Materials Literature
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Abstract The present study concerns the electrochemical synthesis of basic copper carbonate nanoparticles by oxidation of metallic copper on the anode in an aqueous bicarbonate solution. This simple and one-step preparation can be considered as green synthesis. The scanning electron microscopy (SEM) analysis indicates…
Dense Ce 0.8 Pr 0.2 O 2−δ ceramic membranes with submicron grain size can be formed at 1000 °C by minor additions of cobalt oxide. X-ray energy-dispersive spectroscopy shows the additive to be located in the grain boundary. Although a very fine grain interface is obtained for the composition containing 2 mol % cobalt…
Motivated by recently reported chirality-dependent mechanical phenomena of small-radius carbon nanotubes, an anisotropic elastic shell model is developed in the present paper for small-radius single-walled carbon nanotubes. Due to curvature-derived elastic anisotropy, small-radius single-walled carbon nanotubes are be…
Novel hierarchical ZnO−Ga 2 O 3 nanostructures were fabricated via a two stage growth process. Nanowires of Ga 2 O 3 were obtained in the first stage by the vapor−liquid−solid mechanism and used as the foundation for growth of self-assembled, ordered arrays of ZnO nanostructures during the second stage by the vapor−so…
A cyanide-linked Ru(III)(4d)-Mn(III)(3d) bimetallic chain complex (1) was prepared by the self-assembly of a ruthenium(III) bicyanide and a Mn(III) Schiff base. Ferromagnetic couplings between the magnetic centers are present within a chain, while antiferromagnetic interactions between chains (T(N) = 2.5 K) transmit.…
Abstract Magnetic poly(methyl methacrylate) (PMMA) microspheres were prepared by double‐miniemulsion polymerization. First, oleic acid coated magnetite particles synthesized by means of coprecipitation were dispersed into octane to obtain a ferrofluid. The ferrofluid and MMA were emulsified to form O/W emulsion, respe…
We investigate the temperature-dependent polymorphs in diindenoperylene (DIP) thin films on sapphire and silicon oxide substrates using in situ X-ray scattering. On both substrates the DIP unit cell is very similar to the high-temperature phase of bulk crystals, with the substrate stabilising this structure well below…
Abstract A systematic study of the reinforcement of single‐walled carbon nanotubes (SWNTs), multiwalled carbon nanotubes, and vapor‐grown carbon nanofibers (VGCNFs) in poly(methyl methacrylate) (PMMA) is reported. SWNT/PMMA composite films with various SWNT concentrations (from 0.5 to 50 wt % with respect to the weigh…
Experimental solubilities of three antiepileptic drugs, that is, lamotrigine, diazepam, and clonazepam in ethanol + water mixtures at 298.15 K were reported. The solubility of drugs was increased with the addition of ethanol, reached the maximum values, and then decreased with further increase in ethanol concentration…
The explanation of transition between ductile and brittle modes of fracture based on the “incubation time” concept is proposed. This approach allows us to establish relation between the influences of different loading parameters (strain-rate, temperature) on the mode of fracture. Proposed criteria give explanation to…
Applying ATR-FTIR (attenuated total reflection Fourier transform infrared) and TIRF (total internal reflection fluorescence) spectroscopy, we have studied the secondary structure and aggregation properties of different proteins which are adsorbed at a poly(acrylic acid) (PAA) brush that covers a macroscopically large,…
Recently, Pantina and Furst [Phys. Rev. Lett. 94, 138301 (2005)] experimentally demonstrated the existence of tangential forces between bonded colloidal particles and the capability of these bonds to supporting bending moments. We introduce a model to be used in computer simulations that describes these tangential int…
Torsion experiments were carried out on pure magnesium (99.9%) and the magnesium alloy AZ71 under free-end conditions of testing. The alloy had an axisymmetric initial texture, while the pure Mg samples were prepared from a rolled plate with a nonaxisymmetric initial texture. The torque as a function of the twist angl…
Several automated algorithms are presented for the segmentation of features of interest from microstructure images acquired with modern high-throughput electron microscopes. Specifically, the maximization of posterior marginals (MPM) segmentation technique, originally developed for computer vision applications, is app…
Organic-metallic hybrid polymers are formed by the complexation of metal ions with organic modules bearing two coordination sites. The hybrid polymers consisting of bis-terpyridines and metal ions such as Fe(II) or Ru(II) have a specific color based on the metal-to-ligand charge transfer (MLCT) absorption. Cyclic volt…
The porous structure of nanostructured silicas MCM-41 and SBA-15 has been characterized using N2 adsorption at 77 K, before and after n-nonane preadsorption, together with immersion calorimetry into liquids of different molecular dimensions. Selective blocking of the microporosity with n-nonane proves experimentally t…
The long, multicenter bonding in tetrathiafulvalenium cation radical dimers, [TTF](2)(2+), observed in both the solid state and in solution, were computationally investigated via B3LYP, CASSCF(2,2), and MCQDPT/CASSCF(2,2) calculations. The stability of [TTF](2)(2+) dimers originates from [TTF](*+)...anion(-) or [TTF](…
We have measured the dynamic alignment properties of single-walled carbon nanotube (SWNT) suspensions in pulsed high magnetic fields through linear dichroism spectroscopy. Millisecond-duration pulsed high magnetic fields up to 56 T as well as microsecond-duration pulsed ultrahigh magnetic fields up to 166 T were used.…
We describe a surfactant-promoted reductive route for the shape-controlled synthesis of gold nanostructures by hydrothermal treatment of chloroauric acid in the presence of the surfactant hexadecyltrimethylammonium bromide (CTAB) without using reducing agent. The results show that the cationic surfactant CTAB provides…
Abstract Composites of polyvinylidene fluoride (PVDF)/carbon nanofibers (CNFs) with different nanofiber contents were prepared by melt‐blending using a twin‐screw extruder by directly mixing CNFs with PVDF in the molten state. Fibers were extruded from the blended pellets. CNFs improved the nucleation efficiency of PV…