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Photophysical and photoconductivity properties of thiol-functionalized graphene–CdSe QD composites

Joyashish Debgupta、Sadananda Mandal、Hemen Kalita 等 6 位作者2014-01-01RSC Advances

Graphene–semiconductor QD hybrid nanostructure materials have recently emerged as a new class of functional materials because of their potential applications in solar energy conversion, optoelectronic devices, sensing etc. Here, oleic acid-capped CdSe QDs are attached to –PhSH functionalized graphene by ligand exchang…

Graphene research and applications2D Materials and ApplicationsQuantum Dots Synthesis And Properties

Structural determination of protein-based polymer blends with a promising tool: combination of FTIR and STXM spectroscopic imaging

Shengjie Ling、Zeming Qi、Benjamin Watts 等 5 位作者2014-01-01Physical Chemistry Chemical Physics

Fourier transform infrared (FTIR) and scanning transmission X-ray microscopy (STXM) spectroscopic imaging techniques are introduced to determine the structure of protein-based polymer blends, using the silk fibroin/polyethylene oxide (SF/PEO) blend as a model material. We demonstrate that FTIR and STXM imaging techniq…

Proteins in Food SystemsPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Effects of the chemical structure of polyfluorene on selective extraction of semiconducting single-walled carbon nanotubes

Takahiro Fukumaru、Fumiyuki Toshimitsu、Tsuyohiko Fujigaya 等 4 位作者2014-01-01Nanoscale

The selective recognition/extraction of semiconducting (sem)- and metallic (met)-single-walled carbon nanotubes (SWNTs) is still a great challenge in the science and technology of carbon nanotubes because their selective synthesis is still difficult. Poly(9,9-dioctyl-fluorene-2,7-diyl) (2C8-PF) and its derivatives are…

Carbon Nanotubes in CompositesFullerene Chemistry and ApplicationsNanopore and Nanochannel Transport Studies

Tough strained fibers of a polyelectrolyte complex: pretensioned polymers

Qifeng Wang、Joseph B. Schlenoff2014-01-01RSC Advances

Polyelectrolyte complexes, long considered “unprocessible”, are transformed from brittle to tough by extrusion into highly strained fibers with a salt/temperature equivalence relaxation and efficient shape memory in hot water.

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Nucleation and nonisothermal crystallization kinetics in cross-linked polyethylene/zinc oxide nanocomposites

Josmin P. Jose、Laurent Chazeau、J.Y. Cavaillé 等 5 位作者2014-01-01RSC Advances

In the present study organic–inorganic hybrid nanocomposites of cross-linked polyethylene (XLPE) with 0, 2, 5 and 10 wt% of trimethoxyoctyl-silane surface treated ZnO nanoparticles were prepared by melt mixing.

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Strong negative nanocatalysis: oxygen reduction and hydrogen evolution at very small (2 nm) gold nanoparticles

Ying Wang、Eduardo Laborda、Kristina Tschulik 等 6 位作者2014-01-01Nanoscale

The electron transfer kinetics associated with both the reduction of oxygen and of protons to form hydrogen at gold nanoparticles are shown to display strong retardation when studied at citrate capped ultra small (2 nm) gold nanoparticles. Negative nanocatalysis in the hydrogen evolution reaction (HER) is reported for…

Electrocatalysts for Energy ConversionGold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials for catalytic reactions

Zero-field slow magnetic relaxation in a uranium( iii ) complex with a radical ligand

Joana T. Coutinho、M.A. Antunes、Laura C. J. Pereira 等 5 位作者2014-01-01Chemical Communications

[U(Tp(Me2))2(bipy˙)], a uranium(III) complex with a radical bipyridine ligand which has magnetic properties with contributions from both the ligand and the metal, presents slow relaxation of the magnetisation at low temperatures, already under zero static magnetic field, and energy barriers slightly above the non-radi…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Three-dimensional NiAl-mixed metal oxide film: preparation and capacitive deionization performances

Xiaodong Lei、Bo Wang、Junfeng Liu 等 7 位作者2014-01-01RSC Advances

A NiAl layered double hydroxide (NiAl-LDH) film was grown on the surface of a three-dimensional (3D) nickel foam by an in situ hydrothermal method using a nickel foam substrate as a nickel source, and boehmite (AlOOH) sol as an aluminium source.

