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W-Band17O Pulsed Electron Nuclear Double Resonance Study of Gadolinium Complexes with Water

Arnold M. Raitsimring、Andrei V. Astashkin、Debbie Baute 等 5 位作者2004-08-06The Journal of Physical Chemistry A

In this work we have studied pulsed 17 O electron nuclear double resonance (ENDOR) spectra of the Gd 3+ aquo ion and the magnetic resonance imaging (MRI) contrast agent MS-325 in an 17 O-enriched frozen glassy water/methanol solution. The isotropic hyperfine interaction (hfi) constant of the water ligand 17 O was foun…

Advanced MRI Techniques and ApplicationsElectron Spin Resonance StudiesLanthanide and Transition Metal Complexes

Influence of the Particle Size and Particle Size Ratio on the Morphology and Viscoelastic Properties of Bimodal Hard/Soft Latex Blends

Didier Colombini、Helén Hassander、Ola J. Karlsson 等 4 位作者2004-08-06Macromolecules

The morphology and viscoelastic properties of films prepared from bimodal latex blends containing equal weight fractions of soft and hard latex particles were investigated as a function of the particle sizes and the particle size ratio (soft particle diameter/hard particle diameter). Minimum film formation temperature…

Polymer composites and self-healingPolymer crystallization and propertiesMaterial Properties and Processing

Multilayer Biomimetics: Reversible Covalent Stabilization of a Nanostructured Biofilm

Bingyun Li、Donald T. Haynie2004-08-06Biomacromolecules

Designed polypeptides and electrostatic layer-by-layer self-assembly form the basis of promising research in bionanotechnology and medicine on development of polyelectrolyte multilayer films (PEMs). We show that PEMs can be formed from oppositely charged 32mers containing several cysteine residues. The polypeptides in…

Surface Modification and SuperhydrophobicityMarine Biology and Environmental ChemistryPolymer Surface Interaction Studies

Mechanism of Fiber Formation by Interfacial Polyelectrolyte Complexation

Andrew C.A. Wan、I‐Chien Liao、Evelyn K. F. Yim 等 4 位作者2004-08-06Macromolecules

A four-step mechanism is hypothesized for the process of fiber formation by interfacial polyelectrolyte complexation: (1) formation of a polyionic complex film at the interface that acts as a viscous barrier to free mixing; (2) scattering of this complex by a drawing motion, creating submicron “nuclear fibers”; (3) gr…

Blood properties and coagulationPolymer Surface Interaction StudiesSurface Modification and Superhydrophobicity

Car Exhaust Catalysis from First Principles: Selective NO Reduction under Excess O 2 Conditions on Ir

Zhi‐Pan Liu、Stephen J. Jenkins、David A. King2004-08-06Journal of the American Chemical Society

Combining energetic data from density functional theory with thermodynamic calculations, we have studied in detail selective NO reduction under excess O2 conditions on Ir. We show that excess O2 can readily poison the Ir catalyst for NO reduction and the poisoning starts from a low O coverage on the surface. The adsor…

Advanced Chemical Physics StudiesCatalysis and Oxidation ReactionsCatalytic Processes in Materials Science

A Simple Chemical Route To Selectively Eliminate Metallic Carbon Nanotubes in Nanotube Network Devices

Lei An、Qiang Fu、Chenguang Lu 等 4 位作者2004-08-06Journal of the American Chemical Society

Semiconducting-only single-walled carbon nanotube (SWNT) network field effect transistors (FETs) have been fabricated by selectively reacting all the metallic SWNTs in the devices with diazonium reagents in a controlled manner. We have shown that the concentration of diazonium reagents used is crucial for selectively…

Graphene research and applicationsFullerene Chemistry and ApplicationsCarbon Nanotubes in Composites

Strategies in Making Cross-Linked Enzyme Crystals

Joseph Jegan Roy、T. Emilia Abraham2004-08-06Chemical Reviews

ADVERTISEMENT RETURN TO ISSUEArticleNEXTStrategies in Making Cross-Linked Enzyme CrystalsJ. Jegan Roy and T. Emilia AbrahamView Author Information Biochemical Processing Section, Regional Research Laboratory (CSIR), Trivandrum 695 019, India Cite this: Chem. Rev. 2004, 104, 9, 3705–3722Publication Date (Web):August 6,…

Protein Structure and DynamicsEnzyme Catalysis and ImmobilizationEnzyme Structure and Function

Equine Nutrition and Feeding

作者信息未提供2004-08-06OpenAlex

Equine nutrition and feeding , Equine nutrition and feeding , مرکز فناوری اطلاعات و اطلاع رسانی کشاورزی

Metallurgy and Material ScienceAgriculture, Water, and Health

Microwave Current Imaging in Passive HTS Components by Low-Temperature Laser Scanning Microscopy (LTLSM)

A. P. Zhuravel、Steven M. Anlage、A. V. Ustinov2004-08-06arXiv

We have used the LTLSM technique for a spatially resolved investigation of the microwave transport properties, nonlinearities and material inhomogeneities in an operating coplanar waveguide YBa_2Cu_3O_{7-δ} (YBCO) microwave resonator on an LaAlO_3 (LAO) substrate. The influence of twin-domain blocks, in-plane rotated…

SuperconductivityMaterials Science

First-principles calculations for the electronic band structures of small diameter single-wall carbon nanotubes

