Materials Literature
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The Oberst Beam Method is widely used for the measurement of the mechanical properties of damping materials. This method is a classical method based on a multilayer cantilever beam which consists of a base beam and one or two layers of other materials. The base beam is almost always made of a lightly damped material s…
Reaction between EuCl(2) and 2,2'-bipyrimidine (bpm) in de-oxygenated water afforded a cationic molecular complex [EuCl(bpm)(2)(H(2)O)(4)][Cl]·H(2)O (1). When performed in an organic solvent such as THF or methanol, the same reaction yielded a 3-dimensional coordination polymer of formula [EuCl(2)(bpm)(MeOH)(0.5)](∞)…
Co(II), Ni(II), and Cu(II) complexes with a tetradentate nitrogen donor [N4] macrocyclic ligand, viz 1,5,8,13-tetraaza-2,9-dimethyl-4,11- diphenylcyclotetradeca-2,4,4,11-tetraene were synthesized. Their structures were determined based on elemental analyses; molar conductance and magnetic susceptibility measurements;…
Tricarbonylchloro-rhenium(i) (1-4) and catecholato-platinum(ii) complexes (6, 7) of diimine ligands bearing phenol and O-protected phenol substituents have been prepared and fully characterised including single crystal structure analyses of 1, 4 and 7. The redox behaviour of the catecholato platinum(ii) complexes 6 an…
Gold decahedra and triangular plates of small size (30 and 50 nm, respectively) were grown by a green one-step synthesis process of HAuCl4 in the presence of citric acid and amphiphilic copolymer Tetronic T904® (from BASF), which both act as reducing and stabilizing agents. Tetronic T904® is a star-shaped copolymer co…
The hexanuclear cages [Mn(6)O(2)(R-sao)(6)L(2)(EtOH)(x)(H(2)O)(y)] "Mn(6)" behave as single-molecule magnets (SMMs) below a characteristic blocking temperature. As with [Mn(12)O(12)(O(2)CR)(16)(H(2)O)(4)] "Mn(12)" the electronic absorption spectra are rather featureless, yielding little information on the electronic s…
Two novel cyclic phosphazenes with asymmetric spiro rings were synthesized via reactions of hexachlorocyclotriphosphazene with chiral amino alcohol residues. The reactions showed preferential formation of the cis isomer possibly due to the delocalization of the lone pair electrons of the spirocylic nitrogen, which red…
In this paper, we study nonisothermal two-component (air and vapor) fluid flow through a porous textile medium with phase change, which is described by a degenerate and strongly coupled parabolic system. We prove global existence of weak solutions to the heat-air-vapor system and the positivity/nonnegativity of soluti…
Preparation of polystyrene (PS)-montmorillonite nanocomposites was carried out in 3 steps: purification and determination of the cation exchange capacity (CEC) of clay, synthesis of organoclay, and preparation of nanocomposites. In organoclay synthesis, 3 types of surfactants, long-chained (cetyltrimethylammonium brom…
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In order to apply ultra-high strength steel sheets with tensile strength of 980MPa or higher to automobiles, it is necessary to ensure the safety of steel parts against hydrogen embrittlement (HE). HE is influenced by hydrogen content and stress and strain introduced in parts by various forming processes. In this pape…
Hollow microcapsules made of biodegradable polymers have attracted considerable attention as ultrasound contrast agents and carriers in drug delivery systems (DDSs). A hollow polyelectrolyte microcapsule is one of the promising candidates for such applications. Hollow polyelectrolyte microcapsules are normally fabrica…
Under microwave radiation, Ag(+)-doped CdS semiconductor nanocrystals with high photoluminescence quantum yield (approximately 58%) and a surprisingly large optical window (480 to 630 nm) are formed controllably using a center-doping strategy and are optimized through a green approach in pure water solution.
Silver–copper alloys have been proposed as catalysts for ethylene epoxidation due to their superior selectivity compared to pure silver, the predominant catalyst for this reaction. Under reaction conditions it has been previously shown that, rather than a two-dimensional (2D) Ag–Cu alloy, a thin copper oxide-like laye…
A perfect two-way shape memory effect (TWSME) with reversible strain of about 9% has been found in the high-temperature Ni57.5Mn22.5Ga20.0 single crystal transforming into 2M non-modulated martensitic phase. Two thermal/mechanical treatment routes were utilized in the experimental procedures. The outstanding high-temp…
The explosive growth of nanotechnology in the last years has led to dramatic innovations in pharmacology, and it is revolutioning the development of biologically active compounds. Carbon nanotubes (CNTs) are widely explored for biomedical applications such as intracellular transporters for (bio)molecules, and represen…
This review paper presents status of research activity of plasma facing materials, mostly tungsten and critical issues towards DEMO reactors. A helium effect on tungsten surface morphology and its impact on fusion reactors and a pulsed heat effect to tungsten are briefly summarized. For DEMO, effects of steady-state o…
Imine-containing bridging groups were formed during self-assembly of periodic mesoporous organosilicas by in situ dynamic covalent chemistry of aldehyde and amine groups in the presence of poly(ethylene oxide)-poly(dl-lactic acid-co-glycolic acid)-poly(ethylene oxide) block copolymer in acidic aqueous solutions.
Two new cardenolide monoglycosides, cardenolides B-1 (1) and B-2 (2) were isolated from Nerium oleander, together with oleagenin (3) which is the first isolated compound from natural sources. The structure of compounds 1-3 were established on the basis of their spectroscopic data.