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Nematic Order Drives Phase Separation in Polydisperse Liquid Crystalline Polymers

Florence Elias、Stuart M. Clarke、RONA M. PECK 等 4 位作者2000-03-01Macromolecules

In a polydisperse thermotropic main-chain liquid crystalline polymer, we observe the process of thermally induced nematic−nematic phase separation between short and long polymer chains. We study the dynamical features of this system, in particular the evolution of Schlieren textures formed by disclinations surrounding…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesAdvanced Materials and Mechanics

Constriction energy in the presence of a solute field

Scott Andrews、Hüseyin Şehitoğlu、İbrahim Karaman2000-03-01Journal of Applied Physics

It has been widely known that both solute concentration, i.e., frictional effects, and stacking fault energy influence the degree of cross slip and slip planarity in face-centered-cubic alloys. Cross slip is preceded by constriction of two partial dislocations. A model is proposed for the energy required to form a con…

Microstructure and mechanical propertiesHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep

Hydroxylclinohumite, a new member of the humite group: Twinning, crystal structure and crystal chemistry of the clinohumite subgroup

Giovanni Ferraris、Mauro Prencipe、Elena Sokolova 等 5 位作者2000-03-01Zeitschrift für Kristallographie - Crystalline Materials

Hydroxylclinohumite Mg 9 [SiO 4 ] 4 (OH, F) 2 , a new mineral from Zelentsovskaya mine near Magnitka (Zlatoust district, Southwestern Urals), is the OH-dominant equivalent of clinohumite Mg 9 [SiO 4 ] 4 (F,OH) 2 . The crystal structure of hydroxylclinohumite has been refined from single-crystal X-ray data to R = 0.026…

Crystal Structures and PropertiesClay minerals and soil interactionsNuclear materials and radiation effects

Functional polysiloxanes. II. Neighboring effect in the hydrosilylation of poly(hydrogenmethylsiloxane-co-dimethylsiloxane)s by allylglycidylether

Patrick Cancou�t、Sophie Pernin、G�rard H�lary 等 4 位作者2000-03-01Journal of Polymer Science Part A Polymer Chemistry

Polysiloxanes bearing epoxy groups as lateral substituents were prepared by the hydrosilylation of 1-allyloxy-2,3-epoxypropane (allylglycidylether) with poly(hydrogenmethylsiloxane-co-dimethylsiloxane)s (DH-D copolymers) of various compositions. To determine the optimal conditions of the hydrosilylation catalyzed by h…

Organoboron and organosilicon chemistrySynthetic Organic Chemistry MethodsSilicone and Siloxane Chemistry

Solid-State 93Nb NMR and 93Nb Nutation Studies of Polycrystalline Pb(Mg1/3Nb2/3)O3 and (1 - x)Pb(Mg1/3Nb2/3)O3/xPbTiO3 Solid-Solution Relaxor Ferroelectrics

John J. Fitzgerald、Subramanian Prasad、Jiong Huang 等 4 位作者2000-03-01Journal of the American Chemical Society

Solid-state 93 Nb static and MAS NMR and 93 Nb nutation studies of polycrystalline Pb(Mg 1/3 Nb 2/3 )O 3, (PMN) and (1 − x )Pb(Mg 1/3 Nb 2/3 )O 3 / x PbTiO 3 ( x = 0.05 to 0.50) solid-solutions are reported. The 93 Nb static and MAS NMR spectra of PMN measured at 14.1 T have two major resonances due to the central tra…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Photoconductor selection for digital flat panel x-ray image detectors based on the dark current

Safa Kasap、J. A. Rowlands2000-03-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

We consider a flat panel direct conversion x-ray image detector in which a photoconductor is used to directly convert absorbed x-ray photons to collectable electron hole pairs. The storage capacitor at each pixel stores a quantity of charge proportional to the incident radiation. The charge stored at each pixel is rea…

Luminescence Properties of Advanced MaterialsAdvanced Semiconductor Detectors and MaterialsGa2O3 and related materials

A Generalized Model of Oriented Continuum with Defects

H. Stumpf、Jan Saczuk2000-03-01ZAMM ‐ Journal of Applied Mathematics and Mechanics / Zeitschrift für Angewandte Mathematik und Mechanik

The aim of this paper is to present a general model of oriented continuum within the frame of Newtonian-Eshelbian continuum mechanics to describe macro- and microdeformations of solids taking into account the evolution of defects as voids and cracks. Within a manifold-theoretical setting, position- and direction-depen…

Elasticity and Material ModelingComposite Material MechanicsNonlocal and gradient elasticity in micro/nano structures

Physical characteristics and structure of Indian silk fibres

V. B. Gupta、Rangam Rajkhowa、V. K. Kothari2000-03-01Own your potential (DEAKIN)

The physical characteristics and structures of the four commercial varieties of Indian silk fibres, namely Mulberry, Tasar, Eri and Muga, have been studied. It is observed that the silk filaments from the same cocoon show considerable variation in linear density. As one moves from the outer layers to the inner layers…

Silk-based biomaterials and applicationsResearch in Cotton CultivationSilkworms and Sericulture Research

Crystal chemistry of the new mineral brandholzite, Mg(H 2 O) 6 [Sb(OH) 6 ] 2 , and of the synthetic analogues M 2+ (H 2 O) 6 [Sb(OH) 6 ] 2 (M 2+ = Mg, Co)

Alexandra Friedrich、Manfred Wildner、Е. Тиллманнс 等 4 位作者2000-03-01American Mineralogist

Brandholzite, a new magnesium antimony hydroxide hydrate mineral, Mg(H 2 O) 6 [Sb(OH) 6 ] 2 , has been discovered in Au-Sb-Quartz veins of the former mining district of Brandholz-Goldkronach, Fichtelgebirge, Germany. The new mineral is associated with stibnite and antimony-ochers and forms colorless, platelike crystal…

Crystal Structures and PropertiesRadioactive element chemistry and processingLayered Double Hydroxides Synthesis and Applications

Flame Resistant Cotton/Polyester Carpet Materials

Eugene J. Blanchard、Elena Graves、Pablo A. Salame2000-03-01Journal of Fire Sciences

Cotton/polyester carpet materials are resistant to surface flame spread after esterification of the cellulosic fibers with polycarboxylic acid and suitable catalyst. The crosslinked cellulose-containing materials passed the re quired flammability standards for carpet when subjected to the methenamine pill test. This t…

Flame retardant materials and properties

Nitrate retention and leaching in variable charge soils of a watershed in São Paulo state, Brazil

José Flávio Dynia2000-03-01Communications in Soil Science and Plant Analysis

Two Oxisols [Dusky Latosol (LR) and Dark‐Red Latosol (LE)] and one Entisol [Quartzous Sand (AQ)] of a watershed situated at the boundaries of the most important Brazilian aquifer, and intensively cropped to sugarcane, were studied in relation to their nitrate retention and leaching potential, and related electrochemic…

Groundwater and Isotope GeochemistryArsenic contamination and mitigationClay minerals and soil interactions

Swelling behavior of poly(acrylic acid) gels in aqueous ethanol - effects of counterion species and ionic strength

Yuji Nishiyama、Mitsuru Satoh2000-03-01Macromolecular Rapid Communications

The swelling behavior of poly(acrylic acid) (PAA) gels in aqueous ethanol (EtOH) was investigated. These gels were prepared by γ-irradiation and pretreated in aqueous solutions of different pH levels in order to vary the charge density. With increasing pH of the pretreating solutions, a distinct collapse was observed…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationPolymer Nanocomposite Synthesis and Irradiation

Clay mineral distribution in the Devonian-Carboniferous sandstones of the Clair Field, west of Shetland, and its significance for reservoir quality

M. D. Pay、T. R. Astin、A. Parker2000-03-01Clay Minerals

Abstract The Devonian-Carboniferous reservoir of the Clair Field contains a complex and variably abundant clay mineral assemblage. An abrupt vertical change in clay mineralogy has been observed in both wells studied (UKCS 206/8-7 and 206/8-8) from being rich in Mg-chlorite, chlorite- smectite (including dioctahedral c…

Geological and Geochemical AnalysisHydrocarbon exploration and reservoir analysisClay minerals and soil interactions

Generation of second harmonics in Ge-doped SiO2 thin films by ultraviolet irradiation under poling electric field

J. Khaled、T. Fujiwara、Motoshi Ohama 等 4 位作者2000-03-01Journal of Applied Physics

Thin films of Ge-doped silica were prepared by radio-frequency sputtering in a controlled atmosphere of Ar and O2 and then subjected to ultraviolet irradiation under poling electric field (UV poling). Effects of oxygen mass flow content during the sputtering on the second-order nonlinearity of the films were investiga…

Glass properties and applicationsPhotonic Crystals and ApplicationsPhotorefractive and Nonlinear Optics

Stereoregular Copolyamides Derived from d-Xylose and l-Arabinose

Francisca Zamora、Manuel Bueno、Inmaculada Molina Pinilla 等 6 位作者2000-03-01Macromolecules

A series of carbohydrate-based stereoregular copolyamides have been prepared by the active ester polycondensation method. These new optically active polymers contain in their repeating units an aliphatic ω-amino acid and an ω-aminoaldonic acid, which is 5-amino-5-deoxy-2,3,4-tri- O -methyl- l -arabinonic acid in the c…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesCatalysis for Biomass Conversion

Immunolocalization of Gastrolith Matrix Protein (GAMP) in the Gastroliths and Exoskeleton of Crayfish, Procambarus clarkii

Yasuaki Takagi、Katsuaki Ishii、Noriaki Ozaki 等 4 位作者2000-03-01ZOOLOGICAL SCIENCE

Gastrolith matrix protein (GAMP) is a novel protein purified from gastroliths of the crayfish, Procambarus clarkii, and has been suggested to be associated with calcium carbonate deposition. In the present study, a specific antibody against GAMP was raised and distribution of GAMP immunoreactivity was studied in crayf…

Aquaculture Nutrition and GrowthCalcium Carbonate Crystallization and Inhibition

Quantitative analysis of preferential orientation components of ferroelectric thin films

J. Ricote、Daniel Chateigner、L. Pardo 等 6 位作者2000-03-01Ferroelectrics

A quantitative study of the preferred orientation of lanthanum and calcium modified lead titanate thin films, including the measurement of pole figures and calculation of orientation distribution function (OD), is presented. The main preferential orientation components are identified as <001> and <100> perpendicular t…

Ferroelectric and Piezoelectric MaterialsUltrasonics and Acoustic Wave PropagationUltrasound Imaging and Elastography

High resolution phosphor screening method for full-color field emission display applications

Jae Eun Jang、Jihye Gwak、Y. W. Jin 等 8 位作者2000-03-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

A polyvinyl alcohol-slurry screening technology of phosphors was studied for field emission displays with a resolution up to supervideo graphics adapter. Phosphor lines were successfully patterned as narrow as 25 μm on 6 in. glass substrates. Process conditions such as spin coating speeds, exposure time, and shadow ma…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and Sensors

Error analysis of XAFS measurements

H. J. Krappe、H. Rossner2000-03-01Physical review. B, Condensed matter

We propose a method to analyze x-ray-absorption fine-structure data that avoids an arbitrary restriction of the size of the model-parameter space. It starts with an a priori guess of the model parameters which is introduced into the fitting procedure by Bayesian arguments. Two different descriptions are discussed to d…

Copper Interconnects and ReliabilityX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques