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Landau-Level Splitting in Graphene in High Magnetic Fields

Y. Zhang、Zhigang Jiang、Joshua P. Small 等 10 位作者2006-04-06OpenAlex

The quantum Hall (QH) effect in two-dimensional electrons and holes in high quality graphene samples is studied in strong magnetic fields up to 45 T. QH plateaus at filling factors $\ensuremath{\nu}=0,\ifmmode\pm\else\textpm\fi{}1,\ifmmode\pm\else\textpm\fi{}4$ are discovered at magnetic fields $B>20\text{ }\text{…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Fast and Reversible Surface Redox Reaction in Nanocrystalline Vanadium Nitride Supercapacitors

Daiwon Choi、George E. Blomgren、Prashant N. Kumta2006-04-06OpenAlex

Modification of the surface chemistry of nanocrystalline VN yields a new class of supercapacitors that deliver an impressive specific capacitance. The creation of surface nanolayers of VOx (poor electronic conductivity) on the electronically conductive nanocrystalline VN shown in the figure and on the cover gives rise…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationMXene and MAX Phase Materials

Homopolymer Solubilization and Nanoparticle Encapsulation in Diblock Copolymer Micelles

Michelle D. Lefebvre、Kenneth R. Shull2006-04-05Macromolecules

We use self-consistent mean-field theory to investigate a system of A homopolymer, AB copolymer, and C homopolymer, where there are attractive interactions between the B and C components. We calculate volume fraction profiles and chemical potentials of formation for unswollen micelles, swollen micelles, and flat inter…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsBlock Copolymer Self-Assembly

Modification of chitosan towards a biomaterial with improved physico‐chemical properties

P. Mallika、A. Himabindu、D Shailaja2006-04-05Journal of Applied Polymer Science

Abstract Modification of chitosan (CTN), a natural biomaterial, leading to improved physical and chemical properties makes the polymer overcome the limitations on its application in biomedical fields. We have modified CTN using polyvinylpyrrolidone (PVP) in three ways, i.e., by blending (CTN : PVP), by graft copolymer…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Building on the WLF/Free Volume Framework: Utilization of the Coupling Model in the Relaxation Dynamics of the Gelatin/Cosolute System

Stefan Kasapis2006-04-05Biomacromolecules

The onset of softening in the glass transition dispersion of the gelatin/cosolute system at 78% solids was examined using the stress relaxation modulus and dynamic oscillatory data on shear. Measurements were made between 5 and -70 degrees C, and isothermal runs were reduced to a master curve covering 21 orders of mag…

Material Dynamics and PropertiesBee Products Chemical AnalysisMicroencapsulation and Drying Processes

Magnetic dipolar ordering and relaxation in the high-spin molecular cluster compoundMn6

Andrea Morello、F. L. Mettes、O. N. Bakharev 等 8 位作者2006-04-05Physical Review B

Few examples of magnetic systems displaying a transition to pure dipolar magnetic order are known to date. As was recently shown, within the newly discovered class of single-molecule magnets, quite attractive examples of dipolar magnetism may be found. The molecular cluster spins and thus their dipolar interaction ene…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Differential, time-dependent effects of perivenous application of fibrin glue on medial thickening in porcine saphenous vein grafts☆

Song Wan、Ahmed A. Arifi、Michael C. W. Chan 等 8 位作者2006-04-05European Journal of Cardio-Thoracic Surgery

OBJECTIVE: Neointimal and medial thickening play a critical role in late vein graft failure following CABG. Previous ex vivo experiment suggested that perivenous application of fibrin glue may reduce the damage in the circular smooth muscle cell layer of the media of the vein graft shortly after exposing to arterial p…

Electrospun Nanofibers in Biomedical ApplicationsCardiac and Coronary Surgery TechniquesInfectious Aortic and Vascular Conditions

Maghnite‐H+ as a cationic catalyst in the synthesis of poly(1,3‐dioxolane) and α,ω‐methacryloyloxy‐poly(1,3‐dioxolane)

Radja Megherbi、Mohammed Belbachir、Rachid Méghabar2006-04-05Journal of Applied Polymer Science

Abstract The polymerization of 1,3‐dioxolane catalyzed by Maghnite‐H +; (Mag‐H + ), a montmorillonite sheet silicate clay exchanged with protons, was investigated. The cationic ring‐opening polymerization of 1,3‐dioxolane was initiated by Mag‐H + at different temperatures (20, 30, 50, and 70°C) in bulk and in a solven…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

FMR investigations of half‐metallic ferromagnets

Bulat Rameev、F. Yıldız、S. Kazan 等 13 位作者2006-04-05physica status solidi (a)

Abstract Thin films of various half‐metallic ferromagnets, such as chromium dioxide (CrO 2 ) and Heusler alloys (Co 2 Cr 0.6 Fe 0.4 Al, Co 2 MnSi) have been investigated by ferromagnetic resonance (FMR) technique. It is demonstrated that FMR is a very efficient method to study the nanoscale magnetic properties, in par…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesHeusler alloys: electronic and magnetic properties

Devitrification of colloidal glasses in real space

Nikoleta B. Simeonova、Roel P. A. Dullens、Dirk G. A. L. Aarts 等 6 位作者2006-04-05Physical Review E

Confocal scanning laser microscopy has been used to quantitatively analyze the structure and dynamics of concentrated suspensions of spherical colloids in which the magnitude of the short-range attractive potential is increased by adding nonadsorbing polymers. These systems undergo a reentrant glass transition upon in…

Plant Water Relations and Carbon DynamicsPhase Equilibria and ThermodynamicsMaterial Dynamics and Properties

Enzyme‐Catalyzed Preparation of Aliphatic Polythioester by Direct Polycondensation of Diacid Diester and Dithiol

Makoto Katô、Kazunobu Toshima、Shuichi Matsumura2006-04-05Macromolecular Rapid Communications

Abstract Summary: Aliphatic dithiol‐diacid type polythioesters were first enzymatically prepared by the direct polycondensation of hexane‐1,6‐dithiol and diacid diesters using the immobilized lipase from Candida antarctica (lipase CA). As a typical example, diethyl sebacate and hexane‐1,6‐dithiol were polymerized usin…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisChemistry and Chemical Engineering

Nanoscale Conductivity Mapping of Hybrid Nanoarchitectures: Ultrathin Poly(o-phenylenediamine) on Mesoporous Manganese Oxide Ambigels

Todd M. McEvoy、Jeffrey W. Long、Timothy J. Smith 等 4 位作者2006-04-05Langmuir

We use conductive-probe atomic force microscopy (CP-AFM) to characterize and image hybrid electrode structures comprising mesoporous manganese oxide (MnO2) ambigel nanoarchitectures coated with an ultrathin (<10 nm) electrodeposited layer of poly(o-phenylenediamine), PPD. Native MnO2 ambigel films, supported on indium…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

Toughening modification of PBT/PC blends with PTW and POE

Huiyu Bai、Yong Zhang、Yong Zhang 等 7 位作者2006-04-05Journal of Applied Polymer Science

Abstract New toughened poly(butylene terephthalate) (PBT)/bisphenol A polycarbonate (PC) blends were obtained by melt blending with ethylene–butylacrylate–glycidyl methacrylate copolymer (PTW) and ethylene‐1‐octylene copolymer (POE) in a twin‐screw extruder. The mechanical properties of PBT/PC blends were investigated…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Negative Poisson Ratio of Crystalline Cellulose in Kraft Cooked Norway Spruce

Marko Peura、Ingo Grotkopp、H. Lemke 等 7 位作者2006-04-05Biomacromolecules

The tensile properties of kraft cooked Norway spruce were studied by tensile testing with in situ X-ray diffraction (XRD). Samples were of earlywood, cooked for varying times. The total lignin content of the samples was between 21.7% and 9.3%. Tensile tests with XRD were performed on wet samples, without XRD on dry sa…

Wood Treatment and PropertiesAdvanced Cellulose Research StudiesLignin and Wood Chemistry

The Reaction of Phosphohexomutase from Pseudomonas aeruginosa

C.A. Regni、Andrew M. Schramm、Lesa J. Beamer2006-04-05Journal of Biological Chemistry

The enzyme phosphomannomutase/phosphoglucomutase (PMM/PGM) from Pseudomonas aeruginosa catalyzes the reversible conversion of 1-phospho to 6-phospho-sugars. The reaction entails two phosphoryl transfers, with an intervening 180 degrees reorientation of the reaction intermediate (e.g. glucose 1,6-bisphosphate) during c…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionBiochemical and Molecular Research

Spectroscopy and nonlinear microscopy of Au nanoparticle arrays: Experiment and theory

Andreas Hohenau、Joachim R. Krenn、Jonas Beermann 等 7 位作者2006-04-05Physical Review B

Regular arrays of rectangular gold nanoparticles on glass substrates are characterized by using linear extinction spectroscopy (in the wavelength range of $450--950\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$) and nonlinear scanning optical microscopy, in which two-photon photoluminescence (TPL) excited with a strongly foc…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNonlinear Optical Materials Studies

Effect of Drawing Induced Dispersion of Nano‐Silica on Performance Improvement of Poly(propylene)‐Based Nanocomposites

Wen Hong Ruan、Xian Bo Huang、Xian Hou Wang 等 5 位作者2006-04-05Macromolecular Rapid Communications

Abstract Summary: A new route that combines graft pre‐treatment and drawing techniques with melt mixing to prepare nanoparticle‐filled thermoplastic polymer composites is reported. Nano‐SiO 2 particles are first modified by graft polymerization and then the grafted nanoparticles are melt‐compounded with poly(propylene…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Atomistic Molecular Modeling of the Effect of Chromophore Concentration on the Electro-optic Coefficient in Nonlinear Optical Polymers

Megan R. Leahy-Hoppa、Paul D. Cunningham、Joseph A. French 等 4 位作者2006-04-05The Journal of Physical Chemistry A

We employ fully atomistic molecular modeling to investigate the concentration dependence of the electro-optic coefficient of two guest-host polymer composites. Using classical molecular dynamics, we record the time-evolution of the guest-host system under the application of an external electric field. Through analysis…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

A sandwich beam with electrostatically tunable bending stiffness

Andrea Bergamini、R. Christen、B Maag 等 4 位作者2006-04-05Smart Materials and Structures

The tuning of the bending stiffness of structural elements is of interest for, among other things, the suppression of vibrations related to resonance phenomena. For a given cross-sectional area and geometry, the variation of the elastic properties of the material composing the structure provides a viable approach to t…

Shape Memory Alloy TransformationsAeroelasticity and Vibration ControlStructural Analysis and Optimization

Enhanced Electrocatalysis for the Reduction of Hydrogen Peroxide at New Multiwall Carbon Nanotube Grafted Polydiphenylamine Modified Electrode

P. Santhosh、Kalayil Manian Manesh、Yi‐Chia Lee 等 4 位作者2006-04-05Electroanalysis

Abstract A new modified electrode having multiwall carbon nanotube (MWNT) grafted with polydiphenylamine (PDPA) as electrocatalytic layer is fabricated. FESEM image of the modified electrode shows a different morphology indicating the grafting of PDPA over MWNT. This morphology is in quite contrast from the convention…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications