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Metal Chelates as Flame Retardants and Smoke Suppressants for Flexible Poly (Vinyl Chloride)

C. M. Tian、Hongqiang Qu、Wei Wu 等 5 位作者2004-01-01Journal of Fire Sciences

The thermal degradation in air of flexible PVC treated with various metal chelates containing Fe, Co, Ni, Cu, or Zn combined with two compounds Al(OH) 3 and Mg(OH) 2 , have been studied by differential thermal analysis and thermogravimetry from ambient temperature to 1023 K. The kinetic parameters were obtained using…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesPolymer Science and PVC

Cell-adhesive and blood-coagulant properties of ultrathin poly(methyl methacrylate) stereocomplex films

Takeshi Serizawa、Keiko Yamashita、Mitsuru Akashi2004-01-01Journal of Biomaterials Science Polymer Edition

Isotactic (it) and syndiotactic (st) poly(methyl methacrylate)s (PMMAs) were assembled on a poly(ethylene terephthalate) cell disk (as a solid substrate), which is normally used for cell culture, to produce ultrathin stereocomplex films. Static contact angles of the films using air bubbles in aqueous phase revealed th…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Modeling of the Diffusion of Hydrogen in Porous Graphite

M. Warrier、R. Schneider、Emppu Salonen 等 4 位作者2004-01-01Physica Scripta

The graphite used in fusion devices as first wall material is porous and consists of granules and voids. The 1–10 µm granules are further composed of graphitic micro-crystallites (5–10 nm), which are separated by micro-voids. Understanding the hydrogen transport and trapping in such granules is an important aspect of…

Nuclear Physics and ApplicationsMuon and positron interactions and applicationsGraphite, nuclear technology, radiation studies

Dynamical mechanical analysis of photocrosslinked hyperbranched urethane acrylates

Enis S. Džunuzović、Srba Tasic、Branislav Bozic 等 5 位作者2004-01-01Journal of the Serbian Chemical Society

A series of acrylate functionalized samples based on hyperbranched hydroxy-terminated polyesters with different molecular weights and different degrees of acrylation were synthesized. The obtained urethane acrylates were slightly yellow viscose liquids. Their composition was characterized by FTIR and 1H-NMR spectrosco…

Epoxy Resin Curing ProcessesDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Effect of Mechanical Vibration on the Microstructure, Impact Toughness and Thermal Fatigue Behavior of Cast Hot Working Die Steel

Y. G. Zhao、Yunhong Liang、Qingdong Qin 等 5 位作者2004-01-01ISIJ International

The cast hot working die steel is treated by mechanical vibration (MV) with a frequency of 50 Hz during the solidification process. The experimental results indicate that the MV may break off the dendrites growing from mould wall towards center in the steel during solidification. Therefore, the growth of the dendrites…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Synthesis and Electrochemical Properties of N-Substituted Bicarbazyl Derivatives

Yeong Kim、Young Dae Kwon、Kwang Lee 等 6 位作者2004-01-01Molecular Crystals and Liquid Crystals

N,N′-Diethyl-3,3′-bicarbazyl(DEBC)and N,N′-Diphenyl-3,3′-bicarbazyl(DPBC)was synthesized by the oxidative coupling reaction. The electrochemical properties of DEBC and DPBC were characterized by cyclic voltammetric technique. The oxidation of DEBC occurred at 0.56 V and 0.8 V(vs. Ag/Ag+)and the reduction also at 0.47…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Mechanism of adhesion degradation of rubber to brass-plated steel cords

Pankaj Y. Patil、W.J. van Ooij2004-01-01Journal of Adhesion Science and Technology

We have explored the effect of the presence of the sulfide layer on the corrosion performance of sulfidized brass-coated steel cords extracted from tires and squalene formulations. The corrosion performance of sulfidized brass cords extracted from various rubber formulations was tested in 3% NaCl electrolyte solution…

Asphalt Pavement Performance EvaluationCorrosion Behavior and InhibitionConcrete Corrosion and Durability

Influence of untreated and novel electron beam modified surface coated silica filler on dynamic mechanical thermal properties of ethylene‐octene copolymer

Sudip Ray、Anil K. Bhowmick2004-01-01Polymer Engineering and Science

Abstract An extensive study on dynamic mechanical thermal analysis has been carried out to investigate the effect of filler‐filler and polymer‐filler interaction in cured ethylene‐octene copolymer reinforced by unmodified and modified silica. The silica was treated with trimethylolpropane triacrylate (TMPTA) or trieth…

Polymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and IrradiationSilicone and Siloxane Chemistry

Structural Phase Transformations of ZnS Nanocrystalline Under High Pressure

Pan Yue-Wu、Qu Sheng-Chun、Chunxiao Gao 等 8 位作者2004-01-01Chinese Physics Letters

In-situ energy dispersive x-ray diffraction on ZnS nanocrystalline was carried out under high pressure by using a diamond anvil cell. Phase transition of wurtzite of 10 nm ZnS to rocksalt occurred at 16.0 GPa, which was higher than that of the bulk materials. The structures of ZnS nanocrystalline at different pressure…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Carbon Erosion and Migration in Fusion Devices

M. Mayer、V. Rohde、T. P tterich 等 7 位作者2004-01-01Physica Scripta

This paper summarizes observations about net carbon erosion and re-deposition in the limiter tokamak TEXTOR, and the divertor tokamaks ASDEX Upgrade and JET. The major carbon source in TEXTOR is the toroidal graphite belt limiter. Eroded carbon is mainly re-deposited on net deposition dominated areas of that limiter,…

Magnetic confinement fusion researchFusion materials and technologiesNuclear Materials and Properties

