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Up‐Conversion Photoluminescence in Polyfluorene Doped with Metal(II)–Octaethyl Porphyrins

Panagiotis E. Keivanidis、Stanislav Baluschev、Tzenka Miteva 等 7 位作者2003-12-11Advanced Materials

The up‐conversion photoluminescence (PL) in films of polyfluorene (PF) doped with metallated porphyrins is reported for the first time. The dependence of the up‐conversion process on the pump laser intensity and wavelength, the central metal moiety of the dopants, and the temperature is presented. Up‐conversion emissi…

Nonlinear Optical Materials StudiesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Current-Driven Switching in Magnetic Multilayer Nanopillars

S. Urazhdin、Norman O. Birge、W. P. Pratt Jr. 等 4 位作者2003-12-11arXiv

We summarize our recent findings on how the current-driven magnetization switching in nanofabricated magnetic multilayers is affected by an applied magnetic field, changes of temperature, magnetic coupling between the ferromagnetic layers, variations in the multilayer structure, and the relative rotation of the layers…

Materials Science

Sonic crystal lenses that obey Lensmaker's formula

Chao-Hsien Kuo、Zhen Ye2003-12-11arXiv

This paper presents a theoretical study of the phenomenon of acoustic imaging by sonic crystals, which are made of two-dimensional regular arrays of rigid cylinders placed in parallel in air. The scattering of acoustic waves is computed using the standard multiple scattering theory, and the band structures are compute…

Materials Science

Methods of calculation of a friction coefficient: Application to the nanotubes

J. Servantie、P. Gaspard2003-12-11arXiv

In this work we develop theoretical and numerical methods of calculation of a dynamic friction coefficient. The theoretical method is based on an adiabatic approximation which allows us to express the dynamic friction coefficient in terms of the time integral of the autocorrelation function of the force between both s…

Mesoscale and Nanoscale PhysicsMaterials Science

Quantitative Characterization of DNA Films by X-ray Photoelectron Spectroscopy

Dmitri Y. Petrovykh、Hiromi Kimura、Michael J. Tarlov 等 4 位作者2003-12-11Langmuir

We describe the use of self-assembled films of thiolated (dT)25 single-stranded DNA (ssDNA) on gold as a model system for quantitative characterization of DNA films by X-ray photoelectron spectroscopy (XPS). We evaluate the applicability of a uniform and homogeneous overlayer-substrate model for data analysis, examine…

Surface and Thin Film PhenomenaElectron and X-Ray Spectroscopy TechniquesAdvancements in Photolithography Techniques

Spin-dependent transport in phase-separated manganites

K. I. Kugel、A. L. Rakhmanov、A. O. Sboychakov 等 6 位作者2003-12-11arXiv

Starting from the assumption that ferromagnetically correlated regions exist in manganites even in the absence of long-range magnetic order, we construct a model of charge transfer due to the spin-dependent tunnelling of charge carriers between such regions. This model allows us to analyze the temperature and magnetic…

Materials ScienceStrongly Correlated Electrons

Radiative Relaxation Quantum Yields for Synthetic Eumelanin

Paul Meredith、Jenny Riesz2003-12-11arXiv

We report absolute values for the radiative relaxation quantum yield of synthetic eumelanin as a function of excitation energy. These values were determined by correcting for pump beam attenuation and emission re-absorption in both eumelanin samples and fluorescein standards over a large range of concentrations. Our r…

Materials ScienceSoft Condensed Matter

Simulations of cubic-tetragonal ferroelastics

A. E. Jacobs、S. H. Curnoe、R. C. Desai2003-12-11Physical review. B, Condensed matter

We study domain patterns in cubic-tetragonal ferroelastics by solving numerically equations of motion derived from a Landau model of the phase transition, including dissipative stresses. Our system sizes, of up to ${256}^{3}$ points, are large enough to reveal many structures observed experimentally. Most patterns fou…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesShape Memory Alloy Transformations

Biomolecule-Assisted Synthesis of Highly Ordered Snowflakelike Structures of Bismuth Sulfide Nanorods

Qingyi Lu、Feng Gao、Sridhar Komarneni2003-12-11Journal of the American Chemical Society

A biomolecule-assisted simple technique has been developed for the spontaneous ordering of the Bi2S3 nanorods into snowflakelike superstructures in high yield under microwave-hydrothermal conditions. In this method, glutathione (GSH) is used as both an assembling agent and a sulfur source. By controlling the molar rat…

Quantum Dots Synthesis And Properties2D Materials and ApplicationsChalcogenide Semiconductor Thin Films

Deformation twins in nanocrystalline Al

Xiaozhou Liao、Feng Zhou、Enrique J. Lavernia 等 5 位作者2003-12-11OpenAlex

Due to its high stacking fault energy, no deformation twin has ever been observed in coarse-grained Al. Recent molecular dynamic (MD) simulations predicted the formation of deformation twins in nanocrystalline (nc) Al. Here, we report transmission-electron-microscopic observations of two types of twins in nc Al proces…

Aluminum Alloy Microstructure PropertiesMicrostructure and mechanical propertiesAluminum Alloys Composites Properties

Competing stabilization mechanism for the polar ZnO(0001)-Zn surface

Georg Kresse、Olga Dulub、Ulrike Diebold2003-12-11OpenAlex

Density-functional calculations for the (0001)-Zn surface of wurtzite ZnO are reported. Different stabilization mechanisms, such as metallization of the surface layer, adsorption of OH groups or O adatoms, the formation of Zn vacancies, and large scale triangular reconstructions are considered. The calculations indica…

ZnO doping and propertiesGaN-based semiconductor devices and materialsCopper-based nanomaterials and applications

