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Nanostructured Porous Silicon–Polymer-Based Hybrids: From Biosensing to Drug Delivery

Lisa M. Bonanno、Ester Segal2011-11-29Nanomedicine

Organic-inorganic hybrids with controlled morphology at the nanometer scale represent an exciting class of materials that can display unique properties that are culminated by the characteristics of each building block. Recent research highlights their potential as biomimetic composites and application in biosensing, l…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsAnalytical Chemistry and Sensors

Optimum oxygen content in La0.7Sr0.3MnO3 thin films

Yu. M. Nikolaenko、V. N. Varyukhin、Yu. V. Medvedev 等 7 位作者2011-11-29arXiv

The technological conditions of oxygen content variation in epitaxial La0.7Sr0.3MnO3-δ films and the peculiarities of change of their transport characteristics were investigated. The films were grown onto single crystal SrTiO3 substrates by an enhanced method of dc magnetron sputtering of a ceramic target. It was reve…

Materials Science

Van der Waals Interactions in DFT using Wannier Functions: improved $C_6$ and $C_3$ coefficients by a new approach

A. Ambrosetti、P. L. Silvestrelli2011-11-29arXiv

A new implementation is proposed for including van der Waals interactions in Density Functional Theory using the Maximally-Localized Wannier functions. With respect to the previous DFT/vdW-WF method, the present DFT/vdW-WF2 approach, which is based on the simpler London expression and takes into account the intrafragm…

cond-mat.otherMaterials ScienceStrongly Correlated Electronsquant-ph

Single crystal growth by self-flux method of the mixed valence gold halides Cs$_2$[Au$^{I}$X$_2$][Au$^{III}$X$_4$] (X=Br,I)

Scott C. Riggs、M. C. Shapiro、F. Corredor 等 7 位作者2011-11-29arXiv

High quality single crystals of Cs$_2$Au$_2$X$_6$ (X=Br,I) were grown using a ternary self-flux method. Structural refinements based on single crystal X-ray diffraction measurements show that both materials have a distorted perovskite structure belonging to the I4/mmm space group with full site occupancy. Transport me…

Materials Science

Electric potential of the electron sound wave: Sharp disappearance in the superconducting state

Yu. A. Avramenko、E. V. Bezuglyi、N. G. Burma 等 4 位作者2011-11-29arXiv

We study the ac electric potential induced by the electron sound wave (a perturbation of the electron distribution function propagating with the Fermi velocity) in single crystals of high purity gallium. The potential and the elastic components of the electron sound demonstrate qualitatively different dependencies on…

SuperconductivityMaterials Science

Giant Zeeman splitting of light holes in GaAs/AlGaAs quantum wells

M. V. Durnev、M. M. Glazov、E. L. Ivchenko2011-11-29arXiv

We have developed a theory of the longitudinal $g$ factor of light holes in semiconductor quantum wells. It is shown that the absolute value of the light-hole $g$-factor can strongly exceed its value in the bulk and, moreover, the dependence of the Zeeman splitting on magnetic field becomes non-linear in relatively lo…

Materials ScienceMesoscale and Nanoscale Physics

Warm-White-Emitting from Eu2+/Mn2+-Codoped Sr3Lu(PO4)3 Phosphor with Tunable Color Tone and Correlated Color Temperature

Ning Guo、Yuhua Zheng、Yongchao Jia 等 5 位作者2011-11-29The Journal of Physical Chemistry C

A series of single-component Sr 3 Lu(PO 4 ) 3:Eu 2+,Mn 2+ phosphors were successfully synthesized by solid-state reaction, and their photoluminescence properties were investigated. The Sr 3 Lu(PO 4 ) 3:Eu 2+,Mn 2+ phosphor system was efficiently excited at wavelength ranging from 250 to 420 nm, which is well-matched w…

Radiation Detection and Scintillator TechnologiesLuminescence Properties of Advanced MaterialsLuminescence and Fluorescent Materials

Nanoantennas for visible and infrared radiation

Paolo Biagioni、Jer-Shing Huang、Bert Hecht2011-11-29arXiv

Nanoantennas for visible and infrared radiation can strongly enhance the interaction of light with nanoscale matter by their ability to efficiently link propagating and spatially localized optical fields. This ability unlocks an enormous potential for applications ranging from nanoscale optical microscopy and spectros…

Mesoscale and Nanoscale Physicsphysics.opticsMaterials Science

Information Geometry, Phase Transitions, and Widom Lines : Magnetic and Liquid Systems

Anshuman Dey、Pratim Roy、Tapobrata Sarkar2011-11-29arXiv

We study information geometry of the thermodynamics of first and second order phase transitions, and beyond criticality, in magnetic and liquid systems. We establish a universal microscopic characterization of such phase transitions via the equality of correlation lengths $ξ$ in coexisting phases, where $ξ$ is related…

hep-thcond-mat.stat-mechMaterials Science

Magnetic properties and spin dynamics of3d−4fmolecular complexes

P. Khuntia、Manuel Mariani、A. V. Mahajan 等 7 位作者2011-11-29Physical Review B

We present the magnetic properties of three recently synthesized binuclear molecular complexes [NiNd], [NiGd], and [ZnGd] investigated by dc magnetization and proton nuclear magnetic resonance (NMR) measurements. The high-temperature magnetic properties are related to the independent paramagnetic behavior of the two m…

Lanthanide and Transition Metal ComplexesAdvanced NMR Techniques and ApplicationsMagnetism in coordination complexes

Electric field driven insulator-to-metal phase transitions

M. Nardone、V. G. Karpov2011-11-29arXiv

We show that strong enough electric fields can trigger nucleation of needle-shaped metallic embryos in insulators, even when the metal phase is energetically unfavorable without the field. This general phenomenon is due to the gigantic induced dipole moments acquired by the embryos which cause sufficient electrostatic…

cond-mat.otherMaterials Science

Unexpected Structures for Intercalation of Sodium in Epitaxial Graphene-SiC Interfaces

Andreas Sandin、Thushari Jayasekera、J. E. 等 7 位作者2011-11-29arXiv

We show using scanning tunneling microscopy, spectroscopy, and ab initio calculations that several intercalation structures exist for Na in epitaxial graphene on SiC(0001). Intercalation takes place at room temperature and Na electron-dopes the graphene. It intercalates in-between single-layer graphene and the carbon-…

Mesoscale and Nanoscale PhysicsMaterials ScienceStrongly Correlated Electrons

Engineering “Hot” Nanoparticles for Surface‐Enhanced Raman Scattering by Embedding Reporter Molecules in Metal Layers

Yuhua Feng、Yong Wang、Hong Wang 等 9 位作者2011-11-29Small

Ag is deposited on the surface of Au nanoparticles functionalized with 4-mercaptobenzoic acid (MBA). Exceptionally strong surface-enhanced Raman scattering (SERS) signals are observed from the resulting colloid. Using SERS as a tool, evidence is obtained for the embedding of MBA inside the nanoscale metal layer.

Gold and Silver Nanoparticles Synthesis and ApplicationsProtein Interaction Studies and Fluorescence AnalysisElectrochemical Analysis and Applications

RETRACTED: Preparation and performance evaluation of tetracycline hydrochloride loaded wound dressing mats based on electrospun nanofibrous poly(lactic acid)/poly(ϵ‐caprolactone) blends

Payam Zahedi、Zeinab Karami、Iraj Rezaeian 等 7 位作者2011-11-29Journal of Applied Polymer Science

Abstract In this article, we present the drug‐release rate, water uptake, water permeability, morphology, and mechanical properties of a series of active wound dressing nanofibrous mats prepared via an electrospinning process of poly(lactic acid) (PLA), poly(ϵ‐caprolactone) (PCL), and their (50/50) blends loaded with…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation

Assessing the Thermoelectric Properties of Sintered Compounds via High-ThroughputAb-InitioCalculations

Shidong Wang、Zhao Wang、Wahyu Setyawan 等 5 位作者2011-11-29Physical Review X

Building a new physical concept into a high-throughput quantum-mechanical computational approach, researchers from Duke University and the Laboratory for Innovation in Technology for New Energy (LITEN) of CEA in France predict a large set of sintered inorganic compounds as good candidates for high-efficiency thermoele…

Advanced Thermoelectric Materials and DevicesThermal Expansion and Ionic ConductivityThermal properties of materials

Exploiting Dendrimer Multivalency To Combat Emerging and Re-Emerging Infectious Diseases

Meredith A. Mintzer、Eric L. Dane、George A. O’Toole 等 4 位作者2011-11-29Molecular Pharmaceutics

The emergence and re-emergence of bacterial strains that are resistant to current antibiotics reveal the clinical need for new agents that possess broad-spectrum antibacterial activity. Furthermore, bacteriophobic coatings that repel bacteria are important for medical devices, as the lifetime, reliability, and perform…

Antimicrobial Peptides and ActivitiesDendrimers and Hyperbranched PolymersAntimicrobial agents and applications

Spectroscopic scanning tunneling microscopy insights into Fe-based superconductors

Jennifer E Hoffman2011-11-29Reports on Progress in Physics

In the first three years since the discovery of Fe-based high T c superconductors, scanning tunneling microscopy (STM) and spectroscopy have shed light on three important questions. First, STM has demonstrated the complexity of the pairing symmetry in Fe-based materials. Phase-sensitive quasiparticle interference (QPI…

Iron-based superconductors researchRare-earth and actinide compoundsChemical and Physical Properties of Materials

Layer-by-Layer Engineered Co–Al Hydroxide Nanosheets/Graphene Multilayer Films as Flexible Electrode for Supercapacitor

Xinyi Dong、Lei Wang、Wang Dong 等 5 位作者2011-11-29Langmuir

Multilayer films of Co-Al layered double hydroxide nanosheets (Co-Al LDH-NS) and graphene oxide (GO) were fabricated through layer-by-layer (LBL) assembly. By using a three-electrode system, the electrochemical performances of the films were investigated to evaluate their potential as electrode materials to be used in…

Supercapacitor Materials and FabricationAdvancements in Battery MaterialsLayered Double Hydroxides Synthesis and Applications

Crystallization of CaCO3in Water–Alcohol Mixtures: Spherulitic Growth, Polymorph Stabilization, and Morphology Change

Karina K. Sand、Juan Diego Rodriguez‐Blanco、Emil Makovicky 等 5 位作者2011-11-29Crystal Growth & Design

The presence of alcohol in binary alcohol–water mixtures can affect the precipitation pathways of anhydrous crystalline CaCO 3 polymorphs and their morphology. We explored the formation pathways and the effects of several parameters on calcite, vaterite, and aragonite: concentration of simple alcohols, time, and shaki…

Cephalopods and Marine BiologyPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Shell Thickness-Dependent Raman Enhancement for Rapid Identification and Detection of Pesticide Residues at Fruit Peels

Bianhua Liu、Guangmei Han、Zhongping Zhang 等 7 位作者2011-11-29OpenAlex

Here, we report the shell thickness-dependent Raman enhancement of silver-coated gold nanoparticles (Au@Ag NPs) for the identification and detection of pesticide residues at various fruit peels. The Raman enhancement of Au@Ag NPs to a large family of sulfur-containing pesticides is ~2 orders of magnitude stronger than…

Biosensors and Analytical DetectionAdvanced biosensing and bioanalysis techniquesGold and Silver Nanoparticles Synthesis and Applications