Materials Literature
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Magnetic Ru-capped/FeCo nanoflowers are solvothermally synthesised through a self-catalytic growth and assembly process. The synthesised Ru-capped/FeCo nanoflowers (∼3.63 μm) consist of Ru-capped FeCo nanorods with an average diameter of ∼13 nm and a length ranging from 1.33 to 2.1 μm. A vibration sample magnetometer…
Here we describe a new method for the direct patterned synthesis of graphene meshes on Cu foils that use self-assembled silica sphere arrays as growth masks. Structural analyses based on electron microscopy and Raman spectroscopy showed that the graphene meshes are mostly single- or double-layer necks with empty holes…
We present the results of high-field magnetization and muon-spin relaxation measurements on the coordination polymer CuF${}_{2}$(H${}_{2}$O)${}_{2}$(pyrazine) in pressures up to 22.5 kbar. We observe a transition from a quasi-two-dimensional to a quasi-one-dimensional antiferromagnetic phase at 9.1 kbar, driven by a r…
The upconversion properties of Tm3+ and Yb3+ codoped CaSc2O4 phosphor excited at 980 nm are reported. The blue emission of Tm3+:1G4 → 3H6, red emission of Tm3+:1G4 → 3F4, near-infrared emissions of Tm3+:3H4 → 3H6 (800 nm) and 3F4 → 3H6 (1600 nm) are observed when excited Yb3+:2F5/2 level. The spectral properties of Yb…
This study focuses on the investigation of the influence of the ionic strength on the internal structure, film forming behavior, and swelling properties of polyelectrolyte/clay multilayers. Layer-by-layer films were prepared with three different polyelectrolytes [polyethylenimine (PEI), polydiallyldimethylammoniumchlo…
X-ray crystallography is the method of choice to deduce atomic resolution structural information from macromolecules. In recent years, significant investments in structural genomics initiatives have been undertaken to automate all steps in X-ray crystallography from protein expression to structure solution. Robotic sy…
BshB, a key enzyme in bacillithiol biosynthesis, hydrolyses the acetyl group from N-acetylglucosamine malate to generate glucosamine malate. In Bacillus anthracis, BA1557 has been identified as the N-acetylglucosamine malate deacetylase (BshB); however, a high content of bacillithiol (~70%) was still observed in the B…
The influence of the iron content on the magnetic, polar, and magnetoelectric properties of Ga 2– x Fe x O 3 ( x = 1.0; x = 1.4) polycrystalline samples was studied by a combined magnetic (SQUID) and structural (X-ray and temperature-dependent neutrons diffraction) study. As expected, the samples showed a ferrimagneti…
In this paper, 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) was synthesized and used as solvent to dissolve bamboo pulp. Dimethylsulfoxide (DMSO) was selected as cosolvent to adjust the solution viscosity. As compared with the bamboo pulp/[Bmim]Cl system, the addition of DMSO decreases the solution viscosity dramat…
A series of cholesterol-/estradiol-appended alkynylplatinum(II) complexes with tridentate N-donor ligands, based on 2,6-bis(1-alkylpyrazol-3-yl)pyridine, has been synthesized and characterized by (1)H NMR spectroscopy, FAB-mass spectrometry, and elemental analysis. Their photophysical properties have also been investi…
ABSTRACT Nanoporous or mesoporous structures and hence a decrease in dielectric constant can always be induced with the introduction of air into polymeric materials. It is therefore achievable to prepare ultra‐large‐scale integrated circuit (ULSIC) on ultralow dielectric constant (i.e., low‐ k ) materials. The researc…
In a world with ever decreasing natural reserves, researchers are striving to find sustainable methods of producing components for technology. Bioinspired, biokleptic and biomimetic materials can be used to form a wide range of technologically relevant materials under environmentally friendly conditions. Here we inves…
Abstract A superhydrophobic textile for biomedical applications is designed using chitosan‐based hydrophobic nanoparticles. The fabrication of nanoparticles is based on the electrostatic interaction between the amine group of chitosan and the negatively charged fluoroanion. The coating is formed by spraying the nanopa…
ABSTRACT Air‐stable copper catalysts supported by bis‐ BTP ligands ( BTP = N,O ‐bidentate benzotriazole phenoxide) were synthesized and structurally characterized. The reactions of Cu(OAc) 2 ·H 2 O with 2.0 molar equivalents of sterically bulky 2‐(2H‐benzotriazol‐2‐yl)‐4,6‐bis(1‐methyl‐1‐phenylethyl)phenol ( CMe2Ph BT…
The initial growth of the nacreous layer is crucial for comprehending the formation of nacreous aragonite. A flat pearl method in the presence of the inner-shell film was conducted to evaluate the role of matrix proteins in the initial stages of nacre biomineralization in vivo. We examined the crystals deposited on a…
The understanding of radiation-induced strengthening in ferritic FeCr-based steels remains an essential issue in the assessment of materials for fusion and fission reactors. Both early and recent experimental works on Fe-Cr alloys reveal Cr segregation on radiation-induced nanostructural features (mainly dislocation l…
Graphene nanoribbons (GNRs) would be the ideal building blocks for all carbon electronics; however, many challenges remain in developing an appropriate nanolithography that generates high-quality ribbons in registry with other devices. Here we report direct and local fabrication of GNRs by thermochemical nanolithograp…
The study of the spectral-luminescence parameters of LaPO4-Eu and LaPO4-Pr nanoparticles upon excitation by the synchrotron radiation with photon energies 4–40 eV was performed. The differences of the luminescence intensity dependence on the size for LaPO4-Eu and LaPO4-Pr nanoparticles excited at the range of matrix t…
The gold standard for treatment of advanced heart valve disease is surgical heart valve re‐ placement. None of the currently available mechanical and bioprosthetic heart valve substi‐ tutes resembles normal heart valve function. While mechanical heart valves offer excellent durability, they require life-long anticoagu…
Self‐healing is receiving increasing interest worldwide as a technology to autonomously address the effects of damage in composite materials. This article relates to a self‐healing composite exhibiting high levels of healing efficiency under working conditions typical of aeronautic materials. The self‐healing material…