Materials Literature
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Employing two isomeric pyrazine-based ligands a [2 x 2] grid-type tetranuclear cobalt(III) complex, incorporating doubly deprotonated (La)2- ligands, and a "corner-type" mononuclear cobalt(III) complex, incorporating neutral H2Lp ligands in a zwitterionic form, have been synthesised and structurally characterised.
In the CABRI-2 program, 12 tests were performed under various transient conditions covering a wide range of accident scenarios using two types of preirradiated fast breeder reactor (FBR) fuel pins with different smear densities and burnups. For each fuel, a nonfailure-transient test was performed, and it provided basi…
The genomes of more than 100 species have been sequenced, and the biological functions of encoded proteins are now actively being researched. Protein function is based on interactions between proteins and other molecules. One approach to assuming protein function based on genomic sequence is to predict interactions be…
The synthesis of new metal complexes based on imines derived from tris-(2-aminoethyl)amine (TREN) which exhibit different geometries depending on the metal [Cu(II), VO(IV), Pd(II), Ni(II), Ln(III)] has been carried out. TREN has three coordination positions which allow us to obtain different coordination complexes inv…
Acid catalyzed condensation of resorcinol or 2-methylresorcinol with 2 equiv. of an acetoxymethylpyrrole gave bis(pyrrolylmethyl)benzene derivatives in moderate yields; these afforded a series of novel aromatic benziporphyrins using the MacDonald "3 + 1" methodology.
The kinetics and mechanism of the initial steps in the oxidation of 2,4,6-trichlorophenol by hydrogen peroxide using iron(III) meso-tetra(4-sulfonatophenyl)porphine chloride as a catalyst were studied in this work. The first oxidation step is the formation of a substituted 1,4-benzoquinone. This step was also studied…
Liposomes composed of hydrogenated soya phosphatidylcholine (Emulmetik 950)/cholesterol/charged lipids [dicetyl phosphate (-) or stearylamine (+)] were developed. The hydrogenated soya phosphatidylcholine/cholesterol/charged lipid liposomes at molar ratios of 1:1:0, 7:2:0, 7:2:1 (-), and 7:2:1 (+), with and without th…
Using dense medium plasma technology, carbon magnetic nanoparticles (CMNP) were synthesized at room temperature and atmospheric pressure. Based on results from X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy and scanning electron microscopy, we conclude that these nanoparticles are composed o…
Bagging is a three-dimensional residual deformation, seen in used garments, which causes a deterioration in the appearance of the garment. The places it is seen during wear are elbows, knees, pockets, hips, and heels. The common factor in all of these parts of garments is the force exerted on that area of the fabric f…
It was found that doping of tiny ferroelectric particles to a nematic liquid crystal(LC)strongly affects dielectric properties of the system. The doping increases dielectric response of the LC due to interaction between LC molecules and particles, which possess large dipole moment and high polarisability. The suspensi…
Manganocene, Cp(2)Mn, has been employed as a precursor in the synthesis of a range of Mn(II) dimers of the type [CpMn(micro-X)](2)[X = 8-NHC(9)H(6)N (1), N(Ph)(C(5)H(4)N)(2), N(4-EtC(6)H(4))(C(5)H(4)N)(3) and C[triple bond]CPh (4)] as well as the bis-adduct [Cp(2)Mn[HN=C(NMe(2))(2)](2)](5). The solid-state structures…
Mesoporous Ce0.2Zr0.8O2 nanosized powders were synthesized via a hydrothermal method in the presence of urea without any templates using a trivalent cerium salt as the starting material. The analyses by medium-angle powder X-ray diffraction (PXRD) and vis-Raman spectroscopy showed that the Ce0.2Zr0.8O2 powders were so…
The effect of Co2+ ion on the magnetic properties of the sol–gel derived cobalt ferrite thin films (400 nm thickness) was studied. Films with different solution composition ([Co2+]/[Fe3+] = 0.5–1.0) were deposited on a Si substrate from the precursor containing an aqueous solution of FeCl3·6H2O and CoCl2·6H2O. Deposit…
Copper is a generally robust material that has beneficial properties to reduce biofilm formation and pathogen colonisation of pipes supplying potable water. However, a rare pitting corrosion can occur in soft, poorly buffered waters that can lead to pipe failure. This has been shown to be mediated by a copper-tolerant…
Stress relaxation behavior of banana fiber-reinforced polyester composites were investigated with special reference to the effect of fiber loading, fiber treatment, hybridization with glass fiber and also as woven fabric composites. It was observed that incorporation of fiber in the polyester matrix reduces the rate o…
In this paper, data on the performance of thin alumina layers as hydrogen barriers are presented for coatings deposited on Pd–Ag substrate at temperatures of 600, 873 and 1000 K with a filtered arc technique. The permeation reduction factor ranged from 10 to 100 depending on the structure of the deposited layer. Recom…
In this work, the interactions at low temperature (125 °C) of gaseous NH3, NO and O2 with carbon-supported manganese oxide catalysts have been extensively studied, mainly via step–response experiments, with the objective of explaining the low-temperature mechanism of the SCR reaction on such catalysts. To achieve this…
Tritium removal is a major unsolved development task for next-step devices with carbon plasma facing components. The 2–3 order of magnitude increase in duty cycle and associated tritium accumulation rate in a next-step tokamak will place unprecedented demands on tritium removal technology. The associated technical ris…
A novel proton-conducting material based on was developed and its electrical conduction properties were investigated by measuring conductivities under 0.4-5 kPa of and 0.01-100 kPa of at 573-973 K. conducted protons dominantly by partial substitution of Sr for La. Conductivities of the 1 mol % Sr-doped were to S cm −1…
The high benzene gas selectivity of mesoporous silicate (SBA-15) was observed in the sub-nanometre micropore condensation region. The benzene/toluene ratios of the adsorbed amount were >100 and >6 in ideal and pseudo-atmospheric environments, respectively.