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On the Mechanism of Ion Transport through Polyphosphazene Solid Polymer Electrolytes: NMR, IR, and Raman Spectroscopic Studies and Computational Analysis of 15N-Labeled Polyphosphazenes

Thomas A. Luther、Frederick F. Stewart、Joanne Budzien 等 8 位作者2003-03-15The Journal of Physical Chemistry B

Comprehensive investigation of lithium ion complexation with 15 N-labeled polyphosphazenes 15 N -poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene] ( 15 N -MEEP) and 15 N -poly-[((2-allylphenoxy) 0.12 (4-methoxyphenoxy) 1.02 (2-(2-methoxyethoxy)ethoxy) 0.86 )phosphazene] ( 15 N -HPP) was performed by NMR, IR, and Raman s…

Advanced Battery Materials and TechnologiesFlame retardant materials and propertiesPolymer crystallization and properties

Analysis of the small-angle intensity scattered by a porous and granular medium

Olivier Spalla、Sandrine Lyonnard、Fabienne Testard2003-03-15Journal of Applied Crystallography

Using X-ray scattering over a large range of scattering vectors, it is shown how to measure both the pore volume fraction and pore specific surface of an assembly of porous grains forming a powder. Depending on the presence or not of solvent in the inner pores and in the intergranular media, the scattered signal per u…

X-ray Diffraction in CrystallographyCultural Heritage Materials AnalysisRadiation Shielding Materials Analysis

Carrier States and Ferromagnetism in Diluted Magnetic Semiconductors

Masao Takahashi、Kenn Kubo2003-03-15arXiv

Applying the dynamical coherent potential approximation to a simple model, we have systematically studied the carrier states in $A_{1-x}$Mn$_xB$-type diluted magnetic semiconductors (DMS's). The model calculation was performed for three typical cases of DMS's: The cases with strong and moderate exchange interactions i…

Materials Science

Triangular Nanoframes Made of Gold and Silver

Gabriella S. Métraux、Y. Charles Cao、Rongchao Jin 等 4 位作者2003-03-15OpenAlex

Silver nanoprisms (∼74-nm edge length) were etched with HAuCl 4 to generate gold−silver alloy framework structures. Interestingly, these triangular nanoframes possess no strong surface plasmon bands in the ultraviolet or visible regions of the optical spectrum. By adding a mild reducing agent, l -ascorbic acid, gold a…

Nanoporous metals and alloysGold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research

X-Cell: a novel indexing algorithm for routine tasks and difficult cases

Marcus A. Neumann2003-03-15OpenAlex

X-Cell is a novel indexing algorithm that makes explicit use of systematic absences to search for possible indexing solutions from cells with low numbers of calculated reflections to cells with high numbers of reflections. Space groups with the same pattern of systematic absences are grouped together in powder extinct…

Crystallography and molecular interactionsMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Ab Initio Study of Doped Carbon Nanotube Sensors

Shu Peng、Kyeongjae Cho2003-03-15OpenAlex

Recently great advances have been made in demonstrating the viability of using carbon nanotubes (CNTs) to detect the presence of chemical gases such as NO 2, NH 3, and O 2, and they have led to the design of a new breed of sensor devices. Based on intrinsic CNTs, the devices are capable of detecting small concentratio…

Nanopore and Nanochannel Transport StudiesCarbon Nanotubes in CompositesMechanical and Optical Resonators

Green Emission to Probe Photoinduced Charging Events in ZnO−Au Nanoparticles. Charge Distribution and Fermi-Level Equilibration

Vaidyanathan Subramanian、Eduardo E. Wolf、Prashant V. Kamat2003-03-15OpenAlex

Photoinduced electron accumulation in ZnO nanoparticles results in the bleaching of the exciton band as well as quenching of green emission. In the absence of an electron scavenger, photogenerated electrons are stored near the conduction band edge and promote charge recombination via a nonradiative process. By exposin…