Selective Catalytic Oxidation of Ammonia over Copper-Cerium Composite Catalyst

Jie‐Chung Lou、Chang‐Mao Hung、Sheng-Fu Yang2004-01-01Journal of the Air & Waste Management Association

This work considers the oxidation of ammonia (NH3) by selective catalytic oxidation (SCO) over a copper (Cu)-cerium (Ce) composite catalyst at temperatures between 150 and 400 degrees C. A Cu-Ce composite catalyst was prepared by coprecipitation of copper nitrate and cerium nitrate at various molar concentrations. Thi…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Preparation of aqueous gel beads coated by lipid bilayers

Andrew L. Campbell、Pietro Taylor、Olivier J. Cayre 等 4 位作者2004-01-01Chemical Communications

Novel giant liposome microcapsules have been fabricated based on aqueous gel cores encapsulated with a lipid bilayer. The method involves templating of lipid-stabilised water-in-oil emulsions after gelling the aqueous phase with a suitable hydrocolloid.

Advanced Polymer Synthesis and CharacterizationInnovative Microfluidic and Catalytic Techniques InnovationPickering emulsions and particle stabilization

An Investigation on the Influence of a Vinyl Pyrrolidone/Vinyl Acetate Copolymer on the Moisture Permeation, Mechanical and Adhesive Properties of Aqueous-Based Hydroxypropyl Methylcellulose Film Coatings

Teresa Swee Har Kwok、Bruce Sunderland、Paul Wan Sia Heng2004-01-01Chemical and Pharmaceutical Bulletin

Polymers for aqueous film coating, such as hydroxypropyl methylcellulose (HPMC), often require the inclusion of a plasticizer to reduce brittleness and increase flexibility and ductility. A vinyl pyrrolidone/vinyl acetate copolymer (S630) was investigated for its influence on HPMC film coating parameters, comparing th…

Polymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and IrradiationPolymer Science and PVC

Reactivation of aged model Pd/Ce 0.68 Zr 0.32 O 2 three-way catalyst by high temperature oxidising treatment

Neal Hickey、Paolo Fornasiero、R. Di Monte 等 9 位作者2004-01-01Chemical Communications

A deactivated (aged under redox-cycled model TWC feed-stream) Pd/Ce(0.68)Zr(0.32)O(2) catalyst is remarkably reactivated when subjected to a high temperature oxidising treatment whereas this effect is only marginal for Pd/Al(2)O(3), which indicates the key role of such treatment in restoring the Pd-Ce(0.68)Zr(0.32)O(2…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Significance of activation volumes for cation transport in glassy electrolytes

Malcolm D. Ingram、Corrie T. Imrie、Ioannis Konidakis 等 4 位作者2004-01-01Physical Chemistry Chemical Physics

A new model is described for cation transport in glass, in which below Tg a dynamic equilibrium exists between ‘open’ and ‘closed’ sites. Cations migrate by hopping into a relatively small number of open sites, which must be just the right size for them to occupy. This model accounts plausibly for the apparent constan…

Material Dynamics and PropertiesGlass properties and applicationsPhotochemistry and Electron Transfer Studies

A Shape Memory Alloy Based Cryogenic Thermal Conduction Switch

Vaidyanathan Krishnan2004-01-01AIP conference proceedings

Shape memory alloys (SMAs) can produce large strains when deformed (e.g., up to 8%). Heating results in a phase transformation and associated recovery of all the accumulated strain. This strain recovery can occur against large forces, resulting in their use as actuators. Thus an SMA element can integrate both sensory…

Shape Memory Alloy TransformationsLaser and Thermal Forming Techniques

Development of a Non-Radiographic Spall and Damage Diagnostic

D. B. Holtkamp2004-01-01AIP conference proceedings

A new, non‐radiographic diagnostic has been developed that appears to provide information on multiple spall and damage layers in metals. The velocities of multiple layers (up to 5 in copper) can be determined using this method, with additional information possible on damaged material between layers at densities less t…

High-pressure geophysics and materialsHigh-Velocity Impact and Material BehaviorNuclear Physics and Applications

The effect of conservation defects on the suede quality of double-face

Behzat Oral Bitlisli、Hüseyin Ata Karavana、Bahri Başaran 等 6 位作者2004-01-01Dspace Repository (Marmara Üniversitesi)

In this research, the effects of microorganisms on suede quality of double-face leather were examined. The bacterial numbers on salted sheepskin samples were found as 1.8x10 6 -4.3x10 7 cfu/g on solid medium and 1.9x10 6 -4.7x10 7 cfu/g on halophile medium containing 10-30% NaCl. However it was found that salted sheep…

Corrosion Behavior and InhibitionMeat and Animal Product QualityCollagen: Extraction and Characterization

Testing of Case Depth in Case carburized Gear steels using Magnetic Barkhausen Emission technique

Moorthy、Ba Shaw、K Brimble2004-01-01Materials Evaluation

Magnetic barkhausen emission measurements have been made on G86200 and G33106 steel specimens which have been case carburized to different case depths ranging from 0.5 to 1.5 mm (0.02 to 0.06 in.). The profile of root mean square voltage of the magnetic barkhausen emission signal plotted as a function of the voltage a…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Development and industrialization of electric double-layer capacitors

Takeshi Morimoto2004-01-01TANSO

Electric double-layer capacitors based on the charge storage at the interface between a high specific surface area activated carbon electrode and an electrolyte solution have been developed, and are widely used as maintenance-free power source for IC memories and microcomputers. Following the production of small size…

Supercapacitor Materials and FabricationFuel Cells and Related MaterialsConducting polymers and applications