Materials Literature
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We report the design and simulation results of an adaptive GRIN lens based on multi-electrode addressed blue phase liquid crystal. A high dielectric constant layer helps to smoothen out the horizontal electric field and reduce the operating voltage. Such a GRIN lens is insensitive to polarization while keeping parabol…
Monohydrocalcite (CaCO(3)·H(2)O: MHC) is similar in composition and synthetic conditions to hydrated amorphous calcium carbonate (ACC), which is focused recently as a key intermediate compound of biomineralization and biomimetic mineralization of calcium carbonate polymorphs. Detailed comparisons of the physicochemica…
Changes in mechanical and physical properties of polyurethane thermoplastic during aging at 70 °C and 90 °C were investigated. The loss weight response was analyzed by gravimetric measurements under these temperatures. Changes in appearance and morphology of TPU after thermal aging were revealed by optical microscopy.…
A model metal–semiconductor–molecule–metal assembly has been designed for probing the charge-transfer (CT) mechanism of surface-enhanced Raman scattering (SERS). We measured the SERS of ZnO–PATP–Ag, Au–ZnO–PATP–Ag, and Cu–ZnO–PATP–Ag assemblies at excitation wavelengths of 514.5, 785, and 1064 nm. Our results demonstr…
The extreme sensitivity of circularly polarized luminescence (CPL) to long-range excitonic interactions inside a helical aggregate is investigated. It is found to persist even in the presence of strong energetic disorder and coupling of the exciton to molecular vibrations, when the emitting exciton is localized to onl…
Silver nanoparticles (AgNP) are components of various food industry products and are frequently used for medical equipment and materials. Although such particles enter the vertebrate brain, little is known on their biocompatibility for brain cells. To study the consequences of an AgNP exposure of brain cells we have t…
Ferromagnetic cobalt-doped indium oxide, (In${}_{1\ensuremath{-}x}$Co${}_{x}$)${}_{2}$O${}_{3}$, thin films with $x$ between 1.6% and 8.1% have been studied by x-ray, magnetic, and optical methods. Evidence gathered from x-ray diffraction and x-ray absorption fine-structure studies suggest that the Co atoms are substi…
The multiple functional groups and unique two-dimensional (2D) morphology make chemically modified graphene (CMG) an ideal template for the construction of 2D nanocomposites with various organic/inorganic components. Additionally, the recovered electrical conductivity of CMG may provide a fast-electron-transport chann…
This study focuses on the electrical characteristics of nematic liquid crystals doped with anatase titania nanoparticles (NPs). Low-frequency dielectric spectroscopy between 10 −2 and 10 3 Hz is used to investigate the space-charge polarization. The results indicate that the doped samples have lower ionic concentratio…
The structure of the superconducting order parameter in the iron-pnictide superconductor BaFe${}_{2}$(As${}_{0.67}$P${}_{0.33}$)${}_{2}$ (${T}_{c}=31$ K) with line nodes is studied by the angle-resolved thermal conductivity measurements in a magnetic field rotated within the basal plane. We find that the thermal condu…
We develop a phase field crystal model for structural transformations in two-component alloys. In particular, the interactions between components are described by direct correlation functions that are an extension of those introduced by Greenwood et al. [Phys. Rev. Lett. 105, 045702 (2010)] for pure materials. These c…
We analyzed the size effect of spin-crossover transition nanoparticles in a two-dimensional core-shell model, where the edge atoms are constrained to the high-spin (HS) state. Using Monte Carlo (MC) simulations, we showed that this specific edge effect lowers the equilibrium temperature and enhances the HS residual at…
Based on classical molecular dynamics simulations, we discuss the impact of Coulombic interactions on a comprehensive set of properties of room temperature ionic liquids (RTILs) containing 1,3 dimethylimidazolium (MMIM+), N butylpyridinium (BPY+), and bis(trifluoromethane sulfonyl)imide (TFSI-) ions. Ionic transport i…
The band structures of pure and hole doped La$_2$CuO$_4$ with antiferromagnetic (AFM) spin-fluctuations are calculated and compared to spectral weights of ARPES. It is shown that observations of coexisting Fermi surface (FS) arcs and closed FS pockets are consistent with modulated AFM spin fluctuations of varying wave…
We examined the magnetic properties of the square-lattice antiferromagnets CeMnAsO and LaMnAsO and their solid solutions La1-xCexMnAsO by resistivity, magnetic susceptibility, and heat capacity measurements below room temperature. A first-order phase transition is observed at 34.1 K, below which the ground-state doubl…
The effect of the doping of rare earth Gd(3+) ions replacing Nd(3+) in Nd(0.7)Sr(0.3)MnO(3) is investigated in detail. Measurements of resistivity, magnetoresistance, magnetization, and linear and nonlinear ac magnetic susceptibility on chemically synthesized (Nd(0.7-x)Gd(x))Sr(0.3)MnO(3) show various interesting feat…
We report superconductivity in novel iron-based compounds Ca10(PtnAs8)(Fe2-xPtxAs2)5 with n = 3 and 4. Both compounds crystallize in triclinic structures (space group P-1), in which Fe2As2 layers alternate with PtnAs8 spacer layers. Superconductivity with a transition temperature of 38 K is observed in the n = 4 compo…
This is the first textbook describing crystal structure determination (especially inorganic) from high-resolution transmission electron microscopy (HRTEM) and electron diffraction (ED). The theoretical background and practical procedures are explained with hundreds of figures. The fundamental fact that the crystallogr…
Surface plasmon resonances generated in metallic nanostructures can be utilized to tailor electromagnetic fields. The precise spatial arrangement of such structures can result in surprising optical properties that are not found in any naturally occurring material. Here, the designed activity emerges from collective ef…
The breakup of alkaline glass and alumina plates due to planar impacts on one of their lateral sides is studied. Particular attention is given to investigating the spatial location of the cracks within the plates. Analysis based on a phenomenological model suggests that bifurcations along the cracks' paths are more li…