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α-AlF3 by XPS and XAES Referenced by Au 4f7/2

Olaf Böse、Erhard Kemnitz、Andreas Lippitz 等 4 位作者1998-01-01Surface Science Spectra

Powder XRD defined α-AlF3 has been investigated by XPS and XAES using the Au 4f7/2 orbital for static charge referencing. This feature originates from well-defined and chemically inert 20 nm gold particles deposited in a highly dispersed pattern on the sample surface. The particles, with a sharp particle size distribu…

Copper Interconnects and ReliabilityX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Effect of diamond-like carbon coating on the emission characteristics of molybdenum field emitter arrays

Jae Hoon Jung、Byeong‐Kwon Ju、Hoon Kim 等 7 位作者1998-01-01IEEE Transactions on Electron Devices

We have studied the electron emission characteristics of Mo field emitter arrays (FEAs) using a diamond-like carbon (DLC) film deposited by a layer-by-layer technique using plasma enhanced chemical vapor deposition. The turn-on voltage was lowered from 55 to 30 V by a 20 nm thick hydrogen-free DLC coating and maximum…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Electronic instabilities in lithium intercalated ZrSe2

Claudia Felser、Philippe Deniard、Michael Bäcker 等 6 位作者1998-01-01Journal of Materials Chemistry

We have followed the evolution of the superconductingTc on intercalation of Li in ZrSe2 by means of magnetization studies at very low temperatures. To interpret the electronic structure and instabilities, we present the results of extensive LMTO-ASA band structure calculations on ZrSe2 and the idealized compound LiZrS…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Peculiarities of spontaneous-grating formation in light-sensitive films under elliptically polarized laser radiation

V. K. Miloslavsky、Л. А. Агеев、Arashmid Nahal1998-01-01Canadian Journal of Physics

The formation of spontaneous gratings in thin waveguide AgCl–Ag photosensitive films was studied under elliptically polarized laser radiation. New peculiarities of the gratings growth were found (i) a deviation in angular position of the wave vectors of the most probable microgratings from π / 2 about the major axis o…

Optical Coatings and Gratings

Applications of Conformal CVD Diamond Films

Shlomo Rotter1998-01-01Israel Journal of Chemistry

Abstract A method for enhanced nucleation of diamond growth on non‐diamond substrates is introduced via the results obtained in a wide variety of applications. The exact details of the method are still proprietary, but the outcome, as demonstrated in this paper, is unique and promises to be of great practical use. The…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

SCR Performance on a Hydrogen Reformer Furnace

Robert G. Kunz1998-01-01Journal of the Air & Waste Management Association

In late 1993, Air Products and Chemicals, Inc. began operating a new steam-methane reformer at the Tosco Refining Co.'s Avon refinery in Martinez, CA, to provide hydrogen and steam to the refinery under a long-term supply agreement. The hydrogen plant--owned, operated, and maintained by Air Products--includes a select…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingIndustrial Gas Emission Control

RIGOROUS MODAL THEORY OF PHASE GRATING AND THE TOTAL REFLECTANCE PROPERTY

FU KE-XIANG、Zhang Da-yue、WANG Zhi-heng 等 6 位作者1998-01-01Acta Physica Sinica

This paper discusses the electromagnetic field distribution in phase grating and the rate of diffraction for different diffraction orders by using a rigorous modal theory. Piece wise analytical function is used to express the eigen functions instead of the infinite series in other methods. Stable, fast and accurate re…

Photonic and Optical DevicesOptical measurement and interference techniquesOptical Coatings and Gratings

Oxidation of powder and ceramic UO2 by KClO3 in molten (Li–Na–K)2CO3 eutectic

Vladimir A. Volkovich、Trevor R. Griffiths、D. J. Fray 等 5 位作者1998-01-01Journal of the Chemical Society Faraday Transactions

The oxidation of UO2 powder and ceramic has been studied in the (Li–Na–K)2CO3 eutectic melt containing added potassium chlorate between 723 and 873 K. Complete oxidation of the powder could be achieved at 723 K and with KClO3:UO2 mole ratios between 0.25 and 0.3. Potassium monouranate was formed in the reaction and no…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear materials and radiation effects

Notch and Fracture Toughness Studies on Stainless Steels Containing Vanadium.

Robert S. Paton1998-01-01ISIJ International

One of the shortcomings of ferritic stainless steels is their limited toughness. By modifying the steel chemistry to include vanadium, some improvement is obtained in this regard. In this work, the influence of different stabilizers and thermomechanical treatments on the toughness of an experimental 18Cr–4V alloy have…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

The biosynthesis of pramanicin: intact incorporation of serine and absolute configuration of the antibiotic

Petar A. Duspara、Stephen I. Jenkins、Donald W. Hughes 等 4 位作者1998-01-01Chemical Communications

Biosynthetic incorporation of isotopically labelled serines into pramanicin 1 in Stagonospora sp. ATCC 74235 shows that L-serine is incorporated as an intact entity with all four bonds to the α-carbon retained; thus 1 is assigned the 5S absolute configuration.

Microbial Natural Products and BiosynthesisCarbohydrate Chemistry and SynthesisEnzyme Structure and Function

Importance of surface tension for physical paint properties

Michael Osterhold、Kornelia Armbruster1998-01-01Macromolecular Symposia

Abstract Surface tension is a parameter of decisive importance for characterizing painted and unpainted surfaces related to wetting and adhesion phenomena. This article presents measurements of the surface tension of solids by means of an automatic contact angle measurement device. The evaluation of the surface tensio…

Surface Modification and SuperhydrophobicityAnalytical Chemistry and SensorsSurface Roughness and Optical Measurements

Melting Behavior of .BETA.-SiC at High Pressure.

Motohiro Togaya、Shin Sugiyama1998-01-01The Review of High Pressure Science and Technology

The melting behavior of β-SiC with diamond structure was investigated under high pressures up to about 10 GPa using a flash-heating device. The peritectic temperature, at which the SiC decomposes into two phases of carbon saturated liquid Si and solid carbon (graphite) by a peritectic reaction, increases with pressure…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

High-Speed Third-Order Nonlinear Optical Response Using Organic Solutions

Hirohisa Kanbara、Seiji Fujiwara、Kōichiro Tanaka 等 4 位作者1998-01-01The Journal of Physical Chemistry A

We have observed high-speed third-order nonlinear optical response using organic solutions of π-conjugated low-molecular-weight compounds. Optical Kerr shutter (OKS) measurement, third-harmonic generation (THG) measurement, and a degenerate four-wave mixing (DFWM) experiment were carried out to examine the high-speed…

Nonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Transport of electronic excitation energy in solid-state glassy phosphors activated with europium (III) and copper (II)

I. M. Batyaev、A. M. Tinus1998-01-01Technical Physics Letters

A phosphor based on potassium aluminosilicophosphate glass activated with europium (III) and copper (II) has been synthesized. It has been shown that the europium luminescence is quenched by copper ions in the glass.

Luminescence Properties of Advanced MaterialsMedical Imaging Techniques and ApplicationsLanthanide and Transition Metal Complexes

Harmonic interaction between 1500 kVA supply transformer and VFD load at an industrial plant

M.M. Swamy、S.L. Rossiter1998-01-01IEEE Transactions on Industry Applications

The application of variable-frequency drives (VFDs) in industrial and commercial facilities has seen a tremendous increase. However, when multiple VFDs are fed from one dedicated power transformer, care should be taken not to drive the transformer into saturation. At one industrial location, nine VFDs rated at 200 HP…

Multilevel Inverters and ConvertersElectric Motor Design and AnalysisMagnetic Properties and Applications

Determination of the fluorite related structure of Mn3Ta2O8, using synchrotron X-ray powder and electron diffraction data

Saeid Esmaeilzadeh、Jêkabs Grîns、Andy Fitch1998-01-01Journal of Materials Chemistry

The Mn 2+ -containing oxide Mn 3 Ta 2 O 8 has been synthesised at 1200°C in Ar atmosphere, and its structure has been solved from X-ray synchrotron powder data (λ0.65 Å) by direct methods. The structure was refined by the Rietveld method to R F =6.3%, with space group I4 1 /a, a=11.2728(2), c=9.8030(3) Å, V=1243.47 Å…

Advanced Condensed Matter PhysicsNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Structural and Electrical Characterization of Ag3Ga5Te9 and Ag3In5Se9 Crystals

M. Parlak、Ç. Erçelebi、İ. Günal 等 5 位作者1998-01-01Crystal Research and Technology

X-ray powder diffraction studies revealed that Ag3Ga5Te9 and Ag3In5Se9 crystallize in orthorhombic and tetragonal systems, respectively. The temperature dependent conductivity and Hall effect measurements have been carried out between 65—480 K. Ag3Ga5Te9 exhibits p-type conduction with a room temperature conductivity…

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesPhase-change materials and chalcogenides

The Effect of Blowing Agent Solubility on the Long Term Dimensional Stability of Rigid Polyurethane Foams

S. N. Singh、G. Biesmans、M. Karremans 等 4 位作者1998-01-01Journal of Cellular Plastics

More environmentally acceptable blowing agents, such as hydrochlorofluoro-carbons (HCFCs), hydrofluorocarbons (HFCs), hydrocarbons, and carbon dioxide have now replaced chlorofluorocarbon (CFC) blowing agents in many rigid polyurethane (PUR) and polyisocyanurate-modified polyurethane (PIR) foam applications. However,…

Polymer composites and self-healingPolymer Foaming and Composites

Material Design for High Strength and Toughness of Continuous Fiber-Reinforced Ceramic Matrix Composites

Yoshiyasu Itoh、Tsuneji Kameda、Shoko Suyama 等 4 位作者1998-01-01Journal of the Ceramic Society of Japan

Crack growth behaviors in continuous fiber-reinforced ceramic matrix composites have been analyzed in termes of stress intensity factors using the finite-element method. Namely, the effects of Young's modulus ratio, Em/Ef, and fiber volume fraction, Vf, on the stress intensity factors have been investigated. As a resu…

Advanced ceramic materials synthesisInnovative concrete reinforcement materialsAluminum Alloys Composites Properties

FRAGMENTATION OF DENDRITIC CRYSTALS DURING SOLIDIFICATION OF AQUEOUS AMMONIUM CHLORIDE

William C. Montgomery、F. P. Incropera1998-01-01Experimental Heat Transfer

To obtain an improved understanding of the production, development, and transport of crystal fragments during directional solidification of binary alloys, experiments have been performed for an aqueous ammonium chloride solution. For vertical directional solidification (VDS) induced by cooling from below, fragmentatio…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaCrystallization and Solubility Studies