Viktor Zólyomi、J. Kürti2004-08-06Physical Review B

We present first-principles calculations on the band structures of 40 different small diameter $(d)$ single-wall carbon nanotubes (SWCNTs), including 14 chiral ones, employing density functional theory (DFT) within the local density approximation (LDA), using the Vienna ab initio simulation package (VASP). The band ga…

Graphene research and applicationsCarbon Nanotubes in CompositesBoron and Carbon Nanomaterials Research

Low Temperature Neutron Diffraction Study of MnTe

J. B. C. Efrem D'Sa、P. A. Bhobe、K. R. Priolkar 等 7 位作者2004-08-06arXiv

Investigation of transport and magnetic properties of MnTe at low temperatures sInvestigation of transport and magnetic properties of MnTe at low temperatures showed anomalies like negative coefficient of resistance below 100K and a sharp rise in susceptibility at around 83K similar to a ferromagnetic transition. Low…

Materials Science

Electronic and magnetic properties of the (111) surfaces of NiMnSb

I. Galanakis2004-08-06arXiv

Using an ab-initio electronic structure method, I study the (111) surfaces of the half-metallic NiMnSb alloy. In all cases there is a very pronounced surface state within the minority gap which destroys the half-metallicity This state survives for several atomic layers below the surface contrary to the (001) surfaces…

Materials Science

Spin relaxation of two-dimensional holes in strained asymmetric SiGe quantum wells

B. A. Glavin、K. W. Kim2004-08-06arXiv

We analyze spin splitting of the two-dimensional hole spectrum in strained asymmetric SiGe quantum wells (QWs). Based on the Luttinger Hamiltonian, we obtain expressions for the spin-splitting parameters up to the third order in the in-plane hole wavevector. The biaxial strain of SiGe QWs is found to be a key paramete…

Materials ScienceMesoscale and Nanoscale Physics

Reply to "Comment on 'Theory for tailoring sonic devices: Diffraction dominates over refraction' "

N. Garcia、M. Nieto-Vesperinas、E. V. Ponizovskaya 等 4 位作者2004-08-06arXiv

In their comment, A. Hakansson, J. Sanchez-Dehesa, F. Cervera, F. Meseguer, L. Sanchis, and J. Llinares say that our conclusion stating that diffraction prevails over refraction in acoustic lenses whose aperture is of several wavelengths, such as those addressed in our calculations [N. Garcia, M. Nieto-Vesperinas, E.…

Materials Science

Relevance of a magnetic moment distribution and scaling law methods to study the magnetic behavior of antiferromagnetic nanoparticles

N. J. O. Silva、V. S. Amaral、L. D. Carlos2004-08-06arXiv

In antiferromagnetic nanoparticles magnetization the linear component, $χ_{AF}$H superposed to the saturation one usually complicates the fit of experimental data. We present a method based on scaling laws to determine the variation of $χ_{AF}$ with temperature and to find the temperature dependence of the average mag…

Materials Science

Modifications and Extensions to Harrison's Tight-Binding Theory

L. Shi、D. A. Papaconstantopoulos2004-08-06arXiv

Harrison's tight-binding theory provides an excellent qualitative description of the electronic structure of the elements across the periodic table. However, the resulting band structures are in significant disagreement with those found by standard methods. We developed a new procedure to generate both the prefactors…

Materials Science

Fundamentals of Nano-Thermodynamics

M. Hartmann、G. Mahler、O. Hess2004-08-06arXiv

Recent progress in the synthesis and processing of nano-structured materials and systems calls for an improved understanding of thermal properties on small length scales. In this context, the question whether thermodynamics and, in particular, the concept of temperature can apply on the nanoscale is of central interes…

quant-phcond-mat.stat-mechMaterials Science

Versatile and Efficient Formation of Colloids of Biopolymer-Based Polyelectrolyte Complexes

Christophe Schatz、Alain Domard、Christophe Viton 等 5 位作者2004-08-06Biomacromolecules

The formation of colloids based on polyelectrolyte complexes (PECs) of biopolymers was investigated through the complexation between two charged polysaccharides, chitosan as polycation, and dextran sulfate as polyanion. The slow dropwise addition of components, generally used for the formation of PECs, allowed to elab…

Polymer Surface Interaction StudiesElectrostatics and Colloid InteractionsSurfactants and Colloidal Systems

Transformations of Molecules and Secondary Building Units to Materials: A Bottom-Up Approach

Ramaswamy Murugavel、Mrinalini G. Walawalkar、Meenakshi Dan 等 5 位作者2004-08-06Accounts of Chemical Research

A variety of complex inorganic solids with open-framework and other fascinating architectures, involving silicate, phosphate, and other anions, have been synthesized under hydrothermal conditions. The past few years have also seen the successful synthesis and characterization of several molecular compounds that can ac…

Polyoxometalates: Synthesis and ApplicationsSilicone and Siloxane ChemistryChemical Synthesis and Characterization

Natural Polysaccharides and Their Interactions with Dye Molecules: Applications in Effluent Treatment

Richard S. Blackburn2004-08-06OpenAlex

Dyeing effluent is one of the largest contributors to textile effluent and such colored wastewater has a seriously destructive impact on the environment. Adsorption can be a very effective treatment for decolorization of textile dyeing effluent, but current techniques employ adsorption chemistry that is not particular…

Advanced Cellulose Research StudiesAdsorption and biosorption for pollutant removalPolysaccharides Composition and Applications