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Harmful Effects of Nanoparticles on Animals

Jean‐Marie Exbrayat、Elara Moudilou、Emmanuel Lapied2015-01-01Journal of Nanotechnology

Since several years nanoparticles (NPs) are produced by industries and used in several fields of activities. They are finally found in aquatic and terrestrial environments, where they are ingested by living organisms in which they accumulate, before being eliminated. In organisms, NPs represent foreign elements with t…

Nanoparticles: synthesis and applicationsMicroplastics and Plastic PollutionHeavy Metal Exposure and Toxicity

Light emitting diodes based on carbon dots derived from food, beverage, and combustion wastes

Prashant K. Sarswat、Michael L. Free2015-01-01Physical Chemistry Chemical Physics

One important resource for material synthesis is waste. Utilization of waste as a resource for material synthesis is an environmentally responsible approach that reduces the need for virgin resources and subsequent processing. In this report a method to produce multicolored, luminescent carbon dots (CDs) and subsequen…

Mercury impact and mitigation studiesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Tunable emission in lanthanide coordination polymer gels based on a rationally designed blue emissive gelator

Papri Sutar、Venkata M. Suresh、Tapas Kumar Maji2015-01-01Chemical Communications

Rational design and synthesis of a new low molecular weight gelator (LMWG) having 9,10-diphenylanthracene core and terminal terpyridine is reported. Tb(III) and Eu(III) ion coordination to a LMWG results in green and pink emissive coordination polymer gels, respectively, with coiled nanofiber morphology. Further, cont…

Nanoplatforms for cancer theranosticsSupramolecular Self-Assembly in MaterialsNanocluster Synthesis and Applications

Aqueous solution/metal interfaces investigated in operando by photoelectron spectroscopy

Osman Karslıoğlu、Slavomír Nemšák、Ioannis Zegkinoglou 等 20 位作者2015-01-01Faraday Discussions

We describe a new in operando approach for the investigation of heterogeneous processes at solid/liquid interfaces with elemental and chemical specificity which combines the preparation of thin liquid films using the meniscus method with standing wave ambient pressure X-ray photoelectron spectroscopy [Nemšák et al., N…

Spectroscopy and Quantum Chemical StudiesElectrochemical Analysis and ApplicationsElectron and X-Ray Spectroscopy Techniques

Synthesis of a conjugated porous Co( ii ) porphyrinylene–ethynylene framework through alkyne metathesis and its catalytic activity study

Guolong Lu、Haishen Yang、Youlong Zhu 等 7 位作者2015-01-01Journal of Materials Chemistry A

We present the development of a conjugated porous Co( ii ) porphyrinylene–ethynylene framework as an efficient oxygen reduction catalyst through alkyne metathesis polymerization.

Porphyrin and Phthalocyanine ChemistrySynthetic Organic Chemistry MethodsCovalent Organic Framework Applications

What makes a good graphene-binding peptide? Adsorption of amino acids and peptides at aqueous graphene interfaces

Zak E. Hughes、Tiffany R. Walsh2015-01-01Journal of Materials Chemistry B

Investigation of the non-covalent interaction of biomolecules with aqueous graphene interfaces is a rapidly expanding area. However, reliable exploitation of these interfaces in many applications requires that the links between the sequence and binding of the adsorbed peptide structures be clearly established. Molecul…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsGraphene and Nanomaterials Applications

Aggregation-induced circularly polarized luminescence of an (R)-binaphthyl-based AIE-active chiral conjugated polymer with self-assembled helical nanofibers

Shuwei Zhang、Yuan Sheng、Wei Guo 等 6 位作者2015-01-01Polymer Chemistry

An AIE-active chiral conjugated polymer P-1 exhibited aggregation-induced circularly polarized luminescence. The TEM and AFM images show that P-1 self-assembled into helical nanofibers during aggregation.

Luminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in Materials

Shape control in engineering of polymeric nanoparticles for therapeutic delivery

John‐Michael Williford、José Luís Santos、Rishab Shyam 等 4 位作者2015-01-01Biomaterials Science

Nanoparticle-mediated delivery of therapeutics holds great potential for the diagnosis and treatment of a wide range of diseases. Significant advances have been made in the design of new polymeric nanoparticle carriers through modulation of their physical and chemical structures and biophysical properties. Nanoparticl…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Porous BN for hydrogen generation and storage

Hui Zhang、Chuan‐Jia Tong、Yongsheng Zhang 等 5 位作者2015-01-01Journal of Materials Chemistry A

Hydrogen is a highly appealing renewable energy resource, while hydrogen generation and storage for practical applications remain a great challenge at present. The proposed porous p-BN has both good hydrogen generation and storage ability which can be dramatically enhanced by C-dopant and Li-decoration.

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Real-time monitoring of the mitophagy process by a photostable fluorescent mitochondrion-specific bioprobe with AIE characteristics

Weijie Zhang、Ryan T. K. Kwok、Yilong Chen 等 9 位作者2015-01-01Chemical Communications

An isothiocyanate-functionalized tetraphenylethene is synthesized and used as a fluorescent bioprobe for mitochondrion imaging with high specificity and photostability. The covalent conjugation of the bioprobe to mitochondrial proteins endows it with high resistance to microenvironmental changes, enabling it for real-…

Molecular Sensors and Ion DetectionMass Spectrometry Techniques and ApplicationsLuminescence and Fluorescent Materials

Hybridizing wood cellulose and graphene oxide toward high-performance fibers

Yuanyuan Li、Hongli Zhu、Shuze Zhu 等 11 位作者2015-01-01NPG Asia Materials

High-performance microfibers such as carbon fibers are widely used in aircraft and wind turbine blades. Well-aligned, strong microfibers prepared by hybridizing two-dimensional (2D) graphene oxide (GO) nanosheets and one-dimensional (1D) nanofibrillated cellulose (NFC) fibers are designed here for the first time and h…

Graphene research and applicationsAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Nanostructured Polypyrrole Powder: A Structural and Morphological Characterization

Edgar Aparecido Sanches、Scarlat F. Alves、Juliana Coatrini Soares 等 7 位作者2015-01-01Journal of Nanomaterials

Polypyrrole (PPY) powder was chemically synthesized using ferric chloride (FeCl 3 ) and characterized by X‐ray diffraction (XRD), Le Bail Method, Fourier Transform Infrared Spectrometry (FTIR), and Scanning Electron Microscopy (SEM). XRD pattern showed a broad scattering of a semicrystalline structure composed of main…

Ferroelectric and Piezoelectric MaterialsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Probing charge transfer excitons in a MoSe 2 –WS 2 van der Waals heterostructure

Frank Ceballos、Matthew Z. Bellus、Hsin‐Ying Chiu 等 4 位作者2015-01-01Nanoscale

We show that the van der Waals heterostructure formed by MoSe2 and WS2 provides a unique system with near degenerate interlayer and intralayer excitonic states. Photoluminescence measurements indicate that the charge transfer exciton states are approximately 50 meV below the MoSe2 exciton states, with a significant sp…

Graphene research and applicationsPerovskite Materials and Applications2D Materials and Applications

A generalised space-charge theory for extended defects in oxygen-ion conducting electrolytes: from dilute to concentrated solid solutions

David S. Mebane、Roger A. De Souza2015-01-01Energy & Environmental Science

The standard Poisson–Boltzmann approach to modeling the near-interface defect behaviour in solid electrolytes performs well at low dopant concentrations but its applicability is questionable at higher dopant levels where interactions become important.

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsElectronic and Structural Properties of Oxides

Broadly tunable graphene plasmons using an ion-gel top gate with low control voltage

Hai Hu、Feng Zhai、Debo Hu 等 7 位作者2015-01-01Nanoscale

The electrostatic tunability of graphene is vital in the field of active plasmons and would be beneficial in tunable infrared and terahertz optical element applications. The key to realizing broad tunability is achieving high carrier densities in graphene. Here we use an ion-gel, currently one of the most efficient di…

Graphene research and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research

Imaging chemical concentration pattern and early stages of spinodal decomposition in the AgxNa1−xBr system by scanning force microscopy

F Güthoff、B Zhang、G Eckold2015-01-01Materials Research Express

In quasi binary systems like AgBr–NaBr the demixing from the homogeneous high temperature phase into separated phases is a complex process that depends on the ageing temperature as well as on the quench rate. Spinodal decomposition and nucleation processes can be distinguished which lead, however, to the same final eq…