Materials Literature
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Abstract Graft chitosan derivatives (CMCTS‐ g ‐MAAS and CMCTS‐ g ‐AAS) were prepared by the graft copolymerization of methacrylic acid sodium (MAAS) and acrylic acid sodium (AAS) onto the etherification product of chitosan‐carboxymethyl chitosan (CMCTS). Their antioxidant activity was estimated as superoxide anion sca…
Ba (3− x ) Sr x (PO 4 ) 2 orthophosphates (0≤ x ≤3) have been prepared by solid state reaction. The final temperature was 1000°C. The X-ray diffraction analyses show the existence of a continuous solid solution. Ba (3− x ) Sr x (PO 4 ) 2 orthophosphates (0≤ x ≤3) crystallize in the hexagonal system with the space grou…
To test the effectiveness of phase identification software, a two-stage search/match round robin using powder X-ray diffraction data was organized, through the internet and world wide web. The first stage provided powder patterns and a vague sample origin, the second stage provided the chemistry and sample history. Wh…
Cinza da casca de arroz foi incorporada em borracha natural (NR) utilizando-se um misturador de cilindros. O sistema de vulcanização convencional (CV) foi escolhido e os estudos sobre a cura das composições foram conduzidos em um Curômetro TI-100. As curvas de torque foram obtidas em 150, 160, 170 e 180 °C. A velocida…
In the past two decades, significant advances in space charge measurements in polymers have resulted in a better understanding of charge dynamics and their effect on material selection and processing. However, little attention has been given to the effect of semiconducting screens on space charge formation in the bulk…
A new multibranched octopus-type structure of carbon nanofibers is synthesized from a natural precursor, camphor, by a thermal chemical vapor deposition technique. An alloy of Cu:Ni catalyst is prepared by electrochemically coating nickel on a copper sheet, with nickel sulfate as an electrolyte, and heating that nicke…
Impedance spectroscopy technique was used to investigate the electric properties of Zn7Sb2O12, an electroceramic with inverse spinel type structure. The electric characterization of the Zn7Sb2O12 semiconducting ceramic was performed at temperature from 250 to 550 °C, in the frequency range from 5 Hz to 13 MHz. Zinc an…
Several cyclic hydroxylamines containing hydrophobic substituents were prepared. All these hydroxylamines were tested for corrosion inhibition of carbon steel in 1M HCl at 60°C by gravimetric and electrochemical methods. All compounds showed excellent corrosion inhibition efficiency (IE per cent) in acidic solutions c…
As part of an ongoing materials development activity to produce high performance polymers that are space environmentally stable, phosphine oxide containing polyimides were prepared by reacting a novel aromatic dianhydride, 4,4′-(2-diphenylphosphinyl-1,4-phenylenedioxy)diphthalic anhydride 3, with aromatic diamines. Th…
This paper presents a new route about producing carbon black, by which the natural gas cracking is carried out in the absence of oxygen thanks to an electric energy supply externally given by a plasma jet. The carbon black produced by this process has a narrow size distribution and a small average diameter of 38 nm as…
Abstract A combination of two semipermeable microporous hydrophilic polymer films, inserted between two different fabrics (internal and external), proposed for some kinds of protective clothing, when it is necessary to protect the room atmosphere against particles (causing illness) emitted from human body, and to ensu…
Single crystalline zinc oxide (ZnO) nanowires have been grown on Si (100) substrates by a vapor-liquid-solid (VLS) process at temperatures in the range 850-950 °C in an inert atmosphere. The VLS-grown ZnO nanowires have been characterized in detail using X-ray diffraction (XRD), field emission scanning electron micros…
Abstract Photochromic properties of methylacrylate monomers and polymers containing azobenzene groups with heterocyclic sulfonamide functionalities viz sulfisomidyne (4-amino-N-[2,6-dimethylpyrimidyn-4-yl]benzenesulfonamide) and sulfamethoxazole (4-amino-N-[5-methylisoxazol-3-yl]benzenesulfonamide) substituents were i…
The integrated-intensity ratio R of the L β and L α lines in x-ray emission spectra of 3 d transition metal oxides was measured. The magnitude of the ratio was found to depend nonmonotonically on the atomic number of the 3 d elements, with a sharp rise in the middle of the series. In terms of the theory of one-electro…
Within the framework of severe reactor accident studies, we present experimental and numerical parametric studies on debris bed coolability. Data are provided by the SILFIDE multidimensional experimental facility at Electricité de France. The bed is composed of inductively heated steel sphere beads (diameters ranging…
Abstract This paper demonstrates the use of two‐dimensional (2D) correlation spectroscopy in the characterization of the sodium molybdate structures that include and are intermediate between the hexagonal and orthorhombic forms; this series of sodium molybdates is produced by varying the preparation conditions, partic…
Abstract The thermal spin transitions of iron(II) spin-crossover compounds [Fe(PM-iPA)2(NCS)2] (1) and [Fe(PM-iPA)2(NCSe)2] (2) (PM-iPA = N-(2′-pyridylmethyl)-isopropylamine) have occurred at T1/2 = 267 K and 376 K without thermal hysteresis. No light-induced excited spin state trapping (LIESST) effect was observed fo…
Abstract The hydrolytic and thermal stability of random copolyesters of ε ‐caprolactone ( ε ‐CL) and ca. 30 mol‐% 2‐oxepane‐1,5‐dione (OPD) have been investigated. Compared with poly( ε ‐caprolactone) (PCL) of a comparable molecular weight, the hydrolytic degradation of the copolyester is faster in a phosphate buffer…
Pewter, a tin-rich alloy, has been widely used for ornamental and utilitarian purposes for the last 400 years because it is durable, relatively easily worked, resistant to corrosion, and similar to silver in appearance. Pewter plates and implements have been recovered and examined from what is believed to be the wreck…
Calcium (Ca(2+)) fluoroionophores are useful in cell-based functional assays of G-protein coupled receptor (GPCR) activation or ion channel modulation. In this paper we describe new calcium probes that improve or overcome certain deficiencies in existing probes. These new fluoroionophores are based on acylation of ami…