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CHARACTERIZATION OF NICKEL OXIDE NANOPARTICLES SYNTHESIZED VIA RAPID MICROWAVE-ASSISTED ROUTE

Dariush Mohammadyani、S.A. Hosseini、S.K. Sadrnezhaad2012-01-01International Journal of Modern Physics Conference Series

Nickel oxide ( NiO ) nano-particles were produced via a rapid microwave-assisted method. Ni ( OH ) 2 precursor was obtained by slow drop-wise addition of 0.1M sodium hydroxide to 0.1M nickel nitrate. The mixture was vigorously stirred until the pH reached 7.2. The mixture was then irradiated with microwave to deposit…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsCopper-based nanomaterials and applications

Nanoscale characterization and magnetic reversal mechanism investigation of electrospun NiFe2O4 multi-particle-chain nanofibres

Junli Zhang、Jiecai Fu、Guoguo Tan 等 11 位作者2012-01-01Nanoscale

NiFe(2)O(4) multi-particle-chain nanofibres have been successfully fabricated using electrospinning followed by calcination, and their morphology, chemistry and crystal structure were characterized at the nanoscale. Individual NiFe(2)O(4) nanofibres were found to consist of many nanocrystallites stacked along the nano…

Advancements in Battery MaterialsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

Influence of film casting method on block copolymer ordering in thin films

Xiaohua Zhang、Jack F. Douglas、Ronald L. Jones2012-01-01Soft Matter

We study the orientation of the cylinder phase of the block copolymer (BCP) poly(styrene-block-methylmethacrylate) (PS-b-PMMA) in thin spun-cast films having a range of film thicknesses and temperatures and compare to our earlier observations on flow-coated films of the same BCP under similar thermodynamic conditions.…

Rheology and Fluid Dynamics StudiesBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

Novel fluorinated polybenzoxazine–silica films: chemical synthesis and superhydrophobicity

Aikifa Raza、Yang Si、Xianfeng Wang 等 7 位作者2012-01-01RSC Advances

In this study, a novel fluorinated polybenzoxazine (PBZ) is successfully designed for the first time to fabricate superhydrophobic films on a glass surface. 2,2-Bis(3-fluorophenyl-3,4-dihydro-2H-1,3-benzoxazinyl)hexafluoro propane (BAF-fa) is successfully synthesized utilizing a conventional one-pot Mannich reaction.…

Surface Modification and SuperhydrophobicityEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Model oxide-supported metal catalysts – comparison of ultrahigh vacuum and solution based preparation of Pd nanoparticles on a single-crystalline oxide substrate

Huifeng Wang、William E. Kaden、Rhys Dowler 等 5 位作者2012-01-01Physical Chemistry Chemical Physics

Using single-crystalline Fe(3)O(4)(111) films grown over Pt(111) in UHV as a model-support, we have characterized the nucleation behaviour and chemical properties of Pd particles grown over the film using different deposition techniques with scanning tunnelling microscopy and X-ray photoelectron spectroscopy. Comparis…

Advanced Chemical Physics StudiesCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

The Effects of RF Sputtering Power and Gas Pressure on Structural and Electrical Properties of ITiO Thin Film

Accarat Chaoumead、Youl-Moon Sung、Dong-Joo Kwak2012-01-01Advances in Condensed Matter Physics

Transparent conductive titanium-doped indium oxide (ITiO) films were deposited on corning glass substrates by RF magnetron sputtering method. The effects of RF sputtering power and Ar gas pressure on the structural and electrical properties of the films were investigated experimentally, using a 2.5 wt% TiO 2 -doped In…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Design of patchy particles using ternary self-assembled monolayers

Inés C. Pons-Siepermann、Sharon C. Glotzer2012-01-01Soft Matter

Recent simulations have studied the formation of patterns in a binary mixture of immiscible surfactants adsorbed onto the surface of a spherical nanoparticle. The resulting patterns (Janus, spots and stripes) were in good agreement with experimental results. We perform dissipative particle dynamics (DPD) simulations t…

Surfactants and Colloidal SystemsBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Morphology and orientation control of guanine crystals: a biogenic architecture and its structure mimetics

Yuya Oaki、Soichiro Kaneko、Hiroaki Imai2012-01-01Journal of Materials Chemistry

The surface skin of a banded blue-sprat had the mesocrystal structures of biogenic guanine crystals and cytoplasm. The platy guanine crystals were organized in the parallel direction to the surface skin with incorporation of cytoplasm. The size of the platy guanine crystal as a unit was larger than that of the other f…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesCephalopods and Marine Biology

Corrosion Inhibition of Aluminum in Aqueous Alkaline Solutions by Alginate and Pectate Water-Soluble Natural Polymer Anionic Polyelectrolytes

Ishaq Zaafarany2012-01-01Portugaliae electrochimica acta

The influence of water-soluble alginates (Alg) and pectates (Pect) anionic polyelectrolytes as natural polymers containing secondary alcoholic groups on the rate of dissolution of aluminum metal in alkaline medium has been investigated by gasometric and weight-loss techniques. The results showed that addition of algin…

Synthesis and properties of polymersMaterial Properties and ApplicationsAdvanced Theoretical and Applied Studies in Material Sciences and Geometry

Chemically derived graphene–metal oxide hybrids as electrodes for electrochemical energy storage: pre-graphenization or post-graphenization?

