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On the origin of the 1100 cm −1 Raman band in amorphous and nanocrystalline sp 3 carbon

Vincent Paillard2001-04-01Europhysics Letters (EPL)

Recently, the correlation between the 1100 cm −1 Raman band and the sp 3 fraction in amorphous or nanocrystalline carbon films was unambiguously demonstrated. From theoretical and experimental results on carbon-assembled materials, an explanation about the 1100 cm −1 Raman band origin is given. The difficulty to detec…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Rheooptical determination of aspect ratio and polydispersity of nonspherical particles

Jan Vermant、Haoxiang Yang、Gerald G. Fuller2001-04-01AIChE Journal

Abstract A rheooptical method proposed rapidly determines the aspect ratio and polydispersity of small axisymmetric, nonspherical particles. The time evolution of the average orientation angle of optically isotropic, nonabsorbing particles upon inception of a shear flow was monitored by a polarization modulation metho…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesComposite Material Mechanics

Diffuse scattering anisotropy and theP21/a↔A2/aphase transition in titanite, CaTiOSiO4

Thomas Malcherek、Carsten Paulmann、M. C. Domeneghetti 等 4 位作者2001-04-01Journal of Applied Crystallography

Diffuse scattering in titanite has been measured at three temperatures, 0.951 T c , 1.053 T c and 1.177 T c , using synchrotron radiation. T c = 487 K is the temperature of the antiferroelectric paraelectric phase transition. Charge-coupled device (CCD) intensity measurements were centred about the \bar{4}01 reciproca…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Effects of Silicone Treatments on the Dimensional Properties of Wool Fabric

Tae Jin Kang、Min Sun Kim2001-04-01Textile Research Journal

This study evaluates the effects of silicone softeners on the dimensional properties of wool fabric. Samples are treated with a simple pad-dry-cure process in an aqueous bath with aminofunctional and epoxyfunctional silicone softeners. The results indicate that dimensional stability and performance properties improve.…

Skin Protection and AgingDyeing and Modifying Textile FibersTextile materials and evaluations

Filmes poliméricos ultrafinos produzidos pela técnica de automontagem: preparação, propriedades e aplicações

Leonardo G. Paterno、L. H. C. Mattoso、Osvaldo N. Oliveira2001-04-01Química Nova

AND APPLICATIONS.The self-assembly technique is a powerful tool to fabricate ultrathin films from organic compounds aiming at technological applications in molecular electronics.This relatively new approach allows molecularly flat films to be obtained on a simple and cheap fashion from various types of material, inclu…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Polyesters ofω-Unsaturated Fatty Acid Derivatives

Siegfried Warwel、Jörg Tillack、Christof Demes 等 4 位作者2001-04-01Macromolecular Chemistry and Physics

Unsaturated polyesters, based on ω-unsaturated fatty acid esters from oleochemical resources and petrochemical diols, were synthesized via two different synthetic pathways. 9-decenoic and 10-undecenoic acid methyl ester I a, b were transesterified with petrochemical diols to produce the α,ω-alkylene di(un)decenoates I…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingSynthesis and properties of polymers

Effect of Interfacial Reaction on the Thermal Conductivity of Al–SiC Composites with SiC Dispersions

Chihiro Kawai2001-04-01Journal of the American Ceramic Society

The effect of interfacial reactions between Al and SiC on the thermal conductivity of SiC‐particle‐dispersed Al‐matrix composites was investigated by X‐ray diffraction and transmission electron microscopy (TEM), and the thermal barrier conductance ( h c ) of the interface in the Al–SiC composites was quantified using…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesThermal properties of materials

Corrosion behavior of nickel alloys in wet hydrofluoric acid

Raúl B. Rebak、Jeffrey R. Dillman、P. Crook 等 4 位作者2001-04-01Materials and Corrosion

Wet hydrofluoric acid at concentrations below approximately 60% is highly corrosive to glass, reactive metals, carbon steel and stainless steels. Nickel alloys offer moderate corrosion resistance over a wide range of acid concentration and temperature. The corrosion behavior of eleven commercial alloys was quantified…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsHydrogen embrittlement and corrosion behaviors in metals

Influence of plasticizers on the properties of edible films prepared from fish water-soluble proteins

Munehiko Tanaka、Kiyomi Iwata、Romanee Sanguandeekul 等 5 位作者2001-04-01Fisheries Science

The effects of type and concentration of plasticizers on the mechanical properties and water vapor permeability (WVP) of edible films from fish water-soluble proteins (FWSP) were investigated. Among plasticizers investigated in the present study, glycerol and polyethylene glycol (PEG) gave the films flexible structure…

Advanced Sensor and Energy Harvesting MaterialsNanocomposite Films for Food PackagingConducting polymers and applications

Riboflavin Synthase of Escherichia coli

Boris Illarionov、Kristina Kemter、Sabine Eberhardt 等 6 位作者2001-04-01Journal of Biological Chemistry

Conserved amino acid residues of riboflavin synthase from Escherichia coli were modified by site-directed mutagenesis. Replacement or deletion of phenylalanine 2 afforded catalytically inactive proteins. S41A and H102Q mutants had substantially reduced reaction velocities. Replacements of various other conserved polar…

Enzyme Structure and FunctionPlant Gene Expression AnalysisBiochemical and Molecular Research

Pulsed Laser Deposition of Transparent Conducting Indium Tin Oxide Films in Magnetic Field Perpendicular to Plume

Akio Suzuki Akio Suzuki、Tatsuhiko Matsushita、Takanori Aoki Takanori Aoki 等 5 位作者2001-04-01Japanese Journal of Applied Physics

In 2 O 3 doped with 5 wt% SnO 2 (indium-tin oxide(ITO)(5 wt%)) films have been deposited on glass and quartz substrates in a magnetic field generated from three pieces of rare–earth permanent magnets (1.25 T flux density) placed at every 120° angle to surround the plume produced by pulsed laser deposition using an ArF…

ZnO doping and propertiesPlasma Diagnostics and ApplicationsSurface Roughness and Optical Measurements

Squeezing Organic Conjugated Molecules—What Does One Learn?

