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Electron scattering by gas in the Environmental Scanning Electron Microscope (ESEM): Effects on the image quality and on the X-ray microanalysis

L. Khouchaf、Jan Verstraete2004-11-01Journal de Physique IV (Proceedings)

In this work, we studied the electron beam scattering due to the introduction of two gases : water vapour and helium within the specimen chamber of the Environmental Scanning Electron Microscope (ESEM) and the effects of this phenomenon on the image quality and on the microanalysis results. An increase in the pressure…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Steroids from the Roots ofCynanchum stauntonii

Peng Wang、Hai‐Lin Qin、Ling Zhang 等 6 位作者2004-11-01Planta Medica

A chemical investigation of the roots of Cynanchum stauntonii has resulted in the characterization of a new hydroperoxide with a 13,14 : 14,15-disecopregnane-type skeleton, named stauntonine (1), together with three related compounds, anhydrohirundigenin (2), anhydrohirundigenin monothevetoside (3), and glaucogenin-C…

Phytochemical compounds biological activitiesPhytochemistry and Bioactive CompoundsPhytochemistry and biological activities of Ficus species

The Growth Morphology of the {100} Surface of KDP (Archerite) on the Molecular Scale

Andrew G. Stack、J.R. Rustad、J. J. DeYoreo 等 5 位作者2004-11-01The Journal of Physical Chemistry B

The surface morphology of the {100} face growth hillock of potassium dihydrogen phosphate (KDP) is examined through first-principles calculations and using periodic-bonded-chain (PBC) theory. KDP, or archerite ([K, NH 4 ]H 2 PO 4 ), is used extensively in industry and is an excellent model for more complicated materia…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesCrystallization and Solubility Studies

Colloidal Systems with Attractive Interactions: Evaluation of Scattering Data Using the Generalized Indirect Fourier Transformation Method

Josef Innerlohinger、Hans M. Wyss、Otto Glatter2004-11-01The Journal of Physical Chemistry B

Different attractive interacting colloidal systems are characterized by means of static light scattering. As most of these samples are rather concentrated, multiple scattering is suppressed by partial contrast match and the use of very a thin sample cell (13 μm). This is possible with the laboratory built flat cell li…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

Size and Shape Determination of Proteins in Solution by a Noninvasive Depolarized Dynamic Light Scattering Instrument

Naomi E. Chayen、Matthias Dieckmann、Karsten Dierks 等 4 位作者2004-11-01Annals of the New York Academy of Sciences

Dynamic light scattering (DLS) is a well-known noninvasive technique for investigating interactions of protein molecules in solution. Unfortunately, DLS is not very sensitive to small size changes because covariables, such as temperature, viscosity, and refractive index, are not precisely known, or they vary as functi…

Protein Structure and DynamicsPhotosynthetic Processes and MechanismsEnzyme Structure and Function

Effects of Gravity on ZBLAN Glass Crystallization

Dennis S. Tucker、Edwin C. Ethridge、Guy A. Smith 等 4 位作者2004-11-01Annals of the New York Academy of Sciences

The effects of gravity on the crystallization of ZrF(4)-BaF(2)-LaF(3)-AlF(3)-NaF glasses have been studied using the NASA KC-135 and a sounding rocket. Fibers and cylinders of ZBLAN glass were heated to the crystallization temperature in unit and reduced gravity. When processed in unit gravity the glass crystallized,…

Material Dynamics and PropertiesGlass properties and applicationsMineralogy and Gemology Studies

Calorimetry of liquids in the system Na 2 O-Fe 2 O 3 -SiO 2

Toru Sugawara、Masaki Akaogi2004-11-01American Mineralogist

Transposed-temperature, drop-calorimetry measurements were performed in the systems Na 2 SiO 3 - Fe 2 O 3 -SiO 2 and Na 2 SiO 3 -NaFeSi 2 O 6 at 1373 K to investigate thermodynamic properties of Fe 3+ -bearing silicate liquids. The results confirm previously measured enthalpy of Na 2 SiO 3 and SiO 2 melts. No signific…

Metallurgical Processes and ThermodynamicsThermal and Kinetic AnalysisThermodynamic and Structural Properties of Metals and Alloys

Dependence of Physical Properties and Processing Behavior of Blends of Silicone Rubber and Fluororubber on Blend Morphology

Arun Ghosh、S. K. De2004-11-01Rubber Chemistry and Technology

Abstract The paper reports that the processing behavior and physical properties of the blends of silicone rubber and fluororubber based on tetrafluoroethylene/propylene/vinylidene terpolymer. The processing behavior of the fluororubber can be improved on blending with low viscous silicone rubber. The results indicate…

Surface Modification and SuperhydrophobicityPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Preclinical evaluation of a liposome-encapsulated formulation of cisplatin in clinically normal dogs

Amanda K. Marr、Ilene D. Kurzman、David M. Vail2004-11-01American Journal of Veterinary Research

OBJECTIVE: To determine the acute and short-term adverse effects of a liposome-encapsulated form of cisplatin at increasing dosages of up to twice the known maximally tolerated dose (MTD) of unencapsulated cisplatin in clinically normal dogs. ANIMALS: 4 healthy 2.5-year-old sexually intact female hound-type dogs. PROC…

Nanoparticle-Based Drug DeliveryAdvanced Drug Delivery SystemsChemotherapy-induced organ toxicity mitigation

Pitting Corrosion of Copper Tubes in Soft Drinking Waters: Corrosion Mechanism

David B. Harrison、David Nicholas、Geoffrey M. Evans2004-11-01American Water Works Association

The pitting corrosion of copper tubes in drinking water systems is a sporadic but persistent problem along the east coast of Australia, New Zealand, and other locations where predominantly soft water is found. Historically, the lack of an adequate theory for localized soft water copper corrosion has made remedial trea…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Properties and microstructure of ultrathin (La,Ca)MnO3 films under different conditions of strain

Z. Yang、Ruud Hendrikx、J. Aarts 等 5 位作者2004-11-01Physical Review B

Ultrathin films of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}\mathrm{Mn}{\mathrm{O}}_{3}$ $(x\ensuremath{\cong}0.33)$ in a thickness range below $10\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$ were deposited by direct current (dc) magnetron sputtering on different substrates, $(001)\mathrm{Sr}\mathrm{Ti}{\mathrm{O}…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Probing Gelation at the Molecular Level: Head‐to‐Tail Hydrogen‐Bonded Self‐Assembly of an Inositol‐Based Organogelator

Kana M. Sureshan、Kentaro Yamaguchi、Yoshihisa Sei 等 4 位作者2004-11-01European Journal of Organic Chemistry

Abstract A simple cyclitol derivative has been found to gelate many low‐polar solvents. A detailed molecular level investigation demonstrated that the intermolecular head‐to‐tail hydrogen bond plays a key role in the self‐assembly of the monomers to generate supramolecular polymeric fibres. Such self‐assembled oligome…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Extinction Coefficients and Purity of Single-Walled Carbon Nanotubes

Bin Zhao、Mikhail E. Itkis、Sandip Niyogi 等 6 位作者2004-11-01Journal of Nanoscience and Nanotechnology

Single-walled carbon nanotubes (SWNTs) hold great promise for advanced applications in aerospace, electronics and medicine, yet these industries require materials with rigorous quality control. There are currently no accepted standards for quality assurance or quality control among the commercial suppliers of SWNTs. W…

Carbon Nanotubes in CompositesAnalytical Chemistry and Sensorsthermodynamics and calorimetric analyses

Dynamic properties of edge dislocations decorated by interstitial loops in α-iron and copper

Yu.N. Osetsky、David Bacon、Z. Rong 等 4 位作者2004-11-01Philosophical Magazine Letters

Clusters of self-interstitial atoms (SIAs) in the form of parallel crowdions are created directly in high-energy displacement cascades produced in metals by neutron irradiation. They are equivalent to small perfect dislocation loops and, in isolation in pure metals, undergo fast thermally-activated glide in the direct…

Fusion materials and technologiesNuclear Materials and PropertiesIon-surface interactions and analysis

Thermo‐Mechanical and Morphological Characterization of Plasticized Poly[(R)‐3‐hydroxybutyric acid]

Elizabeth Grillo Fernandes、Matteo Pietrini、Emo Chiellini2004-11-01Macromolecular Symposia

Abstract Blends of poly[(R)3‐hydroxybutyryric acid) (PHB) with different plasticizers were investigated by TGA, DSC, OM and mechanical testing. Markedly hydrophilic plasticizers promote PHB thermal‐degradation through a light alcoholysis reaction. All the used plasticizers were compatible with PHB up to a maximum load…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsCarbon dioxide utilization in catalysis

Effective on-site Repulsion in Molecular Conductors with Dimeric Structure: Is the Transfer Integral a Good Measure of Correlation?

Masafumi Tamura、Reìzo Kato2004-11-01Journal of the Physical Society of Japan

The effective repulsive energy between the carriers in a molecular dimer has been examined in terms of the extended Hubbard model. The intermolecular Coulomb repulsion, V , rather than the intradimer transfer integral, t , has been shown to give major contribution to the effective repulsion in a strongly dimerized cas…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Benzo[1,2‐c:3,4‐c']bis[1,2,5]selenadiazole, [1,2,5]selenadiazolo‐[3,4‐e]‐2,1,3‐benzothiadiazole, furazanobenzo‐2,1,3‐thiadiazole, furazanobenzo‐2,1,3‐selenadiazole and related heterocyclic systems

Catherine M. Cillo、Timothy D. Lash2004-11-01Journal of Heterocyclic Chemistry

Abstract The first synthesis of benzo[1,2‐ c :3,4‐ c ']bis[1,2,5]selenadiazole has been developed starting from commercially available 4‐nitrobenzo‐2,1,3‐selenadiazole. Improved syntheses of the related heterocycles [1,2,5]selenadiazolo[3,4‐ e ]‐2,1,3‐benzothiadiazole, furazanobenzo‐2,1,3‐thiadiazole and furazanobenzo…

Porphyrin and Phthalocyanine ChemistrySynthesis and Biological EvaluationChemical Reactions and Mechanisms

Charge Storage in Corona-Charged Polypropylene Films Analyzed by LIPP and TSC Methods

Ryo Ono、Masatoshi Nakazawa、Tatsuki Oda2004-11-01IEEE Transactions on Industry Applications

Negatively corona-charged 50-/spl mu/m-thick polypropylene (PP) film is measured using laser-induced pressure pulse (LIPP) and thermally stimulated current (TSC) in order to study the charge storage mechanism in the PP film. The LIPP can reveal the space-charge distribution in the depth direction of the PP films and t…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaElectrostatic Discharge in Electronics

Line-profile and critical-dimension monitoring using a normal incidence optical CD metrology

Weidong Yang、Jiangtao Hu、R. Lowe-Webb 等 8 位作者2004-11-01IEEE Transactions on Semiconductor Manufacturing

As lithographic technology drives the minimum integrated circuit feature size toward 0.1 /spl mu/m and below, process tolerances for critical-dimension profile excursion are becoming increasingly demanding. In response, optical critical dimension metrology (OCD), an optical-wavelength light-diffraction technique, is e…

Advancements in Photolithography TechniquesOptical Coatings and GratingsSurface and Thin Film Phenomena

Environmentally Triggered Release of Oxygen-Reduction Inhibitors from Inherently Conducting Polymers

M. Kendig、Melitta Hon2004-11-01CORROSION

Background data are presented that support a concept for galvanic and ion exchange release of cathodic (oxygen reduction) corrosion inhibitors from conducting polyaniline (PANI). Such inherently conducting polymers can be potentially formulated into protective coatings for Cu-rich aluminum alloys. The results show tha…

Conducting polymers and applicationsAnalytical Chemistry and SensorsConcrete Corrosion and Durability