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Mechanochemistry of lithium nitride under hydrogen gas

Zhinian Li、Junxian Zhang、Shiping Wang 等 7 位作者2015-01-01Physical Chemistry Chemical Physics

Hydrogen uptake during the mechanochemistry of lithium nitride under 9 MPa hydrogen pressure has been analyzed by means of in situ solid-gas absorption and ex situ X-ray diffraction (XRD) measurements. In situ hydrogenation curves show two H-sorption steps leading to an overall hydrogen uptake of 9.8 wt% H after 3 hou…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionInorganic Chemistry and Materials

Wrinkling Behaviour of Annular Graphynes under Circular Shearing Load Using Molecular Dynamics Simulations

Kunhai Cai、Zheng Li、Kunhai Cai2015-01-01Nanomaterials and Nanotechnology

Graphyne, a novel carbon allotrope, is a two-dimensional lattice of sp2+ sp1 hybridization-type carbon atoms, similar to graphene. The initiation and development of wrinkles in single-layer graphynes ( α-, β-, γ-, and 6, 6, 12-graphyne) subjected to in-plane circular shearing are investigated. In comparison with graph…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvanced Materials and Mechanics

Three-dimensional ZnO porous films for self-cleaning ultraviolet photodetectors

Yuanzhi Cao、Sunbin Deng、Qiyi Hu 等 7 位作者2015-01-01RSC Advances

Three-dimensional (3D) ZnO porous films composed of an interconnected skeleton were fabricated successfully through atomic layer deposition method using carbon nanoparticles as template.

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

A Scanning Kelvin Probe Investigation of the Interaction of PEDOT:PSS Films with Metal Surfaces and Potential Corrosion Protection Properties

Carol Frances Glover、James McGettrick、G. Williams 等 5 位作者2015-01-01Journal of The Electrochemical Society

The study of conducting polymers (CPs) is of high current interest due to their wide application in a range of optical and electronic devices. Poly(3,4-Ethylenedioxythiophene)-Poly(Styrene Sulfonate) (PEDOT:PSS) is considered one of the most electrochemically and thermally stable CPs currently available. In many appli…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Photo-induced surface encoding of gold nanoparticles

Lukas Stolzer、Alexander S. Quick、Doris Abt 等 9 位作者2015-01-01Chemical Communications

Photoreactive gold nanoparticles (NP) can be encoded in a spatially resolved fashion using direct laser writing techniques into variable patterns. The surface of the gold nanoparticles is imparted with photoreactivity by tethering photo-caged dienes ('photoenols'), which are able to undergo a rapid Diels-Alder cycload…

Gold and Silver Nanoparticles Synthesis and ApplicationsPhotonic Crystals and ApplicationsNanofabrication and Lithography Techniques

The effect of nanocrystalline silicon host on magnetic properties of encapsulated iron oxide nanoparticles

Petra Granitzer、Klemens Rumpf、Roberto González-Rodríguez 等 5 位作者2015-01-01Nanoscale

The purpose of this work is a detailed comparison of the fundamental magnetic properties of nanocomposite systems consisting of Fe3O4 nanoparticle-loaded porous silicon as well as silicon nanotubes. Such composite structures are of potential merit in the area of magnetically guided drug delivery. For magnetic systems…

Magnetic Properties and Synthesis of FerritesSilicon Nanostructures and PhotoluminescenceIron oxide chemistry and applications

Carbon dot grafted SrAl 2 O 4 :Eu,Dy dual-emitting phosphor for ratiometric temperature sensing

Bingfu Lei、Wei Li、Haoran Zhang 等 7 位作者2015-01-01RSC Advances

We incorporated carbon dots (CDs) into a SrAl 2 O 4 :Eu,Dy phosphor (SAO), and made use of the dual emission from the CDs and SAO within such a composite to realize ratiometric temperature sensing from 100 to 400 K.

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsCarbon and Quantum Dots Applications

Laser irradiation-induced modification of the amorphous phase in GeTe films: the role of intermediate Ge–Te bonding in the crystallization mechanism

Seung‐Jong Park、Hanjin Park、Moon Hyung Jang 等 10 位作者2015-01-01Journal of Materials Chemistry C

Modified amorphous GeTe was analyzed in terms of variations in the local bonding structure. Inducstion of intermediated Ge–Te bonding in modified structure critically affects the phase change process.

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Transient dynamics of magnetic Co–graphene systems

Bin Wang、Jianwei Li、Fuming Xu 等 6 位作者2015-01-01Nanoscale

We report the investigation of response time of spin resolved electron traversing through a magnetic Co-graphene nano-device. For this purpose, we calculate the transient current under a step-like upward pulse for this system from first principles using non-equilibrium Green's function (NEGF) formalism within the fram…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Direct Gold Plating Selectively on UV Modified Polymer Film Using Tiopronin-Gold

Hitoshi Endo、Katsuhiko TASHIRO、Hengyi Ma 等 9 位作者2015-01-01Journal of The Electrochemical Society

An economic and low toxicity gold plating process for bio-compatible device fabrication was investigated. A tiopronin-gold complex altered by mercaptothiodiazole or mercaptotriazole derivatives gave a form of the complex that could be reduced autocatalytically to enable electroless gold plating. Catalytic ca. 5 nm gol…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsNeuroscience and Neural Engineering

Carrier transport in quantum dot quantum well microstructures of the self-assembled CdTe/CdS/ligand core–shell system

K. Y. Li、Qingsong Shan、Ruiping Zhu 等 6 位作者2015-01-01Nanoscale

The study on the quantum dot quantum well (QDQW) microstructure modified by choosing different ligands containing a sulfhydryl group is of significance because it enables one to regulate photoexcited free charge carriers' (FCCs') transport behaviours in high-quality CdTe/ligand QDs via a self-assembled way. The photoe…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Unexpected thermal decomposition behavior of poly(N-vinylimidazole)-l-poly(tetrahydrofuran) amphiphilic conetworks, a class of chemically forced blends

Csaba Fodor、János Bozi、Marianne Blazsó 等 4 位作者2015-01-01RSC Advances

The underlying chemical processes of the unexpected thermal decomposition behavior of poly( N -vinylimidazole)- l- poly(tetrahydrofuran) amphiphilic conetworks were investigated by thermogravimetric analysis and thermogravimetry-mass spectrometry.

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesSynthesis and properties of polymers

Gold nanostars co-coated with the Cu( ii ) complex of a tetraazamacrocyclic ligand

Piersandro Pallavicini、Claire Bernhard、Giuseppe Chirico 等 8 位作者2015-01-01Dalton Transactions

The twelve-membered tetraazamacrocyclic ligand L1 bears an appended lipoic acid unit, whose disulphide ring is an efficient grafting moiety for the surface of gold nanostars (GNS). The GNS that were used featured a localized surface plasmon resonance (LSPR) absorption at ∼800 nm, i.e. in the near infrared (NIR). We in…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applications

Specific targeting of A54 homing peptide-functionalized dextran-g-poly(lactic-co-glycolic acid) micelles to tumor cells

Yongzhong Du、Jun-Qing Situ、Yi-Qing Ye 等 8 位作者2015-01-01International Journal of Nanomedicine

The delivery of chemotherapeutics into tumor cells is a fundamental knot for tumor-target therapy to improve the curative effect and avoid side effects. Here, A54 peptide-functionalized poly(lactic-co-glycolic acid)-grafted dextran (A54-Dex-PLGA) was synthesized. The synthesized A54-Dex-PLGA self-assembled to form mic…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryNanoplatforms for cancer theranostics

Long- and short-range structure studies of KBT-KBZ solid-solutions using synchrotron radiation

Samuel Liu、Peter E. R. Blanchard、Zhaoming Zhang 等 5 位作者2015-01-01Dalton Transactions

The relaxor ferroelectric K(0.5)Bi(0.5)TiO(3) has been synthesised in a solid-solution series with K(0.5)Bi(0.5)ZrO(3), as K(0.5)Bi(0.5)Ti1-xZrxO(3). High-resolution synchrotron X-ray powder diffraction and X-ray absorption near edge structure spectroscopy were used to characterise the long-range average and local str…

Ferroelectric and Piezoelectric MaterialsCrystal Structures and PropertiesInorganic Chemistry and Materials

High-cycle fatigue behavior of beta-titanium orthodontic wires

Takashi Murakami、Masahiro Iijima、Takeshi Muguruma 等 6 位作者2015-01-01Dental Materials Journal

This study investigated high-cycle fatigue behavior in three β-Ti wires (TMA, Resolve, Gummetal). Fatigue was evaluated using a static three-point bending test and a high-cycle fatigue test with a three-point bending mode. The surfaces of fractured wires were observed with scanning electron microscopy, and the post-fa…

Orthopaedic implants and arthroplastyWelding Techniques and Residual StressesTitanium Alloys Microstructure and Properties