M. Chandrasekhar、S. Guha、W. Graupner2001-04-01Advanced Materials

The effects of hydrostatic pressure on conjugated polymers, in particular polyphenyls (see Figure for monomer unit) have been studied using photoluminescence, absorption, photo-induced absorption, and Raman spectroscopy. The effect of pressure on the singlet and triplet excitons and polarons allows an understanding of…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsLuminescence and Fluorescent Materials

Low Voltage Operation of Nonvolatile Metal-Ferroelectric-Metal-Insulator-Semiconductor (MFMIS)-Field-Effect-Transistors (FETs) Using Pt/SrBi2Ta2O9/Pt/SrTa2O6/SiON/Si Structures

Eisuke Tokumitsu、Kojiro Okamoto、Hiroshi Ishiwara2001-04-01Japanese Journal of Applied Physics

We report p-channel metal-ferroelectric-metal-insulator-semiconductor (MFMIS)-field-effect-transistors (FETs) which can operate at a voltage as low as 3.5 V using Pt/SrBi 2 Ta 2 O 9 /Pt/SrTa 2 O 6 /SiON/Si structures. It is shown that the use of the saturated P – E hysteresis loop is effective to improve the data rete…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Illite “Crystallinity” Revisited

Michel Jaboyedoff、F. Bussy、Bernard Kübler 等 4 位作者2001-04-01Clays and Clay Minerals

Abstract The Kübler Index (KI) is defined as the full width at half-maximum height (FWHM) of the 10-Å X-ray diffraction peak of illite-smectite interstratified (I-S) clay minerals. The only parameters controlling the Kübler Index are assumed to be the mean number of layers (N) in the coherent scattering domains (CSD),…

Concrete and Cement Materials ResearchSoil and Unsaturated FlowClay minerals and soil interactions

The Potential of Waste Heat Thermoelectric Power Generation From Diesel Cycle and Gas Turbine Cogeneration Plants

Joseph Khedari Panya Yodovard2001-04-01Energy Sources

This study assesses the potential of waste heat thermoelectric power generation for diesel cycle and gas turbine cogeneration in the manufacturing industrial sector in Thailand. To this end, data from more than 27,000 factories from different sectors, namely, chemical product, food processing, oil refining, palm oil m…

Advanced Thermoelectric Materials and DevicesSolar Thermal and Photovoltaic SystemsHybrid Renewable Energy Systems

Thermal Expansion of Supported Thin Polymer Films: A Direct Comparison of Free Surface vs Total Confinement

Darrin J. Pochan、Eric K. Lin、Sushil K. Satija 等 4 位作者2001-04-01Macromolecules

Neutron reflectivity measurements on deuterated polystyrene (dPS) thin films reveal a strong dependence of the coefficient of thermal expansion (CTE) on both the thickness of the film and the specific confinement boundaries. A direct comparison is made between films on low energy, fluorinated polyimide (fPI) substrate…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermal properties of materials

An algorithm for solving the optical problem for stratified anisotropic media

S. P. Palto2001-04-01Journal of Experimental and Theoretical Physics

An algorithm for solving the Maxwell equations for propagation of light through anisotropic stratified media is considered. The algorithm uses the Berreman matrices of order 4 × 4. In contrast to the numerical methods suggested by Berreman, the new method is exact. The Sylvester theorem for calculating functions of a…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsOptical Polarization and Ellipsometry

Sonochemical Degradation of a Polydisperse Nonylphenol Ethoxylate in Aqueous Solution

K. Vinodgopal、Muthupandian Ashokkumar、Franz Grieser2001-04-01The Journal of Physical Chemistry B

The ultrasound (363 kHz) induced decomposition of a commercially available polydisperse nonylphenol ethoxylate surfactant (Teric GN9) has been investigated. The initial rate of decomposition was found to be a function of the monomer concentration of the surfactant below and above the critical micelle concentration. Ba…

Advanced oxidation water treatmentUltrasound and Cavitation PhenomenaOil Spill Detection and Mitigation

Integrated Sculptured Thin Films

Motofumi Suzuki、Yasunori Taga2001-04-01Japanese Journal of Applied Physics

We have demonstrated the integration of various morphologies generated by dynamic oblique deposition, during which the deposition angle and the azimuth of the substrate are varied. The layers with zigzag, helicoidal and cylindrical columns have been successfully stacked on a substrate without using any etching process…

ZnO doping and propertiesCopper Interconnects and ReliabilityOptical Coatings and Gratings

Electrospinning and Properties of Some Nanofibers

Alexandre Buer、S. C. O. Ugbolue、S. B. Warner2001-04-01Textile Research Journal

Electrospinning is a unique process that is capable of producing fibers with diameters ranging over several orders of magnitude, from the micrometer range typical of conventional fibers down to the nanometer range. Electrospun fibers possess unusually large surface-to-volume ratios and are expected to display morpholo…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics