Materials Literature
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This review covers both the history and present state of the kinetics of thermally stimulated reactions in solids. The traditional methodology of kinetic analysis, which is based on fitting data to reaction models, dates back to the very first isothermal studies. The model fitting approach suffers from an inability to…
Poly(ethylene oxide) (PEO) polymer, in linear and star form, was covalently grafted to silicon surfaces, and the surfaces were tested for their ability to adsorb proteins. Linear PEG of molecular weight 3400, 10 000, and 20 000 g/mol and star PEO molecules were coupled via their terminal hydroxyl groups activated by t…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTPoly(Amidoamine) Dendrimer-Templated Nanocomposites. 1. Synthesis of Zerovalent Copper NanoclustersLajos Balogh and Donald A. TomaliaView Author Information Michigan Molecular Institute, 1910 W. St. Andrews Road Midland, Michigan 48640 Cite this: J. Am. Chem. Soc. 1998…
We solve exactly and describe in detail a simplified scalar model for the low frequency shear rheology of foams, emulsions, slurries, etc. [P. Sollich, F. Lequeux, P. H\'ebraud, and M. E. Cates, Phys. Rev. Lett. 78, 2020 (1997)]. The model attributes similarities in the rheology of such ``soft glassy materials'' to th…
Quantitative XPS has been used to determine the surface concentration of hydroxyl groups in native air-formed oxide films on metals having low surface areas. A mathematical expression has been derived to give the concentration of surface hydroxyl groups as a function of the intensity ratio of the OH to O2− contributio…
Abstract In the past few years, an enormous amount of work has been reported on the progress in the application of conventional fillers and the development of new products to improve the reinforcement of rubber, dynamic properties in particular. While all agree that the filler as one of the main components of the fill…
Imagine you are in the last stages of typing your thesis, the year is 1980, and it's a hot, hazy summer afternoon, a thunderstorm brews on the horizon. Tense and tired, you have forgotten to save the document on your hard disk. Suddenly, lightning strikes! Your computer shuts down. Your final chapter is lost.
Styroflex, a new styrenic thermoplastic elastomer, is obtained by sequential anionic polymerization of styrene and butadiene having a block sequence S-SB-S. It proved to match the property profile of plasticized PVC in the most important features such as transparency, mechanics, processability, and permeability. Impac…
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Physical organogels of a 4- tert -butyl-1-arylcyclohexanol derivative ( BACOl ) are investigated. The small-angle scattering (SAS) technique (neutrons and X-rays) demonstrates that gel networks result from the entanglement of long, solidlike, and rigid fibers. The related cross-sections are shown to be circular ( r ≈…
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The SERS (surface-enhanced Raman scattering) and SERRS (surface-enhanced resonant Raman scattering) spectra of iron(II) phthalocyanine (FePc) adsorbed onto a silver electrode have been investigated. The electrochemical SERRS has shown that the reduction of FePc molecule is reversible at negative potentials below −1.0…
The 'double exchange' mechanism and Jahn—Teller instabilities are shown to account for the low-temperature properties of slightly doped LaMnO3 in the framework of the band insulator model. Analysis of the doping of La1-xAxMnO3 with divalent A atoms suggests that Coulomb forces cause holes to be localized near dopants,…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTPolyelectrolyte Behavior of Astramol Poly(propyleneimine) DendrimersV. A. Kabanov, A. B. Zezin, V. B. Rogacheva, Zh. G. Gulyaeva, M. F. Zansochova, J. G. H. Joosten, and J. BrackmanView Author Information Polymer Science Department, Faculty of Chemistry, Moscow State University…
We have built an ab-initio LDA energy database with over 60 hypothetical extended structures of pure Boron, in each of which the coordination environment of each atom is equivalent. Focusing on eleven 6-coordinated structures, which are most relevant to the observed Boron phases, we deduce a nearest-neighbor-only 2-bo…
We report the direct measurement by video microscopy of the Van Hove function of quasi-two-dimensional colloidal suspensions. Under these conditions of confinement, the effective interparticle potential exhibits an intermediate range attractive component. This is obtained by deconvoluting the measured pair correlation…
We report a high energy and high angular resolution angle resolved photoemission study of $2H\ensuremath{-}{\mathrm{TaSe}}_{2}$ at temperatures both above and below the charge-density-wave (CDW) transition. In the normal state, an extended saddle band very close to the Fermi energy was observed. The CDW-induced energy…
The effect of substrate-induced lattice strains on the structural and magnetic properties of epitaxial barium ferrite (BaFe12O19) thin films is studied. The 5000 Å thick film shows a very narrow ferromagnetic resonance (FMR) line with a width of about 140 Oe. After appropriate annealing, the linewidth measured at 58 G…
3D domain swapping of proteins involves the interconversion of a monomer containing a single domain-domain interface and a 2-fold symmetrical dimer containing two equivalent intermolecular interfaces. Human glyoxalase I has the structure of a domain-swapped dimer [Cameron, A. D., Olin, B., Ridderström, M., Mannervik,…
${\mathrm{D}}_{3}{\mathrm{O}}^{+}$ and ${\mathrm{Cs}}^{+}$ ions $(\ensuremath{\le}1\mathrm{eV})$ were soft landed on vacuum-deposited amorphous water ice at 30 K. The samples charged capacitively with an initial dielectric constant of 2. Then the voltage was measured via a Kelvin probe while the sample temperature was…