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Reaction Kinetics on Complex Model Catalysts under Single Scattering Conditions

Jörg Libuda、Hans‐Joachim Freund2002-05-01The Journal of Physical Chemistry B

To approach a microscopic understanding of the reaction kinetics on complex surfaces of heterogeneous catalysts, we combine multimolecular beam techniques and a supported model catalyst approach. The model systems are prepared under ultrahigh vacuum (UHV) conditions and have been characterized in detail with respect t…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Synthetic, Structural, Magnetic, and Mössbauer Spectral Study of {Fe[HC(3,5-Me2pz)3]2}I2 and Its Spin-State Crossover Behavior

Daniel L. Reger、C.A. Little、Mark D. Smith 等 9 位作者2002-05-01European Journal of Inorganic Chemistry

The complex {Fe[HC(3,5-Me2pz)3]2}I2 (1) has been prepared from the reaction of FeI2 and HC(3,5-Me2pz)3 (pz = pyrazolyl ring) in a 1:2 ratio. The complex is high-spin in both the solid state and in solution at ambient temperature. In the solid state, magnetic susceptibility and Mössbauer spectral studies indicate that…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Structural and mechanical behavior of polypropylene/ maleated styrene‐(ethylene‐co‐butylene)‐styrene/sisal fiber composites prepared by injection molding

Xiaolin Xie、K. L. Fung、Robert K.Y. Li 等 5 位作者2002-05-01Journal of Polymer Science Part B Polymer Physics

Abstract Hybrid composites consisting of isotactic poly(propylene) (PP), sisal fiber (SF), and maleic anhydride grafted styrene‐(ethylene‐ co ‐butylene)‐styrene copolymer (MA‐SEBS) were prepared by melt compounding, followed by injection molding. The melt‐compounding torque behavior, thermal properties, morphology, cr…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesTribology and Wear Analysis

New Approaches Toward the Formation of Silicon-Carbon Bonds on Porous Silicon

Michael Stewart、Jillian M. Buriak2002-05-01Comments on Inorganic Chemistry

Porous silicon is a material of intense technological and fundamental interest, due to its high surface area, quantum confinement effects, light emission, and complex nanoscale architecture. There is a strong desire to be able to control the surface properties of this versatile material at will through functionalizati…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchSilicon Nanostructures and Photoluminescence

Tissue Engineered Heart Valves: Autologous Cell Seeding on Biodegradable Polymer Scaffold

Toshiharu Shinoka2002-05-01Artificial Organs

We previously reported on the successful creation of tissue-engineered valve leaflets and the implantation of these autologous tissue leaflets in the pulmonary valve position. Mixed cell populations of endothelial cells and fibroblasts were isolated from explanted ovine arteries. Endothelial cells were selectively lab…

Electrospun Nanofibers in Biomedical ApplicationsCardiac and Coronary Surgery TechniquesTissue Engineering and Regenerative Medicine

Rigorous electromagnetic analysis of dipole emission in periodically corrugated layers: the grating-assisted resonant-cavity light-emitting diode

Danaë Delbeke、Peter Bienstman、Ronny Bockstaele 等 4 位作者2002-05-01Journal of the Optical Society of America A

We study the grating-assisted light-emitting diode, an LED design for high brightness based on a resonant cavity containing one- or two-dimensionally periodically corrugated layers (grating). We give in detail a generally applicable electromagnetic analysis based on the rigorous coupled-wave theory to calculate the ex…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Sodium Niobate (NaNbO3) Powders Synthesized by a Wet-Chemical Method Using a Water-Soluble Malic Acid Complex

Emerson R. Camargo、Mónica Popa、Masato Kakihana2002-05-01Chemistry of Materials

Sodium niobate powders were prepared by the amorphous complex method using a water-soluble Nb−malic acid complex and sodium carbonate. Niobium oxide pentahydrate was dissolved in hot oxalic acid solution, followed by the addition of NH 3 (30%) until pH = 11, precipitating niobic acid that was added into a solution of…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Scanning tunneling microscopy study of WS2 nanotubes

Luana Scheffer、R. Rosentzveig、A. Margolin 等 7 位作者2002-05-01Physical Chemistry Chemical Physics

Inorganic nanotubes of WS2 have been investigated by high-resolution transmission electron microscopy, and scanning tunneling microscopy, providing support for the theoretical prediction of correlation of bandgap with diameter.

Graphene research and applications2D Materials and ApplicationsNanowire Synthesis and Applications

Production of a Biodegradable Plastic Polymer, Poly‐β‐Hydroxybutyrate, in Transgenic Alfalfa

Purev Saruul、Friedrich Srienc、David A. Somers 等 4 位作者2002-05-01Crop Science

Alfalfa ( Medicago sativa L.) is primarily used as a source of forage and animal feed. Improving the economic value of alfalfa could be achieved by developing new uses of this perennial crop. To investigate the potential of alfalfa as a source of industrial materials, we employed a genetic transformation approach to p…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionBiopolymer Synthesis and Applications

Resealing of Polyelectrolyte Capsules after Core Removal

Gemma Ibarz、Lars Dähne、Edwin Donath 等 4 位作者2002-05-01Macromolecular Rapid Communications

Poly(styrene sulfonate) and poly(allylamine hydrochloride) layers have been adsorbed supplementarily on polyelectrolyte capsules. The permeability of the original capsules consisting of four layer pairs was of the order of 10–5 m/s for fluorescein. They were also permeable for macromolecules. Polyelectrolyte layers ad…

