microseed matrix-screening method for protein crystallization

A. D’Arcy、Frédéric Villard、M. Marsh2007-03-16Acta Crystallographica Section D Biological Crystallography

A microseed-matrix procedure has been established with the aim of influencing the nucleation event in standard crystallization screens. The method is based on the original description of matrix seeding described by Ireton & Stoddard (2004, Acta Cryst. D60, 601-605). Seed stocks are produced using a simple "seed-bead"…

Protein Structure and DynamicsEnzyme Structure and FunctionProtein purification and stability