Supercapacitor Materials and FabricationLayered Double Hydroxides Synthesis and ApplicationsMembrane-based Ion Separation Techniques

Series asymmetric supercapacitors based on free-standing inner-connection electrodes for high energy density and high output voltage

Jiayou Tao、Nishuang Liu、Jiangyu Rao 等 8 位作者2014-01-01Nanoscale

Asymmetric supercapacitors (ASCs) based on free-standing membranes with high energy density and high output voltage are reported. MnO(2) nanowire/carbon nanotube (CNT) composites and MoO(3) nanobelt/CNT composites are selected as the anode and the cathode materials of the devices, respectively. The ASC has a high volu…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Spiranic BODIPYs: a ground-breaking design to improve the energy transfer in molecular cassettes

Esther M. Sánchez‐Carnerero、Leire Gartzia‐Rivero、Florencio Moreno 等 9 位作者2014-01-01Chemical Communications

Boosted excitation energy transfer in spiranic O-BODIPY/polyarene cassettes, when compared with the parent non-spiranic (flexible) system, is highlighted as a proof for the ability of a new structural design to improve the energy transfer in molecular cassettes.

Organic Light-Emitting Diodes ResearchPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Synthesis and Characterization of Metal Sulfides Nanoparticles/Poly(methyl methacrylate) Nanocomposites

Peter A. Ajibade、Johannes Z. Mbese2014-01-01International Journal of Polymer Science

Metal sulfides nanoparticles in poly(methyl methacrylate) matrices were prepared and characterized by infrared spectroscopy, thermogravimetric analysis, powder X-ray diffraction, scanning electron microscope (SEM), and transmission electron microscope (TEM). The FTIR confirms the dispersion of the nanoparticles in PMM…

Polymer Nanocomposites and PropertiesThermal and Kinetic AnalysisMagnesium Oxide Properties and Applications

A femtogram level competitive immunoassay of mercury( ii ) based on surface-enhanced Raman spectroscopy

Yuzhen Wang、Shuai Chen、Chao Wei 等 8 位作者2014-01-01Chemical Communications

A femtogram level and specific surface enhanced Raman spectroscopy (SERS) based competitive immunoassay was developed to detect Hg(II) in aqueous solution for the first time. This novel approach provides an alternative, ultrasensitive and specific analytical method for the detection of Hg(II).

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesElectrochemical Analysis and Applications

Controlled synthesis and characterization of poly[methyl(3,3,3-trifluoropropyl)siloxane] with selective end groups

Hua‐Feng Fei、Wenchun Xie、Qian Wang 等 7 位作者2014-01-01RSC Advances

Controlled polymerization method to synthesize poly[methyl(3,3,3-trifluoropropyl)siloxane] with narrow molar mass distribution, broad “termination window”, selective end groups and quantitative transformation.

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Fluorescence quenching between unbonded graphene quantum dots and gold nanoparticles upon simple mixing

Yi Liu、Wei Quan Loh、Arundithi Ananthanarayanan 等 6 位作者2014-01-01RSC Advances

Fluorescence quenching is an interesting phenomenon that has been widely utilized in developing fluorescence-based sensors. However, most of the research focuses on the quencher and fluorophore in the bonded states. The fluorescence quenching between two unbonded nanostructures has been rarely studied. In this work, w…

Gold and Silver Nanoparticles Synthesis and ApplicationsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Blood Vessel-Derived Acellular Matrix for Vascular Graft Application

Luigi Dall’Olmo、Ilenia Zanusso、Rosa Di Liddo 等 7 位作者2014-01-01BioMed Research International

To overcome the issues connected to the use of autologous vascular grafts and artificial materials for reconstruction of small diameter (<6 mm) blood vessels, this study aimed to develop acellular matrix- (AM-) based vascular grafts. Rat iliac arteries were decellularized by a detergent-enzymatic treatment, whereas en…

Electrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative MedicineInfectious Aortic and Vascular Conditions

Immobilization of iodine into a hydroxyapatite structure prepared by cementation

Antoine Coulon、Danielle Laurencin、Agnès Grandjean 等 6 位作者2014-01-01Journal of Materials Chemistry A

A cementation route was developed to prepare an iodate-bearing apatite phase, in view of the long-term conditioning of radioactive iodine-129.

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear materials and radiation effects

Effect of γ-ray on optical characteristics of dyed PVA films

E. M. Antar2014-01-01Journal of Radiation Research and Applied Sciences

Poly vinyl alcohol doped with Crystal violet and carbol fuchsine films were prepared using dipping method. The spectral behavior and the effects of dose on the absorption coefficient α , optical energy gap, refractive index and extinction coefficient were investigated. The optical energy gap estimated and found to be…

Conducting polymers and applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation