Materials Literature
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The geometric structure of a biopolymer network impacts its mechanical and biological properties. In this paper, we develop an algorithm for extracting the network architecture of three-dimensional (3d) fluorescently labeled collagen gels, building on the initial work of Wu et al., (2003). Using artificially generated…
The transformation optics technique is applied to design three novel devices—a wave collimator, far-zone and near-zone focusing flat optical lenses and a right-angle bend for propagating beam fields. The structures presented in this paper are all two-dimensional (2D), however, the transformation optics design methodol…
Abstract A nanocomposite of waterborne polyurethane (WPU) was prepared with functionalized graphene sheets (FGSs) which are a new type of nano‐sized conductive filler. The FGS were finely dispersed in a polymer matrix to improve the conductivity of the WPU. Conductivity of about 10 5 times that of pristine WPU was att…
This introductory review discusses the main problems facing the attempt to build quantum information processing systems (like quantum computers) from spin-based qubits. We emphasize ‘bottom-up’ attempts using methods from chemistry. The essentials of quantum computing are explained, along with a description of the qub…
Caught in a trap: Colloids of gold nanoparticles coated with a thermally responsive poly-(N-isopropylacrylamide) (pNIPAM) microgel can trap molecules in different ways as a function of temperature (see scheme). The porous pNIPAM shells prevent electromagnetic coupling between metal particles, thus providing highly rep…
We provide an overview of the progress made in the past few years in investigating fluorescence resonance energy transfer (FRET) using semiconductor quantum dots (QDs) and the application of QD-based FRET to probe specific biological processes. We start by providing some of the pertinent conceptual elements involved i…
Hydrogen storage for transportation applications requires high volumetric and gravimetric storage capacity. B-N compounds are well suited as storage materials due to their light weight and propensity for bearing multiple protic (N-H) and hydridic (B-H) hydrogens. This critical review briefly covers the various methods…
A new polymerization procedure with the aid of reverse micelles in supercritical carbon dioxide (SCCO2) has been employed to synthesize polyaniline (PANI). Sodium bis(2-ethylhexyl)-sulfosuccinate (AOT) and polyether-modified polysiloxane (PeSi) were used as mixing surfactants. PANI with more favorable needle-like aggr…
The thermal decomposition of the cobalt complex with hexamethylenetetramine (NO 3 ) 2 Co(H 2 O) 6 (HMTA) 2 · 4(H 2 O) was studied by the methods of differential thermal analysis, thermogravimetry, mass spectrometry, X-ray diffraction analysis, and by the magnetic method. It was established that the thermal decompositi…
The crystal and local atomic structure of monoclinic ReO2 (alpha-ReO2) under hydrostatic pressure up to 1.2 GPa was investigated for the first time using both X-ray absorption spectroscopy and high-resolution synchrotron X-ray powder diffraction and a home-built B4C anvil pressure cell developed for this purpose. Exte…
The Ru-Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru-Ru bond order, due to increased internal rotation.
The macromolecular crystallography experiment lends itself perfectly to high-throughput technologies. The initial steps including the expression, purification and crystallization of protein crystals, along with some of the later steps involving data processing and structure determination have all been automated to the…
Nach der Ära des Siliciums: Die Verbindung zwischen Radikalchemie unter Standardbedingungen und Reinraumlithographie kann die elektronische Struktur von Graphenlagen durch kovalente chemische Funktionalisierung permanent verändern. Die Potentialveränderung folgt der Hammett-Beziehung. Diese einfache Methode ist ein vi…
Diatoms are unicellular eukaryotic algae found in fresh and marine water. Each cell is surrounded by an outer shell called a frustule that is composed of highly structured amorphous silica. Diatoms are able to transform silicic acid into these sturdy intricate structures at ambient temperatures and pressures, whereas…
During the last decade, molecular photonics has been highlighted in the field of materials chemistry, providing the possibility of the construction of photonic devices at individual molecular level. In parallel, well-established single molecule fluorescence spectroscopy enables us to assess the functionality of indivi…
The structure analyses of sodium chromium digermanate, NaCrGe(2)O(6), (I), and lithium chromium digermanate, LiCrGe(2)O(6), (II), provide important structural information for the clinopyroxene family, and form part of our ongoing studies on the phase transitions and magnetic properties of clinopyroxenes. (I) shows C2/…
Abstract In the present paper, polyaniline (PANI) was polymerized by ammonium persulphate using a chemically oxidative process under mild tempertures ranging from −5–20°C. Electrical conductivity of as synthesized PANI got enhanced gradually owing to the increase in molecular weight and crystallinity with decrease in…
The refractive index of the CuAlO 2 delafossite has been determined from interference measurements in single crystals performed in the visible, near and mid infrared regions of the spectrum. The analysis of the refractive index dispersion corresponding to light polarization perpendicular to the c -axis ( P ⊥ c ) yield…
Flexible "pacman" scaffolds built upon a calix[4]arene platform bearing a [18]crown-6 ether and either two OH functions or two OPr groups at the lower rim have been used to generate donor-acceptor (D-A) dyads incorporating a zinc-porphyrin donor and a free-base porphyrin acceptor. Through-space singlet energy transfer…
Through a detailed study of the specific heat, resistivity, and susceptibility under pressure in polycrystalline and single-crystal ${\text{CoS}}_{2}$, we demonstrate that the thermodynamic and transport properties of this system are governed by spin-density fluctuations. We give the correct $(P,T)$ coordinates of its…