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“Protein-Like” Copolymers: Effect of Polymer Architecture on the Performance in Bioseparation Process

Per‐Olof Wahlund、Igor Yu. Galaev、Sergei A. Kazakov 等 5 位作者2002-01-01Macromolecular Bioscience

Recently, a new class of copolymers, so-called protein-like copolymers has been predicted theoretically by computer simulation. In these copolymers, the conformation of the copolymer determines the exposure of certain comonomer units to the outer solution. Depending on the conformation, copolymer molecules with essent…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesAnalytical Chemistry and Chromatography

The gas phase proton affinity of uracil: measuring multiple basic sites and implications for the enzyme mechanism of orotidine 5′-monophosphate decarboxylase

Mary Ann Kurinovich、Linda M. Phillips、Seema Sharma 等 4 位作者2002-01-01Chemical Communications

We have shown for the first time experimentally that the O2 and O4 sites of uracil have different proton affinities, and as implied in previous computational studies, the O4 is more basic and would be energetically preferred in an orotate ribose 5'-monophosphate decarboxylase catalysis mechanism involving proton trans…

Photosynthetic Processes and MechanismsEnzyme Structure and FunctionBiochemical and Molecular Research

Control of structure, pore size and morphology of three-dimensionally ordered mesoporous silicas prepared using the dicationic surfactant [CH 3 (CH 2 ) 15 N(CH 3 ) 2 (CH 2 ) 3 N(CH 3 ) 3 ]Br 2

Alfonso E. Garcia‐Bennett、Sylvia Williamson、Paul A. Wright 等 4 位作者2002-01-01Journal of Materials Chemistry

The synthesis of mesoporous silicas in the presence of the dicationic gemini surfactant [CH3(CH2)15N(CH3)2(CH2)3N(CH3)3]Br2 (C16-3-1) has been investigated at low temperatures (−4 °C) under basic and acidic conditions. Under basic conditions, the SBA-2 phase (based on a close-packed arrangement of micelles and exhibit…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisCovalent Organic Framework Applications

Development of Cold Rolling Mill Rolls of High Speed Steel Type by Using Continuous Pouring Process for Cladding.

Mitsuo Hashimoto、Taku Tanaka、Tsuyoshi INOUE 等 6 位作者2002-01-01ISIJ International

The quality of work rolls that come into direct contact with the steel product has a direct effect on product quality and mill operation. A forged steel with a chromium content of 5 mass% has been conventionally used to meet the requirement of metallurgical structure homogeneity and high hardness for work rolls in col…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

A dithienylethene-tethered β-cyclodextrin dimer as a photoswitchable host

Alart Mulder、Amela Juković、Linda N. Lucas 等 7 位作者2002-01-01Chemical Communications

The binding of TSPP by a dithienylethene-tethered beta-cyclodextrin dimer can be altered reversibly by irradiation with light.

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Tunable Non-locality of Thermal Non-linearity in Dye Doped Nematic Liquid Crystal

Jean‐Francois Henninot、Matthieu Debailleul、M. Warenghem2002-01-01Molecular Crystals and Liquid Crystals

In this paper we report on experiments performed to estimate the non-locality of the photothermal non-linearity in thick dye-doped nematic liquid crystal (DDNLC). We have studied the interaction of two counter-propagating self-focused laser beams parallel to each other. From this experiment, a rough estimation of the…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationSemiconductor Lasers and Optical Devices

Mineralogy, Petrology and Geochemistry of Beryllium: An Introduction and List of Beryllium Minerals

Edward S. Grew2002-01-01Reviews in Mineralogy and Geochemistry

Research Article| January 01, 2002 Mineralogy, Petrology and Geochemistry of Beryllium: An Introduction and List of Beryllium Minerals Edward S. Grew Edward S. Grew Department of Geological Sciences, 5790 Bryand Center, University of Maine, Orono, Maine 04469, esgrew@maine.edu Search for other works by this author on:…

Crystal Structures and PropertiesRadioactive element chemistry and processingMineralogy and Gemology Studies

Century 21 - Pregnant with Ozone

Rip G. Rice2002-01-01Ozone Science and Engineering

As we enter this new century, it is striking how the number of applications for ozone is growing. During ozone's first century, the emphasis for using it involved primarily, potable water treatment, wastewater treatment, bottled water treatment, odor control and medical therapy. Of these, potable water and wastewater…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceAdvanced Nanomaterials in Catalysis

Phase diagrams of dilute binary alloys

博明 岡本2002-01-01ASM International eBooks

In this volume, regarded as a supplement to the Desk Handbook: Phase Diagrams for Binary Alloys published in 2000, the editor has included all the information available on limited solubility in every binary system. While the smaller format of the desk handbook served well in providing overall information, the range of…

Aluminum Alloy Microstructure PropertiesMetallurgical and Alloy Processes

Characteristics of porous nickel-titanium alloys for medical applications.

