Materials Literature
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It is shown that the intensity of photoluminescence of nitrogen-vacancy (NV) centers in nanodiamond decreases 4-fold (with a wide spread among nanocrystals) when the surrounding temperature rises from 300 to 670 K. The effect is accompanied by a 2.7-fold decrease in the luminescence lifetime but negligible changes in…
Abstract Novel bio‐based polyols were prepared from hydroformylated oleic acid (9/10‐hydroxymethyl‐octadecanoic acid) methyl esters (HFME) and trimethylolpropane by transesterification. Hydroformylation produces primary hydroxyls, which allow relatively lower transesterification temperatures and better yields than hyd…
Differing from the reported strategy of push or pull electron effects of the complexant, a new strategy of the combination effects of both push and pull electrons of the complexant to enhance the first hyperpolarizability is performed with two Li atom doped complexants with a pair of difluorophenyl subunit rings. Larg…
D iatoms are the largest group of microalgae, play an enormous role in the biosphere, and have major significance as bioindicators. Traditional identification requires inter alia long training, considerable microscopical skill, and use of av ast and scattered literature. During the life cycle, diatom cells change in s…
This paper presents information on the physical and mechanical properties of different sizes of palm kernel shells (PKS) used here as lightweight aggregates (LWA) and their influence on mechanical properties of palm kernel shell concrete (PKSC). Silica fume and fly ash were used as cementitious materials and all mixes…
A new kind of silver indium tungsten oxide (AgIn(WO(4))(2)) mesocrystals with high hierarchy can be synthesized by a microwave-assisted approach, which shows high and selective photocatalytic activity for the degradation of different organic dyes under UV and visible light irradiation.
The results of the first principles spin-polarized DFT calculations of the atomic and electronic structure of a complex perovskite (Ba1-xSrx)(Co1-yFey)O3-δ (BSCF) used as a cathode material for solid oxide fuel cells (SOFC) and gas separation membranes are presented and discussed. The formation energies of oxygen vaca…
This tutorial review centers on recent advances and applications of experimental techniques that help characterize surface species and catalyst structures under in situ conditions. We start by reviewing recent applications of IR spectroscopy of working catalysis, emphasizing newer approaches such as Sum Frequency Gene…
Due to their unique properties, Anticancer dendrimer-based drugs have been displaying promising results in both in vitro and in vivo in the treatment of cancerous cells, as compared to the traditional polymers. In this report, two conjugates (G1+Pt and G2+Pt) of cisplatin [cis-diaminedichloroplatinum; (CDDP)] with two…
Highly oriented SnO(2) nanotubes and nanowires arrays have been selectively fabricated via a convenient one-step wet-chemical approach using anodic aluminium oxide (AAO) as a hard template. Wall thickness of the SnO(2) nanotubes was tunable. The as-prepared nanostructures were composed of fine particles with sizes as…
We have monitored the physical aging process below the glass transition temperature (Tg) of poly(methyl methacrylate) PMMA/silica nanocomposites by means of broadband dielectric spectroscopy (BDS). To do so, we have followed the evolution with time of the dielectric strength of the PMMA secondary relaxation process th…
The electronic and magnetic properties of a BN sheet doped with 3d transition metals (Fe, Co and Ni) have been investigated using ab initio calculations. Our calculations show many interesting physical properties in a metal-doped BN sheet. A Fe-doped BN sheet is a half-metal with the magnetic moment of 2.0 micro(B), a…
Liposomal doxorubicin and nab-paclitaxel are nanoparticle formulations of traditional cancer chemotherapy drugs which have ample clinical experience both pre- and post-nanoparticle modification. The alterations in pharmacokinetics, pharmacodynamics, efficacy, and toxicity compared with their parent compounds are instr…
Part 1 Infection control and barrier materials. Part 2 Healthcare and hygiene products. Part 3 Wound care materials. Part 4 Bandaging and pressure garments. Part 5 Implantable materials. Part 6 Medical devices. Part 7 Smart materials and technologies. Part 8 Industry standards and regulations.
Block copolymers, having the ability to self-assemble into arrays of well-defined nanostructures, can be turned into thin films. Their application as membrane was so far strongly limited by the fact that these thin films have to be transferred manually onto a porous membrane support, or because of the very strict prep…
Well-defined nanoporous Pt46Ni54 alloy nanowires were fabricated by mild dealloying of the electrodeposited Pt4Ni96 nanowires, and showed a remarkably enhanced electrocatalytic activity towards methanol oxidation and good H2O2 sensing properties.
Targeted delivery of drug molecules to tumor tissue is one of the most interesting and challenging endeavors faced in pharmaceutical field, due to the critical and pharmacokinetically specific environment that exists in tumor. Over these years, cancer targeting treatment has been greatly improved by new tools and appr…
A novel highly fluorinated beta-diketonate ligand, 1-(3,5-bis(benzyloxy)phenyl)-4,4,5,5,5-pentafluoropentane-1,3-dione (HBBPPF) and its corresponding europium(III) ternary complex, Eu(BBPPF)(3)(DDXPO) [DDXPO = 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene oxide] were synthesized via a dexterously designed routine, c…
The ability of ICl <sub>3</sub> to activate electrophilic substrates through halogen bonding and its catalytic activity towards the ring-opening polymerization of L-lactide is demonstrated in this communication. Association of techniques highlights the production of narrowly dispersed PLA of predictable molecular weig…
This manuscript describes the selective modification of ZnO multipods with a series of wide bandgap and narrow bandgap semiconductors (ZnS, ZnSe, Bi2S3, and Cu2S). ZnO multipods are firstly synthesized via the aqueous phase reaction of Zn2+ ions with KOH at a temperature lower than 70 °C, which is simple, facile and f…