Materials Literature
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Polyurethane (PU) has long been investigated due to its excellent mechanical properties, shape memory effect, and biocompatibility, and was grafted with pendant functional groups to tailor the polymer characteristics without affecting their basic structure. Actually, polyethyleneglycol has been grafted to polyurethane…
A series of 2,5-diazapentalene containing dyes with tunable energy gaps are visible and near-infrared halochromic towards various acids and their protonated counterparts represent a new class of thermochromic materials with the near-infrared absorption being switched on at room temperature and off above 50 °C.
Abstract Low‐molecular‐weight polyesters were obtained by the ring‐opening homopolymerization and copolymerization reaction of ϵ‐caprolactone, rac ‐ or L ‐lactide, and glycolide in the presence of poly(ethylene glycol) with an enzyme catalyst, a lipase from Candida antarctica, Pseudomonas cepacia , or Pseudomonas fluo…
Nanostructure ZnO was grown on thin aluminium layer, deposited on silicon substrate using the sol–gel method. The surface morphologies of nanostructure ZnO at different precursor concentrations were studied using scanning electron microscopy. Raman spectroscopy suggested that nanorods started to grow along with nanofl…
A novel, green, and highly efficient strategy for room-temperature reduction of solid-state graphene oxide films has been successfully developed using hydrogen-involved reduction with the assistance of a small amount of Pd catalyst. Based on this approach, flexible reduced graphene oxide films with high conductivity c…
Two PbZr1−xTixO3 (PZT) single crystals with x≈ 0.45 and 0.42 near the morphotropic phase boundary were studied by Brillouin light scattering, giving rise to the first single-crystal elastic data which were discussed in terms of the correlation between the acoustic anomalies and the phase transition sequence. The ferro…
Nanomedicine formulations are considered to be superior to standard low-molecular-weight drugs because of an increased drug accumulation at the pathological site and a decreased localization to healthy non-target tissues, together leading to an improved balance between the efficacy and the toxicity of (chemo-) therape…
In this study, we used conventional ceramics techniques to prepare lead‐free ceramics ( K 0.5 Na 0.5 ) NbO 3 ‐ x mol CuO ( KNN ‐ xCu ) sintered in air atmosphere and argon atmosphere, respectively, and investigated the corresponding hardening characteristics. The microstructure, P–E hysteresis loops, and X‐ray photoel…
Transmission electron microscopy (TEM) of (de-)hydrogenation reactions is crucial to characterize efficiency of hydrogen storage materials. The nanoreactor, a micromachined channel with 15-nm-thick windows, effectively confines the gas flow to an electron-transparent chamber during TEM of reactions. Realistic experime…
This paper reports a molecular modelling study of the adsorption of protein subdomains with unlike secondary structures on different surfaces of ceramic titanium dioxide (TiO(2)), forming a passivating film on titanium biomaterials that provides the interface between the bulk metal and the physiological environment, a…
Fully dense nanocrystalline MgO ‐based ceramics were consolidated by field and pressure assisted sintering (also known as Spark Plasma Sintering) using anhydrous nanosized powders (~5 nm) prepared by laser ablation and handled in a controlled, water‐free environment prior to sintering. The high reactivity of the powde…
Abstract In this study, we examined the effect of applied electrostatic voltages and the types of electrical charging on jet movement, fiber productivity, fiber diameter and deposited configuration by two inverse polarity systems, termed as spinneret and collector charging systems. Jet movement parameters such as Tayl…
A new rapid, very simple and one-step sol-gel strategy for the large-scale preparation of highly porous γ-Al2O3 is presented. The resulting mesoporous alumina materials feature high surface areas (400 m2 g−1), large pore volumes (0.8 mL g−1) and the γ-Al2O3 phase is obtained at low temperature (500 °C). The main advan…
Abstract The aim of this work is to prepare low‐density polyethylene (LDPE)/thermoplastic corn starch (TPCS) compounds containing the highest amount of starch for biodegradable applications. It is intended to increase concentration of corn starch into LDPE without affecting basic required mechanical properties of LDPE…
Abstract The curing process of a typically formulated spray polyurea elastomer (SPUA) system has been thoroughly investigated with the help of a combined analysis of Fourier transform infrared spectroscopy, differential scanning calorimetry, and dynamic mechanical analysis. The evolvement of the microstructure and mec…
Biopolymers have received in recent years an increasing interest for their potential applications in the field of biomedical engineering. Among the natural polymers that have been experimented, chitosan is probably the most promising in view of its exceptional biological properties. Several techniques may be employed…
Abstract MQ silicone resins, which represent a broad range of hydrolytic condensation products of monofunctional silane (M) and tetrafunctional silane (Q), were synthesized by reaction of water glass with hexamethyldisiloxane. The optimum reaction time and the optimal reaction temperature is 30 min and 30–40°C, respec…
INTRODUCTION: Resistance to chemotherapy is a major obstacle in the successful amelioration of tumors in many cancer patients. Resistance is either intrinsic or acquired, involving mechanisms such as genetic aberrations, decreased influx and increased efflux of drugs. Strategies for the reversal of resistance involve…
Abstract Silk fibroin (SF) is a biocompatible and slowly biodegradable material with excellent mechanical properties and huge potential for use as biofunctional interface in electronic devices that aim to stimulate and control neural network activity and peripheral nerve repair. It is shown that SF films act as materi…
BACKGROUND: It is energetically expensive to synthesize certain amino acids. The proteins (spidroins) of spider major ampullate (MA) silk, MaSp1 and MaSp2, differ in amino acid composition. Glutamine and proline are prevalent in MaSp2 and are expensive to synthesize. Since most orb web spiders express high proline sil…