Materials Literature
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We have performed in situ transmission electron microscopy studies of abnormal grain growth in electroplated copper films at room temperature and 55 °C, starting minutes after the plating process by electroplating directly onto electron-transparent membranes. A kinetic analysis indicates that the grains that grow abno…
The temperature dependence of the resistivity $\ensuremath{\rho}(T)$ and of the dc magnetic susceptibility $\ensuremath{\chi}(T)$ were measured on high-quality $L{\mathrm{NiO}}_{3}$ $(L\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}\mathrm{La},\mathrm{Pr},\mathrm{Nd},{\mathrm{Nd}}_{0.5}{\mathrm{Sm}}_{0.5})$ sample…
Reactions of dioxoruthenium(VI) porphyrins, [Ru(VI)O2(Por)], with p-chloroaniline, trimethylamine, tert-butylamine, p-nitroaniline, and diphenylamine afforded bis(amine)ruthenium(II) porphyrins, [Ru(II)(Por)(L)2] (L-p-ClC6H4NH2, Me3N, Por=TTP, 4-Cl-TPP; L=tBuNH2, Por = TPP, 3,4,5-MeO-TPP, TTP, 4-Cl-TPP, 3,5-Cl-TPP) an…
A nonempirical exciton chirality circular dichroic (CD) method for determining the absolute configurations of primary monoamines with amino group directly linked to the stereogenic center is described. Conventional exciton chirality CD method cannot be applied to these compounds since they lack the two sites for attac…
The catalytic degradation of polyethylene to short-chain hydrocarbons is possible with zirconium hydride compounds (see picture), and represents the first step in the reversal of Ziegler - Natta polymerization. Thus, even in the case of polyolefins the important target of plastics recycling, the recovery of reusable m…
A combination of azido and dipyridylketone (dpk) ligands led to the isolation of the tetranuclear Ni(II) complex 1 (dpkOH and dpkOCH(3) result from solvolysis of dpk). The complex exhibits ferromagnetic behavior, and its structure can be described as a dicubane unit with two missing vertices (see picture).
In the three-dimensional oxalate network structures [M(II)(bpy)3][M(I)-M(III)(ox)3] (ox= C2O4(2-); bpy = 2,2'-bipyridine) the negatively charged oxalate backbone provides perfect cavities for tris-bipyridyl complex cations. The size of the cavity can be adjusted by variation of the metal ions of the oxalate backbone.…
Silicon nanocrystals with diameters ranging from ≈2 to 5.5 nm were formed by Si ion implantation into SiO2 followed by annealing. After passivation with deuterium, the photoluminescence (PL) spectrum at 12 K peaks at 1.60 eV and has a full width at half maximum of 0.28 eV. The emission is attributed to the recombinati…
We discuss the local cutting of single-walled carbon nanotubes by a voltage pulse to the tip of a scanning tunneling microscope. The tip voltage ($\mid V \mid \ge $~3.8 eV) is the key physical quantity in the cutting process. After reviewing several possible physical mechanisms we conclude that the cutting process rel…
We study effective-medium approximations for linear composite media by means of a path integral formalism with replicas. We show how to recover the Bruggeman and Hori-Yonezawa effective-medium formulas. Using a replica-coupling ansatz, these formulas are extended into new ones which have the same percolation threshold…
An effective-medium theory is proposed for random weakly nonlinear dielectric media. It is based on a new gaussian approximation for the probability distributions of the electric field in each component of a multi-phase composite. These distributions are computed to linear order from a Bruggeman-like self-consistent f…
Self-consistent field theory predicts that the complex phase behavior of block copolymers does not originate solely from the interface seeking constant mean curvature as once thought, but instead reflects competing minimization of interfacial tension and packing frustration. To test this prediction, we directly measur…
Luminescence of Nd(III) in an organic solvent having C-H bonds was achieved for the first time by complexing Nd(III) with long-chain perfluoroalkylated ligands such as bis(perfluorooctylsulfonyl)aminate (pos). The complex [Nd(pos)(3)] gave an emission quantum yield of 3.0+/-0.5 % in undeuterated acetone. The bulky pos…
We present a comprehensive study of the partially reduced polyoxomolybdate [H3-Mo57V6(NO)6O183(H2O)18]21-encapsulated in a shell of dimethyldioctadecylammonium (DODA) surfacmolecules. Treatment of an aqueous solution of (NH4)21[H3Mo57V6-(NO)6O183(H2O)18] . 65H2O (1a) with a trichloromethane solution of the surfactant…
Recent studies have shown a current limiting effect in the field emission behavior of carbon nanotubes. In this letter, we demonstrate that an individual nanotube exhibits current saturation above 100 nA of emission current, and we show that this current saturation is a direct result of an adsorbate-enhanced field emi…
Aluminum-doped zinc oxide (AZO) thin films (∼3000 Å) with low electrical resistivity and high optical transparency have been grown by pulsed-laser deposition on glass substrates without a postdeposition anneal. Films were deposited at substrate temperatures ranging from room temperature to 400 °C in O2 partial pressur…
An approximate expression for the free energy of a single crystal is derived to determine equilibrium positions of atoms on vicinal faces of a fcc crystal at various temperatures thermodynamically. The obtained free energy has a peculiarity (critical temperature) in all the considered cases: infinite crystal, low-inde…
This article describes the effect of the target magnetic field on the plasma process and the physical properties of films deposited by magnetically controlled rf and dc planar magnetron sputtering techniques. The target magnetic field, which is parallel to the target surface, is controlled and its’ strength is a key p…
Many experimental studies of protein deposition on solid surfaces involve alternating adsorption/desorption steps. In this paper, we investigate the effect of a desorption step (separating two adsorption steps) on the kinetics, the adsorbed-layer structure, and the saturation density. Our theoretical approach involves…
The opdA (prlC) gene of Salmonella enterica serovar Typhimurium and Escherichia coli encodes the metalloprotease oligopeptidase A (OpdA). We report that opdA is cotranscribed with a downstream open reading frame, yhiQ. Transcription of this operon is induced after a temperature shift (30 to 42 degrees C), and this ind…