Quantum Dots Synthesis And PropertiesCopper-based nanomaterials and applicationsZnO doping and properties

Mussel Adhesive Protein Mimetic Polymers for the Preparation of Nonfouling Surfaces

Jeffrey L. Dalsin、Bi−Huang Hu、Bruce P. Lee 等 4 位作者2003-03-15OpenAlex

A new biomimetic strategy for modification of biomaterial surfaces with poly(ethylene glycol) (PEG) was developed. The strategy exploits the adhesive characteristics of 3,4-dihydroxyphenylalanine (DOPA), an important component of mussel adhesive proteins, to anchor PEG onto surfaces, rendering the surfaces resistant t…

Marine Biology and Environmental ChemistryPolymer Surface Interaction StudiesKnee injuries and reconstruction techniques

An intensity evaluation method:EVAL-14

A. J. M. Duisenberg、Loes M. J. Kroon-Batenburg、A.M.M. Schreurs2003-03-15OpenAlex

A reflection intensity integration method is presented based upon ab initio calculation of three-dimensional ( x , y , ω) reflection boundaries from a few physical crystal and instrument parameters. It is especially useful in challenging circumstances, such as the case of a crystal that is far from spherical, anisotro…

Solid-state spectroscopy and crystallographyAcoustic Wave Resonator TechnologiesX-ray Diffraction in Crystallography

Liquid-crystalline metallophthalocyanines containing late first-row transition metals

Jurgen Sleven、Thomas Cardinaels、Christiane Görller‐Walrand 等 4 位作者2003-03-14ARKIVOC

Cobalt(II), nickel(II), copper(II) and zinc(II) phthalocyanines substituted by eight alkoxy chains in the peripheral (2,3,9,10,16,17,23,24) positions were prepared. The alkoxy chain lengths are octyloxy (C 8 H 17 O), dodecyloxy (C 12 H 25 O) and hexadecyloxy (C 16 H 33 O). Studies by polarized optical microscopy and h…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Diffusion-Corrected Simultaneous Multilayer Growth Model

Qiang Fu、Thomas Wagner2003-03-14Physical Review Letters

A diffusion-corrected simultaneous multilayer (DCSM) model was developed, taking into account up-step and down-step diffusion of adatoms and enabling rapid identification of different film growth modes. This DCSM model was applied to the initial growth of Cr on (100) ${\mathrm{S}\mathrm{r}\mathrm{T}\mathrm{i}\mathrm{O…

Electron and X-Ray Spectroscopy TechniquesSemiconductor materials and devicesSurface and Thin Film Phenomena

Equation of State for Monolayers under Consideration of the Two-dimensional Compressibility in the Condensed State

B. Fainerman、D. Vollhardt2003-03-14The Journal of Physical Chemistry B

The equation of state for Langmuir monolayers proposed earlier (Fainerman, V. B.; Vollhardt, D. J. Phys. Chem. B 1999, 103, 145.) is generalized for the case that one, two or more phase transitions in the monolayer take place, provided that the two-dimensional compressibility undergoes a jump at the phase transition,…

Spectroscopy and Quantum Chemical StudiesThermodynamic properties of mixturesNonlinear Optical Materials Research

Heteroepitaxial Growth of Nanostructured Cerium Dioxide Thin Films by MOCVD on a (001) TiO2 Substrate

Raffaella Lo Nigro、Roberta G. Toro、Graziella Malandrino 等 4 位作者2003-03-14Chemistry of Materials

The deposition of epitaxial CeO 2 nanostructured thin films on rutile (TiO 2 ) substrates by metal−organic chemical vapor deposition (MOCVD) has been carried out in a wide temperature range. Films have been grown on (001)TiO 2 from the Ce(III) 1,1,1,5,5,5-hexafluoro-2,4-pentanedionato diglyme adduct (Ce(hfa) 3 ·diglym…

Electronic and Structural Properties of OxidesZnO doping and propertiesCatalytic Processes in Materials Science

Polymer blends of poly(trimethylene terephthalate) and polystyrene compatibilized by styrene‐glycidyl methacrylate copolymers

Jieh‐Ming Huang2003-03-14Journal of Applied Polymer Science

Abstract The compatibilizing effects of styrene‐glycidyl methacrylate (SG) copolymers with various glycidyl methyacrylate (GMA) contents on immiscible blends of poly(trimethylene terephthalate) (PTT) and polystyrene (PS) were investigated using scanning electron microscopy (SEM), Fourier transform infrared spectroscop…

biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesFiber-reinforced polymer composites

Analysis of the isothermal crystallization of isotactic polypropylene nucleated with sorbitol derivatives

C. Marco、Gary Ellis、Marián A. Gómez‐Fatou 等 4 位作者2003-03-14Journal of Applied Polymer Science

Abstract The isothermal crystallization kinetics of isotactic polypropylene (iPP) and iPP nucleated with the sorbitol derivatives 1,3:2,4‐bis(4‐methyldibenzylidene)sorbitol and 1,3:2,4‐bis(3,4‐dimethylbenzylidene)sorbitol was studied, along with the subsequent melting behavior, as a function of the nucleating agent co…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Molecular design at the calamitic/discotic cross-over point. Mononuclear ortho-metallated mesogens based on the combination of rod-like phenylpyrimidines and -pyridines with bent or half-disc-shaped diketonatesElectronic supplementary information (ESI) available: procedures and analytical data for all compounds not described in the Experimental. See http://www.rsc.org/suppdata/jm/b2/b210250a/

Torsten Hegmann、Jens Kain、Siegmar Diele 等 6 位作者2003-03-14Journal of Materials Chemistry

Six novel series of mononuclear ortho-palladated and ortho-platinated metallomesogens have been obtained by combination of rod-like heteroaromatic liquid crystals with bent or half-disc-shaped 1,3-diketonate units. The synthesis of these molecules was achieved by ortho-metallation of rod-like 2-phenylpyrimidines and 2…

Liquid Crystal Research AdvancementsMolecular spectroscopy and chiralityCoordination Chemistry and Organometallics

Morphology control of MnWO4 nanocrystals by a solvothermal route

Shu-Jian Chen、Xue‐Tai Chen、Zi‐Ling Xue 等 7 位作者2003-03-14Journal of Materials Chemistry

A solvothermal route to MnWO4 nanoparticles and nanorods has been developed. These nano-size products have been characterized by X-ray diffraction and transmission electron microscopy. The pressure, pH and temperature of the reaction systems were found to play important roles in determining the morphologies of the MnW…

Ferroelectric and Piezoelectric MaterialsLuminescence Properties of Advanced MaterialsTransition Metal Oxide Nanomaterials

Synthesis and Spectroscopic Properties of Finite Ph2N-Containing Oligo(arylenevinylene) Derivatives That Emit Blue to Red Fluorescence

Chien‐Le Li、Shwu‐Ju Shieh、Shien-Chang Lin 等 4 位作者2003-03-14Organic Letters

[structure: see text] A series of oligo(phenylenevinylene) (OPV) derivatives with finite conjugation units were prepared in short steps from few building blocks. The central and terminal aryl groups of these OPV dyes contain cyano and Ph(2)N substituents, respectively, which affect color of fluorescence. The wavelengt…

Photochromic and Fluorescence ChemistryOrganic Electronics and PhotovoltaicsLuminescence and Fluorescent Materials

Simulating the morphology and mechanical properties of filled diblock copolymers

Gavin A. Buxton、Anna C. Balazs2003-03-14Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We couple a morphological study of a mixture of diblock copolymers and spherical nanoparticles with a micromechanical simulation to determine how the spatial distribution of the particles affects the mechanical behavior of the composite. The morphological studies are conducted through a hybrid technique, which combine…

Material Dynamics and PropertiesPickering emulsions and particle stabilizationBlock Copolymer Self-Assembly