Phonon transport in nanowires coated with an amorphous material: An atomistic Green’s function approach

Natalio Mingo、Liu Yang2003-12-11OpenAlex

An approach is presented for the atomistic study of phonon transport in real dielectric nanowires via Green's functions. The formalism is applied to investigate the phonon flow through nanowires coated by an amorphous material. Examples for a simple model system and for real Si nanowires coated by silica are given. Ne…

Thermal properties of materialsAdvancements in Semiconductor Devices and Circuit DesignThermal Radiation and Cooling Technologies

Reversible Super-hydrophobicity to Super-hydrophilicity Transition of Aligned ZnO Nanorod Films

Xinjian Feng、Lin Feng、Meihua Jin 等 6 位作者2003-12-11OpenAlex

Remarkable surface wettability transition occurs with an inducement of ultraviolet (UV) for aligned ZnO nanorod films. The inorganic oxide films, which show super-hydrophobicity (left), become super-hydrophilic (right) when exposed to UV illumination. After the films are placed in the dark, the wettability evolves bac…

Surface Modification and SuperhydrophobicityLuminescence and Fluorescent MaterialsZnO doping and properties

Low Frequency Dielectric Study of Barium and Strontium Substituted Pb(Zn1/3Nb2/3)O3Ceramics

R. R. Vedantam、V. Subramanian、V. Sivasubramanian 等 4 位作者2003-12-10Japanese Journal of Applied Physics

The dielectric dispersion of the solid solutions (Pb 1- x Ba x )(Zn 1/3 Nb 2/3 )O 3 and (Pb 1- x Sr x )(Zn 1/3 Nb 2/3 )O 3 with x =0.2 and 0.3 has been studied as a function of temperature for the frequency range 0.1 to 200 kHz. The variation in the relaxor nature between the studied compounds is discussed using the g…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Structure and properties of the mesophase of syndiotactic polystyrene—III. Selective sorption of the mesophase of syndiotactic polystyrene

Shinji Mohri、D. Amutha Rani、Yusuke Yamamoto 等 5 位作者2003-12-10Journal of Polymer Science Part B Polymer Physics

Abstract Syndiotactic polystyrene (sPS) has various crystalline forms such as α, β, γ, and δ forms, and a mesophase depending on the preparation method. In this study, we focused on the mesophase with the molecular cavity of sPS, which is obtained by step‐wise extraction of the guest molecules from the sPS δ form. To…

Polymer Nanocomposites and PropertiesMembrane Separation and Gas TransportPolymer crystallization and properties

Kinetic features of the nonisothermal oxidative degradation of ethylene vinyl acetate copolymers

L. V. Ruban、O. V. Sychugova、Н. Н. Колесникова 等 4 位作者2003-12-10Journal of Applied Polymer Science

Abstract Thermogravimetric analysis was used for a comparative investigation of the thermooxidative decomposition of ethylene vinyl acetate (EVA) copolymers with different vinyl acetate (VA) group contents. There were two stages of mass loss in this process. It was revealed that the apparent activation energies were c…

Inorganic and Organometallic ChemistryPolymer Science and PVCThermal and Kinetic Analysis

Preparation and Ferroelectric Properties of Lanthanum Modified Sr0.8Bi2.2Ta2O9Thin Films

Yu Zhong、Guangda Hu、Ting-Ao Tang2003-12-10Japanese Journal of Applied Physics

La modified Sr 0.8 Bi 2.2 Ta 2 O 9 (SLBT) thin films were fabricated on Pt/Ti/SiO 2 /Si substrates by metalorganic decomposition. All the films were annealed at 800°C using a rapid thermal annealing furnace. X-ray diffraction analysis indicated that single-phase layered perovskite SLBT ferroelectric thin films can be…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisAcoustic Wave Resonator Technologies

Preparation of the polymer–clay nanocomposites in exfoliated state by interface stabilization

Sang‐Soo Lee、Junkyung Kim2003-12-10Journal of Polymer Science Part B Polymer Physics

Abstract To suppress the repulsive interfacial energy between hydrophilic clay and a hydrophobic polymer matrix for polymer–clay nanocomposites, a third component of amphiphilic nature such as poly(ϵ‐caprolactone) (PCL) was introduced into the styrene–acrylonitrile copolymers (SAN)/Na‐montmorillonite system. Once ϵ‐ca…

biodegradable polymer synthesis and propertiesPolymer Nanocomposite Synthesis and IrradiationPolymer Nanocomposites and Properties

Holographic grating for dense wavelength division optical filters at 1550 nm using phenanthrenquinone-doped poly(methyl methacrylate)

Atsushi Sato、Raymond K. Kostuk2003-12-10Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

The characteristics of Phenanthrenquinone (PQ) doped Polymethyl methacrylate (PMMA) for recording edge-illuminated holographic spectral filters for dense wavelength division multiplexing applications are evaluated. Filter design includes the effects of material absorption and apodization of the index profile. Rigorous…

Photonic and Optical DevicesAdvanced Fiber Optic SensorsOptical Coatings and Gratings

A Pair of New C-21 Steroidal Glycoside Epimers from the Roots of Cynanchum paniculatum

Shun‐Lin Li、Hua Tan、Yuemao Shen 等 5 位作者2003-12-10Journal of Natural Products

Two new C-21 steroidal glycoside epimers, paniculatumosides A and B (1 and 2), based on a 13,14:14,15-disecopregnane-type skeleton, with neocynapanogenin B (3) and neocynapanogenin C (4) as two new aglycons, were isolated from the roots of Cynanchum paniculatum. Their structures were determined by spectral data interp…

Phytochemistry and Bioactive CompoundsPhytochemistry and Bioactivity StudiesPhytochemical compounds biological activities