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Comment on “The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh 4 (CO) 12 ] and [Rh 6 (CO) 16 ]” by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D

Brian T. Heaton、Elena V. Grachova、Sergey P. Tunik 等 4 位作者2015-01-01Dalton Transactions

Experimental results (recent IR, DFT calculations and modern multinuclear NMR measurements on Rh-containing clusters, together with earlier VT multinuclear NMR measurements) show that the use of the Ligand Polyhedral Model (LPM) to provide a general mechanism for ligand fluxionality in Transition Metal Carbonyl Cluste…

Organometallic Complex Synthesis and CatalysisRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Toward a robust porous coordination polymer: the inhibition of mutual movement between interpenetrating sub-networks by introduction of multiple C–H⋯π interactions

Xiang Jiang、Hui‐Zhong Kou2015-01-01RSC Advances

We demonstrate that a robust porous coordination polymer can be achieved by introduction of multiple C–H⋯π interactions between diamonded sub-networks.

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesCovalent Organic Framework Applications

Photoactive amphiphiles for the assembly of supramolecular architectures

Benjamin P. Jarman、Fabio Cucinotta2015-01-01Faraday Discussions

The presented study reports the use of photoactive templating structures for the design of porous frameworks with built-in optical functionalities. The materials have been synthesised and characterised using powder X-ray diffractometry, UV-visible absorption and emission spectroscopy. The latter shows that, by varying…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Fabrication and Output Characteristics of a Belt-Driven Type Heat-Engine Using Shape Memory Alloy Spiral Spring Actuators

Takahiro Morita、Yasumasa Nishimura、Hiroumi Fujiki 等 6 位作者2015-01-01Transactions of the Materials Research Society of Japan

Shape memory alloys (SMAs) have been employed to apply to heat-engines using low temperature thermal energy (such as hot exhaust heat and hot spring water). However, since previous SMA heat-engines use wire- or coil-shape SMA elements, it is necessary to increase the applied strain of SMA elements for increasing engin…

Shape Memory Alloy Transformations

The impact of the thermal conductivity of a dielectric layer on the self-heating effect of a graphene transistor

Taisong Pan、Min Gao、Zhenlong Huang 等 6 位作者2015-01-01Nanoscale

The self-heating effect of a graphene transistor on the transport properties was studied. Different dielectric layers, SiO2 and AlN, which have different thermal conductivities, were used to tune the thermal dissipation of the graphene transistor. An obvious change in channel resistance and a shift of charge neutralit…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Polyethylenimine/grapefruit peel hybrid biosorbent for the removal of toxic CdTe quantum dots from water

Ying Zhang、Baozhu Hu、Yuming Huang2015-01-01RSC Advances

The polyethyleneimine (PEI)-decorated grapefruit peel (GP) composites were facilely prepared by a simple one-step reaction and served as adsorbents for the efficient removal of CdTe quantum dots as one of the emerging pollutants of water.

Quantum Dots Synthesis And PropertiesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Interaction between Iron Oxide Nanoparticles and HepaRG Cells: A Preliminary In Vitro Evaluation

Maxime Helvenstein、Dimitri Stanicki、Sophie Laurent 等 4 位作者2015-01-01Journal of Nanomaterials

Nowadays, the use of iron oxide nanoparticles is widespread to label cells for magnetic resonance imaging tracking. More recently, magnetic labeling provides promising new opportunities for tissue engineering by controlling and manipulating cells through the action of an external magnetic field. The present work descr…

Nanoparticle-Based Drug DeliveryMicrofluidic and Bio-sensing TechnologiesElectrohydrodynamics and Fluid Dynamics

Rational design of a degradable polyanion for layer-by-layer assembly for encapsulation and release of cationic functional biomolecules

Ryuichi Hiraoka、Yuichi Funasaki、Jun Ishii 等 4 位作者2015-01-01Chemical Communications

A novel degradable polyanion, poly(phthalic ethylene glycol ester), was synthesized in one pot in a single step. The degradable polyanion assembles with various polycations to form layer-by-layer films that can encapsulate physiologically active biomolecules. Polyanion degradation can induce film disassembly and relea…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Real time imaging of the growth of silver ribbons by evanescent wave microscopy

Angshuman Pal、Panart Khajornrungruang、S. V. Babu2015-01-01RSC Advances

Real time visualization of the in situ growth of ∼40 μm long silver ribbons, synthesized by template-free galvanic displacement using ∼100 nm Cu particles and Ag ions in aqueous conditions, is demonstrated using evanescent wave microscopy.

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

Ab initio calculation of band alignment of epitaxial La2O3 on Si(111) substrate

A. Debernardi、CNR-IMM, ss Agrate Brianza, via C. Olivetti 2, I-20864, Agrate Brianza, Italy, European Union2015-01-01AIMS Materials Science

By means of plane wave pseudopotential method we have studied the electronic properties of the heterostructure formed by an high dielectric constant (k) oxide, the hexagonal La2O3 epitaxially grown with (0001)-orientation on Si (111) substrate. We found that for La2O3 both the dielectric constant along the growth dire…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Synthesis and photocatalytic activity of N-K 2 Ti 4 O 9 /UiO-66 composites

Sunfeng Li、Xing Wang、Qi Chen 等 8 位作者2015-01-01RSC Advances

N-K 2 Ti 4 O 9 /UiO-66 composites synthesized by a facile solvothermal method possess a hierarchical core–shell structure with UiO-66 forming the shell around the N-K 2 Ti 4 O 9 core.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

The luminescence inner filter effect of Mn 2+ -doped (ZnS) 2 ·octylamine inorganic/organic hybrid thin films and their sensor application for environmental contaminants

Yu Chen、Jinhui Wang、Jing Li 等 5 位作者2015-01-01RSC Advances

The inner filter effect (IFE) for Mn 2+ luminescence of (ZnS:Mn) 2 ·octylamine hybrid thin film was investigated and verified by detecting three selected environmental contaminant species, which indicated that it was a good IFE-based fluorescence sensor.

Luminescence Properties of Advanced MaterialsLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes

A Study Of Distinctive Characteristics Of Soaps Made Of Saw Dust Ash (Lye ) With Palm And Olive Oils And Their Oil Blends In Benue State Nigeria.

C I Beetseh、J Godwin2015-01-01Journal of environment and earth science

In Benue State Nigeria saw dust is dumped in large quantities as waste while in other parts of the country it is used in producing ceiling boards and plywood . In order to further explore its use, palm oil and olive oil with saw dust ash as the source of alkali (lye) were used in the production of soap and the choice…

Polymer Science and PVC

Chemo-, regio-, and stereo-selective perfluoroalkylations by a Grignard complex with zirconocene

Motohiro Fujiu、Kazuyuki Negishi、Jie Guang 等 6 位作者2015-01-01Dalton Transactions

The synthesis of highly reactive perfluoroalkyl Grignard reagents with early transition metal zirconocene complexes and their new types of highly chemo-, regio-, and stereo-selective perfluoroalkylation reactions are reported with epoxides in particular. The zirconocene complex is advantageous in activating the perflu…

Porphyrin and Phthalocyanine ChemistryFluorine in Organic ChemistryInorganic Fluorides and Related Compounds

Programmable self-assembly of a cystamine-block copolymer in response to pH and progressive reduction–ionization–oxidation

Hui Shi、Kaiyi Zhou、Qiuping Yu 等 7 位作者2015-01-01Polymer Chemistry

A water-soluble cystamine-block copolymer undergoes air/pH-mediated programmable self-assembly/reconstructions simply stemming from the unique environment-mediated reaction complexity of the cystamine-functionalized unit.

Advanced Polymer Synthesis and CharacterizationMolecular Sensors and Ion DetectionSupramolecular Self-Assembly in Materials

Tetrathiafulvalene-based nanocrystals: site-selective formation, device fabrication, and electrical properties

Hiroyuki Hasegawa2015-01-01Journal of Materials Chemistry C

A tetrathiafulvalene (TTF)-based nanocrystal was selectively synthesized only in the gap between two electrodes using a nanoscale electrocrystallization. A two-terminal TTF-based device and an FET could be readily obtained via an eco-friendly nanofabrication process.

Advanced Memory and Neural ComputingElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices

Molecular Dynamics Simulations of the Nucleotides and Metallic Nanoparticles Interaction on a Carbon Nanotube Matrix

Mirzoaziz Khusenov、Ermuhammad Dushanov、Kholmirzo Kholmurodov2015-01-01MATERIALS TRANSACTIONS

We simulated the interaction of the small nucleotide chain (NC) with gold nanoparticles (NPs) inside carbon nanotube (CNT) of an open ended boundary. Such system represents a great interest in many aspects of today biochemical and nanotechnological research (diagnostic applications, drug delivery in cell, nanorobotic…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresNanopore and Nanochannel Transport Studies

Degradability in vitro of polyurethanes based on synthetic atactic poly[(R,S)-3-hydroxybutyrate]

Joanna Brzeska、Henryk Janeczek、Helena Janik 等 5 位作者2015-01-01Bio-Medical Materials and Engineering

The aim of the present study was to determine the degradability of aliphatic polyurethanes, based on a different amount of synthetic, atactic poly[(R,S)-3-hydroxybutyrate] (a-PHB), in hydrolytic (phosphate buffer) and oxidative (H2O2/CoCl2) solutions. The soft segments were built with atactic poly[(R,S)-3-hydroxybutyr…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionPolymer composites and self-healing