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Watching molecules reorient in liquid crystal droplets with multiphoton-excited fluorescence microscopy

Daniel A. Higgins、Brenda J. Luther2003-08-01The Journal of Chemical Physics

A new form of time-resolved multiphoton-excited fluorescence imaging is described and used to study electric-field-induced reorientation dynamics in polymer-dispersed liquid crystal (LC) films. This method provides information on the static and dynamic LC orientation via polarization-dependent three-photon excitation…

Liquid Crystal Research AdvancementsAdvanced Fluorescence Microscopy TechniquesForce Microscopy Techniques and Applications

Laser Raman studies on compounds 7.O4O.7 and 7.O5O.7

B. Gogoi、Ayon Bhattacharjee、P. R. Alapati 等 4 位作者2003-08-01Liquid Crystals

Laser Raman studies on two compounds of the α,ω-bis(4-alkylanilinebenzylidene -4′-oxy)alkane series were carried out in the spectral regions 1140–1220 and 1550–1650 cm-1 as a function of temperature. Compounds 7.O4O.7 and 7.O5O.7, exhibit SmA and SmF phases. The structural differences between these liquid crystal dime…

Liquid Crystal Research AdvancementsMolecular spectroscopy and chiralityChemical Thermodynamics and Molecular Structure

Simulations of Electric Field Induced Lamellar Alignment in Block Copolymers in the Presence of Selective Electrodes

Andriy V. Kyrylyuk、G. J. A. Sevink、A. V. Zvelindovsky 等 4 位作者2003-08-01Macromolecular Theory and Simulations

Abstract Computer simulations have been performed for electric field induced parallel‐perpendicular lamellar phase transition in the presence of electrodes. The simulations are based on the dynamic density functional theory. Here we provide the extension of earlier work in two dimensions (2D) to three dimensions (3D).…

Polymer crystallization and propertiesBlock Copolymer Self-AssemblyMachine Learning in Materials Science

An electrochemical study of tin oxide thin film in borate buffer solutions

Raúl Dı́az、Ismael Díez‐Pérez、Pau Gorostiza 等 5 位作者2003-08-01Journal of the Brazilian Chemical Society

The electrochemical behavior of tin polycrystals in borate buffer solutions at pH 7.5 was systematically investigated using cyclic voltammetry, EC-STM and electrochemical impedance measurements. A systematic shift to more negative values of the potentials corresponding either to the major reduction peak either to the…

Corrosion Behavior and InhibitionElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Quantitative Analysis of Polyethylene Blends by Fourier Transform Infrared Spectroscopy

Marlene J. Cran、Stephen W. Bigger2003-08-01Applied Spectroscopy

The quantitative analysis of binary polyethylene (PE) blends by Fourier transform infrared (FT-IR) spectroscopy has been achieved based on the ratio of two absorbance peaks in an FT-IR spectrum. The frequencies for the absorbance ratio are selected based on structural entities of the PE components in the blend. A line…

Polymer crystallization and propertiesSpectroscopy and Chemometric AnalysesMicroplastics and Plastic Pollution

Electro‐Oxidation of Methanol and Ethanol on Poly(3,4‐Ethylenedioxythiophene) with Dispersed Pt, Pt + Sn, and Pt + Pb Particles

S. Białłozór、A. Kupniewska、V. Jasulaitenė2003-08-01Fuel Cells

Abstract The influence of tin and lead additives on the catalytic activity of platinum particles dispersed on a poly(3,4‐dioxyethylenethiophene) (PEDT) layer deposited on gold or steel towards anodic oxidation of methanol and ethanol was studied. It was found that these additives increase the rate of anodic oxidation…

Electrocatalysts for Energy ConversionConducting polymers and applicationsElectrochemical Analysis and Applications

Influence of the inoculation process, the chemical composition and the cooling rate, on the solidification macro and microstructure of ductile iron

G. Rivera、R. Boeri、J. Sikora2003-08-01International Journal of Cast Metals Research

The solidification structure of any casting has a marked influence on its final microstructure and properties. Nevertheless, the correlation between solidification structure, microstructure and properties has not been clearly established for ductile irons.The objective of this investigation is to study the influence o…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Si-DEFICIENT, OH-SUBSTITUTED, BORON-BEARING VESUVIANITE FROM THE WILUY RIVER, YAKUTIA, RUSSIA

Evgeny V. Galuskin、Irina O. Galuskina、Maciej Sitarz 等 4 位作者2003-08-01The Canadian Mineralogist

Une variete de vesuvianite deficitaire en Si, formee a basse temperature, fait partie d'un amas tetraedrique de hibschite forme par pseudomorphose (achtarandite) le long des rives de la riviere Wiluy, en Yakoutie, Russie, la localite-type du grossulaire et de la wiluite. La substitution de (H 4 O 4 ) 4 - au (SiO 4 ) 4…

Crystal Structures and PropertiesClay minerals and soil interactionsMineralogy and Gemology Studies

Influence of shed parameters on the aging performance of silicone rubber insulators in salt-fog

Ayman El‐Hag、Shesha Jayaram、E.A. Cherney2003-08-01IEEE Transactions on Dielectrics and Electrical Insulation

The paper presents the results of a study on the effect of shed design on the aging performance of silicone rubber (SIR) insulators in salt-fog. The experiments on a single shed design at 35 V/mm average stress and 0.25 S/m salt-fog conductivity level are reported. Shed diameter, location and inclination angle are the…

High voltage insulation and dielectric phenomenaElectrical Fault Detection and ProtectionThermal Analysis in Power Transmission

Corrosion behaviour of iron and AISI 304 stainless steel in tungstate aqueous solutions containing chloride

Denise Schermann Azambuja、Emilse M.A. Martini、Iduvirges L. Müller2003-08-01Journal of the Brazilian Chemical Society

The corrosion behavior of iron and AISI 304 stainless steel in aqueous tungstate solutions containing chloride ion was investigated by cyclic voltammetry, open circuit measurements and impedance spectroscopy. The obtained results point out that the inhibitive performance of tungstate depends on the presence of dissolv…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Synthesis and Characterization of the Au11 Cluster with Sterically Demanding Phosphine Ligands by Single Crystal X-ray Diffraction and XPS Spectroscopy

K. Nunokawa、Satoru Onaka、Tadashi Yamaguchi 等 6 位作者2003-08-01Bulletin of the Chemical Society of Japan

Abstract A new Au11 cluster with (m-CF3C6H4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substit…

Organometallic Complex Synthesis and CatalysisRadioactive element chemistry and processingNanocluster Synthesis and Applications

A kinetic model of the oxidative dissolution of brannerite, UTi2O6

B.S. Thomas、Y. Zhang2003-08-01Radiochimica Acta

Summary The aqueous dissolution of synthetic brannerite (UTi 2 O 6 ) in an open atmosphere has been investigated. Previous data in the literature have been combined with new experimental work, dealing with the release of uranium from brannerite as a function of solution pH and aqueous carbonate species, in oxygenated…

Radioactive element chemistry and processingNuclear materials and radiation effectsChemical Synthesis and Characterization

Poly(vinyl alcohol)‐Encapsulated Hydrophilic Carbon Black Nanoparticles Free from Aggregation

Hanying Li、Hongzheng Chen、Jing‐Zhi Sun 等 6 位作者2003-08-01Macromolecular Rapid Communications

Abstract Carbon black (CB) nanoparticles were encapsulated by poly(vinyl alcohol) (PVA) by a simple method of coacervation. Transmission electron microscopy (TEM) images clearly demonstrated that the successful encapsulation of PVA happened at the surfaces of CB nanoparticles. The particle‐size distribution measuremen…

Polymer Nanocomposites and PropertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation

Thermo and mechanoluminescence of Dy3+ activated K2Mg2(SO4)3 phosphor

Ashis Kumar Panigrahi、S. J. Dhoble、R. S. Kher 等 4 位作者2003-08-01physica status solidi (a)

A solid state diffusion method for the preparation of (K2 : Dy)Mg2(SO4)3 and (K2 : Dy,P)Mg2(SO4)3 phosphors is reported. Thermoluminescence (TL) and mechanoluminescence (ML) characteristics are studied. TL, shown by the (K2 : Dy,P)Mg2(SO4)3 phosphor is 60% as intense as the conventional CaSO4 : Dy phosphor used in the…

Luminescence Properties of Advanced MaterialsSolid-state spectroscopy and crystallographybioluminescence and chemiluminescence research

Monte Carlo Study of Heteroarm Star Copolymers in Good and Selective Solvents

Jitka Havránková、Zuzana Limpouchová、Karel Procházka2003-08-01Macromolecular Theory and Simulations

Abstract Lattice Monte Carlo simulations of conformations of hereroarm star copolymers A n B n in selective solvents were performed using a special variant of the Siepman and Frenkel algorithm. The effects of solvent quality, the number and lengths of blocks on the collapse of the insoluble block A, segregation of the…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

High‐Temperature Strength of Sinter‐Forged Silicon Nitride with Lutetia Additive

Naoki Kondo、Masahiro Asayama、Yoshikazu Suzuki 等 4 位作者2003-08-01Journal of the American Ceramic Society

A sinter‐forging technique was successfully applied to fabricate a silicon nitride with a lutetia (Lu 2 O 3 ) additive. The sinter‐forged specimen had a strongly anisotropic microstructure where rodlike silicon nitride grains preferentially aligned perpendicular to the forging direction. The specimen exhibited superio…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsMXene and MAX Phase Materials

Rotman lens with equal height of array and feed contours

P. K. Singhal、Priyanka Sharma、Rakesh Gupta2003-08-01IEEE Transactions on Antennas and Propagation

The design of a compact Rotman (1963) type lens for wide angle scanning has been proposed. Equations to design the lens have been derived. The lenses designed using the proposed approach have been analyzed using the contour integral approach. Results of the analysis are in close agreement with the designed value.

Microwave Engineering and WaveguidesAdvanced optical system designOptical Coatings and Gratings

Evaluation of readily available nonexchangeable potassium in soil by sequential extractions with 0.01 molar hydrochloric acid

Naoki Moritsuka、Junta Yanai、Ayane Fujii 等 5 位作者2003-08-01Soil Science & Plant Nutrition

Nonexchangeable potassium (K-ne), i.e. 1 M NH4OAc-nonexchangeable K, often contributes significantly to plant nutrition. However conventional extraction methods often extract much more K-ne than plants even after intensive cropping, suggesting the difficulty in evaluating the amount of readily available soil K-ne. In…

Groundwater and Isotope GeochemistrySoil and Unsaturated FlowClay minerals and soil interactions

Characterization of eva-based adhesives containing different amounts of rosin ester or polyterpene tackifier

María Luisa Barrueso-Martínez、Teresa del Pilar Ferrándiz-Gómez、Marı́a D. Romero-Sánchez 等 4 位作者2003-08-01The Journal of Adhesion

Different amounts (50-170 php--parts per hundred parts of EVA, 33-63 wt%) of two tackifiers (hydrogenated rosin ester, polyterpene resin) were added to an ethylene vinyl acetate (EVA) copolymer containing 28 wt% vinyl acetate. The EVA and the tackifier were characterized using infrared (IR) spectroscopy, DSC measureme…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes