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Electric-stimulus-responsive multilayer films based on a cobaltocenium-containing polymer

Jingjing Wei、Lixia Ren、Chuanbing Tang 等 4 位作者2014-08-08Polymer Chemistry

Robust fabrication of electroactive multilayer films from a cationic metallocene-containing polymer and their redox-controlled disassembly are presented. Multilayers are assembled from the cationic cobaltocenium polymer (PMCl) and anionic poly(styrene sulfonate) (PSS), and the effect of salt on the assembly process is…

Conducting polymers and applicationsPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Molding the flow of light with a magnetic field: plasmonic cloaking and directional scattering

Wilton J. M. Kort-Kamp、F. S. S. Rosa、F. A. Pinheiro 等 4 位作者2014-08-08Journal of the Optical Society of America A

We investigate electromagnetic (EM) scattering and plasmonic cloaking in a system composed of a dielectric cylinder coated with a magneto-optical shell. In the long-wavelength limit we demonstrate that the application of an external magnetic field can not only switch on and off the cloaking mechanism but also mitigate…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Robust technique for the polarisability matrix retrieval of bianisotropic scatterers via their reflection and transmission coefficients

Theodosios D. Karamanos、Alexandros I. Dimitriadis、Nikolaos V. Kantartzis2014-08-08IET Microwaves Antennas & Propagation

A consistent algorithm for extracting the polarisability matrix of bianisotropic meta‐atoms directly from their reflection and transmission properties is introduced in this study. Considering a two‐dimensional periodic distribution of the scatterer under study, illuminated by properly‐polarised, normally‐incident, pla…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Processing magnesium alloys by severe plastic deformation

Roberto B. Figueiredo、Maria Teresa Paulino Aguilar、Paulo Roberto Cetlin 等 4 位作者2014-08-08IOP Conference Series Materials Science and Engineering

The use of severe plastic deformation techniques for processing magnesium alloys has moved from the early difficulties of processing to a stage of tailoring the best properties of these materials. The present paper reviews processing, structure and mechanical properties characterization. It is shown that ultrafine-gra…

Microstructure and mechanical propertiesMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Study of mechanical, thermal, morphological, and process rheology of acrylonitrile styrene acrylate (ASA)/ Na+1 poly(ethylene‐co‐methacrylic acid) ionomer blend

Pulak Datta、Chandan Guha、Gautam Sarkhel2014-08-08Polymer Engineering and Science

Acrylonitrile–styrene–acrylic (ASA) terpolymer was blended with a sodium neutralized poly (ethylene‐co‐methacrylic acid) ionomer to develop a weather‐resistant ASA with good heat sealing and adhesion properties. Both tensile strengths and modulus were reduced by about 45% with an increase in Na‐ionomer concentration o…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Atomic Layer Deposition and Characterization of Bi2Te3 Thin Films

Tiina Sarnet、Timo Hatanpää、Esa Puukilainen 等 8 位作者2014-08-08The Journal of Physical Chemistry A

Bi2Te3 thin films were deposited by atomic layer deposition (ALD) from BiCl3 and (Et3Si)2Te at 160-300 °C. The process was studied in detail, and growth properties typical of ALD were verified. Films were stoichiometric with low impurity content. The film thickness was easily controlled with the number of deposition c…

Physics of Superconductivity and MagnetismAdvanced Thermoelectric Materials and DevicesTopological Materials and Phenomena

Controlled Release of Mangiferin Using Ethylene Vinyl Acetate Matrix for Antioxidant Packaging

Rungkan Boonnattakorn、Vanee Chonhenchob、Muhammad Siddiq 等 4 位作者2014-08-08Packaging Technology and Science

This study investigated the use of ethylene vinyl acetate (EVA) matrix in controlled release packaging. Mangiferin, having high antioxidant activity, was incorporated into the EVA matrix with different vinyl acetate (VA) contents. Mangiferin release rate increased with increasing VA content (or decreasing crystallinit…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Ab initiostudy of the photocurrent at the Au/Si metal–semiconductor nanointerface

Yulun Han、David A. Micha、Dmitri S. Kilin2014-08-08Molecular Physics

Photo-induced charge transfer at the interface of two materials is a fundamental process in photovoltaic applications. In this study, we have considered a model of a simplified photovoltaic cell composed of a Si nanocrystal co-doped with Al and P, interfacing with Au electrodes. The photo-induced time-dependent electr…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresSemiconductor materials and interfaces

Flexible and flame resistant poly(lactic acid)/organomontmorillonite nanocomposites

W. S. Chow、Ee Lian Teoh2014-08-08Journal of Applied Polymer Science

ABSTRACT The PLA/OMMT nanocomposites were produced using a melt compounding technique with isopropylated triaryl phosphate ester flame retardant (FR; 10–30 parts per 100 resin). The flammability of the PLA/OMMT composites was evaluated with an Underwriter Laboratory (UL‐94) vertical burning test, and their char morpho…

biodegradable polymer synthesis and propertiesFlame retardant materials and propertiesCarbon dioxide utilization in catalysis

Synthesis on Winged Graphene Nanofibers and Their Electrochemical Capacitive Performance

Chengshi Gong、Yongmin He、Jinyuan Zhou 等 10 位作者2014-08-08ACS Applied Materials & Interfaces

Assembly techniques of graphene have attracted intense attention since their performance strongly depends on the manners in which graphene nanosheets are arranged. In this work, we demonstrate a viable process to synthesize winged graphene nanofibers (G-NFs) which could generate optimized pore size distribution by the…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Polymer coated gold nanoparticle–protein agglomerates as nanocarriers for hydrophobic drug delivery

Rumi Khandelia、Amit Jaiswal、Siddhartha Sankar Ghosh 等 4 位作者2014-08-08Journal of Materials Chemistry B

Polymer coated gold nanoparticle-protein agglomerates having excellent protease and human blood serum stability are reported. These biocompatible agglomerates served as nanocarriers (NCs) for the hydrophobic anticancer drug camptothecin. The NCs were fabricated based on non-covalent interactions and meet the size crit…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsRNA Interference and Gene Delivery

Charge Transfer, Luminescence, and Phonon Bottleneck in TiO2Nanowires Computed by Eigenvectors of Liouville Superoperator

Shuping Huang、Dmitri S. Kilin2014-08-08Journal of Chemical Theory and Computation

A nonadiabatic excited state dynamics study of ⟨001⟩ anatase TiO2 nanowire is obtained by combining density matrix in Liouville-Redfield formalism and ab initio electronic structure calculations. The properties of eigenvectors of Liouville-Redfield superoperator are investigated. The time evolutions of Kohn-Sham orbit…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Self-Assembly of a Model Peptide Incorporating a Hexa-Histidine Sequence Attached to an Oligo-Alanine Sequence, and Binding to Gold NTA/Nickel Nanoparticles

Ian W. Hamley、Steven Kirkham、Ashkan Dehsorkhi 等 13 位作者2014-08-08Biomacromolecules

Amyloid fibrils are formed by a model surfactant-like peptide (Ala)10-(His)6 containing a hexa-histidine tag. This peptide undergoes a remarkable two-step self-assembly process with two distinct critical aggregation concentrations (cac's), probed by fluorescence techniques. A micromolar range cac is ascribed to the fo…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsNanocluster Synthesis and Applications

Alterable Superhydrophobic–Superhydrophilic Wettability of Fabric Substrates Decorated with Ion–TiO2 Coating via Ultraviolet Radiation

Yunjie Yin、Ning Guo、Chaoxia Wang 等 4 位作者2014-08-08Industrial & Engineering Chemistry Research

To prepare a functional fiber surface with alterable superhydrophobic–superhydrophilic wettability on fabrics, a TiO 2 hybrid sol was synthesized with tetrabutyl titanate and a fluoride silane coupling agent, 1H,1H,2H,2H-perfluorooctyltrimethoxysilane, via sol–gel technology. Within irradiation under UV light, the dec…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAerogels and thermal insulation

Pbca -Type In 2 O 3 : The High-Pressure Post-Corundum phase at Room Temperature.

B. García-Domene、J. A. Sans、O. Gomis 等 15 位作者2014-08-08The Journal of Physical Chemistry C

High-pressure powder X-ray diffraction and Raman scattering measurements in cubic bixbyite-type indium oxide (c-In 2 O 3 ) have been performed at room temperature. On increasing pressure c-In 2 O 3 undergoes a transition to the Rh 2 O 3 –II structure but on decreasing pressure Rh 2 O 3 –II-type In 2 O 3 undergoes a tr…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Fundamental measure theory for smectic phases: Scaling behavior and higher order terms

René Wittmann、Matthieu Maréchal、Klaus Mecke2014-08-08The Journal of Chemical Physics

The recent extension of Rosenfeld's fundamental measure theory to anisotropic hard particles predicts nematic order of rod-like particles. Our analytic study of different aligned shapes provides new insights into the structure of this density functional, which is basically founded on experience with hard spheres. We c…

Liquid Crystal Research Advancements

Formation of Free-Standing Supercrystals from the Assembly of Polyhedral Gold Nanocrystals by Surfactant Diffusion in the Solution

Chih‐Wen Yang、Chun‐Ya Chiu、Michael H. Huang2014-08-08Chemistry of Materials

Gold supercrystals with polyhedral morphologies can be prepared from the ordered packing of octahedral and rhombic dodecahedral nanocrystals in the presence of a sufficient amount of surfactant by slow water droplet evaporation. The whole supercrystal formation process has been video-recorded using a specially designe…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and Applications

Thermodynamic Properties of Form A and Form B of Florfenicol

Zhihong Sun、Hongxun Hao、Chuang Xie 等 8 位作者2014-08-08Industrial & Engineering Chemistry Research

In this research, a new polymorph of florfenicol (form B) was discovered and successfully prepared. The new polymorph was characterized and identified by powder X-ray diffraction (PXRD) and differential scanning calorimetry (DSC) techniques. It was found that form A has lower melting temperature while higher fusion en…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesPharmacological Effects of Natural Compounds

Hydroxylation of Ultrathin Al2O3/NiAl(110) Films at Environmental Humidity

Andrey Shavorskiy、Kathrin Müller、John T. Newberg 等 5 位作者2014-08-08The Journal of Physical Chemistry C

We have investigated the reaction of ultrathin Al 2 O 3 /NiAl(110) films with water vapor from ultrahigh vacuum to relative humidities (RH) up to 10%, over the temperature range from −5 to 65 °C, using ambient pressure X-ray photoelectron spectroscopy (APXPS) and scanning tunneling microscopy (STM). The APXPS experime…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesnanoparticles nucleation surface interactions

Introduction of Co into the Vacant T-Atom Sites of SiBEA Zeolite as Isolated Mononuclear Co Species

Rafał Baran、Thomas Onfroy、Sandra Casale 等 4 位作者2014-08-08The Journal of Physical Chemistry C

A CoSiBEA zeolite was obtained by a postsynthesis method which consisted of a treatment of tetraethylammonium BEA zeolite with nitric acid in the first step and introduction of Co ions into the vacant T atom sites of the SiBEA zeolite by reaction of aqueous Co(NO 3 ) 2 solution with silanol groups. The introduction of…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisMesoporous Materials and Catalysis