R Hernández、Stéfania Polizu、S. Turenne 等 4 位作者2002-01-01PubMed

We investigate the behavior of NiTi porous alloys, possessing the property of shape memory, by using different characterization methods XPS, Auger, DSC and SEM. The study mainly focuses on the determination of porosity, surface characteristics and the phase transformation. In the case of porous material the biomechani…

Shape Memory Alloy Transformations

Alumina ceramics for ballistic protection. Part 1

Eugene Medvedovski2002-01-01American Ceramic Society bulletin

High-alumina and alumina-zirconia ceramics have been successfully used as armor material for personnel and vehicular ballistic protection.

Advanced ceramic materials synthesisEnergetic Materials and CombustionHigh-Velocity Impact and Material Behavior

Polyelectrolyte multilayer films modulate cytoskeletal organization in chondrosarcoma cells

Dominique Vautier、Véronique Karsten、Christophe Egles 等 7 位作者2002-01-01Journal of Biomaterials Science Polymer Edition

The aim of this study was to evaluate polyelectrolyte multilayer films as interfaces for implants. Polyelectrolyte multilayers were built up with different terminating layers by alternate deposition of oppositely charged polyelectrolytes on which chondrosarcoma (HCS-2/8) cells were grown in the presence of serum. Film…

Bone Tissue Engineering MaterialsPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Performance of Solid Oxide Fuel Cells with LSGM-LSM Composite Cathodes

Tad J. Armstrong、Anil V. Virkar2002-01-01Journal of The Electrochemical Society

Anode-supported cells comprising zirconia (YSZ) anode, thin YSZ electrolyte, and composite cathodes containing a mixture of (LSM) and (LSGM) were fabricated. The relative proportions of LSGM and LSM were varied between 30 wt % % LSM and 70 wt % % LSM, while the firing temperature was varied between 1000 and 1200°C. Th…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Ni Catalyst for Hydrogen Conversion in Gadolinia-Doped Ceria Anodes for Solid Oxide Fuel Cells

S. Primdahl、Y. L. Liu2002-01-01Journal of The Electrochemical Society

A gadolinia-doped ceria (CG4) is considered as anode material for solid oxide fuel cells with an yttria-stabilized zirconia electrolyte. Symmetrical cells are mounted in a novel setup geometry with auxiliary electrodes to avoid concentration polarization outside the electrode structure. The polarization resistance in…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Study of the formation of mesoporous titania via a template approach and of subsequent Li insertion

Fabrice Leroux、Patricia J. Dewar、Mourad Intissar 等 5 位作者2002-01-01Journal of Materials Chemistry

Mesostructured titania was prepared according to Rao et al. using dodecylamine as the amine template. X-Ray absorption spectroscopy was used to study changes in the Ti local coordination environment during formation of the mesoporous material—starting from the alkoxide precursor, followed by hydrolysis and condensatio…

Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesMesoporous Materials and Catalysis

Synthesis, Spectra and Photophysics of some Free Base Tetrafluoroalkyl and Tetrafluoroaryl Porphyrins with Potential Applications in Imaging¶

J. C. P. Grancho、Mariette M. Pereira、Maria G. Miguel 等 5 位作者2002-01-01Photochemistry and Photobiology

The synthesis, characterization and photophysical properties of two perfluoroalkyl (5,10,15,20-tetrakis-[trifluoromethyl]- and [heptafluoropropyl]-porphyrin) and two perfluoroaryl (5,10,15,20-tetrakis-[2,6-difluorophenyl]- and [pentafluorophenyl]-porphyrin) are described, with reference to their potential in both phot…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Porphyrins in 1,3-Dipolar Cycloaddition Reactions: Synthesis of a Novel Pyrazoline-fused Chlorin and a Pyrazole-fused Porphyrin

Ana M. G. Silva、Augusto C. Tomé、Maria G. P. M. S. Neves 等 4 位作者2002-01-01Synlett

β-Nitro-meso-tetraphenylporphyrin reacts with diazomethane to give a pyrazoline-fused chlorin as the main product. This compound was converted into the corresponding pyrazole-fused porphyrin, by treatment with DBU, and into a methanochlorin by refluxing in toluene.

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and Disorders

Biofilm architecture of Phanerozoic cryptic carbonate marine veneers

Robert Riding2002-01-01Geology

Research Article| January 01, 2002 Biofilm architecture of Phanerozoic cryptic carbonate marine veneers Robert Riding Robert Riding 1Department of Earth Sciences, Cardiff University, Cardiff CF10 3YE, UK Search for other works by this author on: GSW Google Scholar Author and Article Information Robert Riding 1Departme…

Paleontology and Stratigraphy of FossilsMethane Hydrates and Related PhenomenaCalcium Carbonate Crystallization and Inhibition

Carbon dioxide extraction of residual chloroform from biodegradable polymers

Wendy S. Koegler、Carmen Patrick、Michael J. Cima 等 4 位作者2002-01-01Journal of Biomedical Materials Research

Biodegradable polymeric devices for drug delivery and tissue engineering are often fabricated with the use of organic solvents and may still contain significant amounts of solvent (> 1 wt%) even after aggressive vacuum drying. This excess solvent can interfere with tissue response and the mechanical properties of the…

biodegradable polymer synthesis and propertiesPolymer Foaming and CompositesPolymer Science and PVC