Cheng‐Meng Chen、Qiang Zhang、Jia‐Qi Huang 等 10 位作者2012-01-01Journal of Materials Chemistry

The introduction of a secondary phase is an efficient and effective way to improve the electrochemical performance of graphene towards energy storage applications. Two fundamental strategies including pre-graphenization and post-graphenization were widely employed for graphene-based hybrids. However, there is still an…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane

Sung‐Kwan Kim、Taejin Kim、Tae Young Kim 等 7 位作者2012-01-01Chemical Communications

Palladium nanoparticles (PdNPs) were conveniently prepared in tetraglyme (TG) solution using a variety of palladium precursors. At 140 °C, TG promoted Pd(3)(OAc)(6) to produce irregular shaped PdNPs with an average size of 4 nm. When these PdNPs were re-dispersed in TG and used for the dehydrogenation of ammonia boran…

Metal-Organic Frameworks: Synthesis and ApplicationsHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Polyurethanes based on renewable polyols from bioderived lactones

Senthil A. Gurusamy Thangavelu、S.J. Emond、Aman Kulshrestha 等 7 位作者2012-01-01Polymer Chemistry

Ring opening transesterification polymerization of lactones derived from menthone and carvomenthone was used to synthesize polyols for polyurethane film formulations. The polyols were synthesized at 140 °C using tin(II) octoate as catalyst, diethanolamine as trifunctional initiator, and with ratios of lactone : initia…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingCarbon dioxide utilization in catalysis

Colloidal gelation of oppositely charged particles

Emily R. Russell、Joris Sprakel、Thomas E. Kodger 等 4 位作者2012-01-01Soft Matter

Colloidal gelation has been extensively studied for the case of purely attractive systems, but little is understood about how colloidal gelation is affected by the presence of repulsive interactions. Here we demonstrate the gelation of a binary system of oppositely charged colloids, in which repulsive interactions com…

Proteins in Food SystemsMaterial Dynamics and PropertiesPickering emulsions and particle stabilization

Facile synthesis of bifunctional silica-coated core–shell Y2O3:Eu3+,Co2+ composite particles for biomedical applications

Timur Sh. Atabaev、Oh Seong Jin、Jong-Ho Lee 等 7 位作者2012-01-01RSC Advances

In the present study, bifunctional silica-coated Y2O3:Eu3+,Co2+ spherical-shaped submicron composite particles were successfully prepared using a facile urea-assisted homogenous precipitation method. Synthesized Y2O3:Eu3+,Co2+ phosphor composites showed both ferromagnetic behaviour and strong visible red luminescence…

Luminescence Properties of Advanced MaterialsQuantum Dots Synthesis And PropertiesLuminescence and Fluorescent Materials

Coupling aspects in the simulation of hydrogen-induced stress-corrosion cracking

W. Brocks、Rainer Falkenberg、Ingo Scheider2012-01-01Procedia IUTAM

Modelling of hydrogen-induced stress-corrosion cracking (HISCC) has to consider coupling effects between the mechanical and the diffusion field quantities. Four main topics are addressed: i) surface kinetics, ii) diffusion, iii) deformation and iv) crack growth. Surface kinetics is realised by a chemisorptions model,…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

An efficient and recyclable dendritic catalyst able to dramatically decrease palladium leaching in Suzuki couplings

Michel Keller、Aurélien Hameau、Grégory Spataro 等 7 位作者2012-01-01Green Chemistry

A series of novel monomeric and dendritic thiazolyl phosphines (generations 1 and 3) was prepared and the activity these ligands conferred to palladium in Suzuki couplings was evaluated. The heteroaryl ligands were revealed to be very efficient and were able to perform the reactions in mild conditions. Besides, their…

Catalytic Cross-Coupling ReactionsSynthetic Organic Chemistry MethodsDendrimers and Hyperbranched Polymers

A re-entrant glass transition in colloidal disks with adsorbing polymer

Anand K. Atmuri、George Peklaris、Suhasini Kishore 等 4 位作者2012-01-01Soft Matter

A re-entrant colloidal glass transition has been observed in dispersions of a model disk shaped colloid, laponite®, with the addition of an adsorbing low molecular weight polymer, poly(ethylene oxide) (PEO). In basic solutions laponite® forms a repulsive colloidal glass. With the addition of low molecular weight PEO,…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsAdsorption, diffusion, and thermodynamic properties of materials

Artificial light-harvesting antenna systems grafted on a carbohydrate platform

Paola Bonaccorsi、Maria C. Aversa、Anna Barattucci 等 6 位作者2012-01-01Chemical Communications

An enantiopure α-D-glucopyranoside derivative has been used as a platform to prepare artificial antenna systems based on bodipy subunits. Efficient and ultrafast energy transfer (in the fs and ps time regimes) takes place in the multibodipy systems.

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPhotoreceptor and optogenetics research

Enzymatic pre-treatment as a means of enhancing the antibacterial activity and stability of ZnO nanoparticles sonochemically coated on cotton fabrics

Ilana Perelshtein、Yelena Ruderman、Nina Perkas 等 11 位作者2012-01-01Journal of Materials Chemistry

Zinc oxide nanoparticles (ZnO NP's) are known for their excellent antibacterial properties. This paper describes a method for enhancing the stability and the antibacterial activity of ZnO NPs synthesized and embedded sonochemically on cotton fabrics, by pre-treating the fabric surface with cellulase enzyme. The enzyma…

Nanoparticles: synthesis and applicationsElectrospun Nanofibers in Biomedical ApplicationsUltrasound and Cavitation Phenomena

Electrochemically reduced graphene porous material as light absorber for light-driven thermoelectric generator

Yunqiang Chen、Kaiwu Chen、Hua Bai 等 4 位作者2012-01-01Journal of Materials Chemistry

Chemically converted graphene–room temperature ionic liquid (CCG–RTIL) porous materials were prepared by electrochemical reducing graphene oxide followed by solvent exchange. The resulted CCG–RTIL materials possess 3D porous structure with textured surface, and show good stability in air. Under laser irradiation the t…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesAdvanced Thermoelectric Materials and Devices