Polymer crystallization and propertiesPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Mutational Analysis of All Conserved Basic Amino Acids in RAG-1 Reveals Catalytic, Step Arrest, and Joining-Deficient Mutants in the V(D)J Recombinase

Leslie E. Huye、Mary M. Purugganan、Ming‐Ming Jiang 等 4 位作者2002-05-01Molecular and Cellular Biology

Although both RAG-1 and RAG-2 are required for all steps of V(D)J recombination, little is known about the specific contribution of either protein to these steps. RAG-1 contains three acidic active-site amino acids that are thought to coordinate catalytic metal ions. To search for additional catalytic amino acids and…

Ubiquitin and proteasome pathwaysEnzyme Structure and FunctionGenetics and Neurodevelopmental Disorders

Conversion of Polycrystalline Al 2 O 3 into Single‐Crystal Sapphire by Abnormal Grain Growth

Curtis Scott、Mary Kaliszewski、C. Greskovich 等 4 位作者2002-05-01Journal of the American Ceramic Society

In a given batch more than 30%–40% of polycrystalline, MgO‐doped Al 2 O 3 tubes were converted into single crystals of sapphire by abnormal grain growth (AGG) in the solid state at 1880°C. Most crystals grew 4–10‐cm in length in tubes with wall thicknesses of 1/2 and 3/4 mm and outer diameters of 5 and 7 mm, respectiv…

Solidification and crystal growth phenomenaMetallurgical Processes and ThermodynamicsAcoustic Wave Resonator Technologies

Molecular orbital calculations on aluminosilicate tricluster molecules: Implications for the structure of aluminosilicate glasses

James D. Kubicki、Michael J. Toplis2002-05-01American Mineralogist

Ab initio, molecular orbital calculations were carried out to study the energetic stability and NMR characteristics of “triclusters” of composition [T(XO)(OH) 2 ]O[Al(OH) 3 ][T(OH) 3 ] (X = no atom, H + , Li + , Na + , K + , Mg 2+ , or Ca 2+ ; T = Si 4+ or Al 3+ ). These triclusters consist of a central oxygen atom in…

Zeolite Catalysis and SynthesisGlass properties and applicationsNuclear materials and radiation effects

Characterization of the Free‐Carbon Phase in Si‐C‐N Ceramics: Part II, Comparison of Different Polysilazane Precursors

Stephan Traßl、Hans‐Joachim Kleebe、Heike Störmer 等 6 位作者2002-05-01Journal of the American Ceramic Society

The excess carbon of various polysilazane precursors with varying carbon contents was investigated using 13 C MAS NMR, Raman and ESR spectroscopies, and microwave conductivity measurements. Microstructure characterization was investigated using TEM. The collected data were compared with those from a previous study on…

Advanced ceramic materials synthesisGlass properties and applicationsOrganoboron and organosilicon chemistry

Fatigue behavior of polycrystalline thin copper films

Oliver Kraft、P. Wellner、M. Hommel 等 5 位作者2002-05-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Author: Kraft, O. et al.; Genre: Journal Article; Issued: 2002-05; Keywords: MPI für Intelligente Systeme; Ehemalige Abt. Arzt; 14-ar_2002; fatigue; thin films; size effect; Title: Fatigue behavior of polycrystalline thin copper films

Metal and Thin Film MechanicsElectronic Packaging and Soldering TechnologiesCopper Interconnects and Reliability

Miscibility evolution of polycarbonate/polystyrene blends during compounding

C. Z. Chuai、Kristoffer Almdal、I. Johannsen 等 4 位作者2002-05-01Polymer Engineering and Science

Abstract The miscibility evolution of polycarbonate/polystyrene (PC/PS) blends during the compounding process in three blending methods of industrial relevance, namely melt blending, remelt blending in a twin‐screw extruder and third melt blending in an injection molding machine, was investigated by measuring their gl…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Caldimonas manganoxidans gen. nov., sp. nov., a poly(3-hydroxybutyrate)-degrading, manganese-oxidizing thermophile

Minoru Takeda2002-05-01INTERNATIONAL JOURNAL OF SYSTEMATIC AND EVOLUTIONARY MICROBIOLOGY

Microbiology Society journals contain high-quality research papers and topical review articles. We are a not-for-profit publisher and we support and invest in the microbiology community, to the benefit of everyone. This supports our principal goal to develop, expand and strengthen the networks available to our members…

Diatoms and Algae Research

The diatom genus Thalassiosira: species from the northern San Matias Gulf (Rio Negro, Argentina)

Eugenia A. Sar、Inés Sunesen2002-05-01Nova Hedwigia

This study deals with the morphology, taxonomy and distribution of species belonging to the diatom genus Thalassiosira found in the marine waters along the northern coast of San Matias Gulf, Argentina. Net samples were collected from the surface layer of the water column at Punta Orengo, Las Garzas, Banco Reparo, Los…

Marine Biology and Ecology ResearchDiatoms and Algae Research

Separation of Hydrogen Isotopes by Thermal Cycling Absorption Process: An Experimental Device

Didier Ducret、C. Laquerbe、A. Ballanger 等 7 位作者2002-05-01Fusion Science & Technology

The separation of hydrogen isotopes is an essential element for tritium processing systems. A new process invented at the Savannah River Site, has been developed at Valduc facility: Thermal Cycling Absorption Process. This system uses palladium packed in a column to absorb a stream of hydrogen isotopes. By repeated he…

Fusion materials and technologiesHydrogen Storage and MaterialsParticle accelerators and beam dynamics