Materials Literature
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Colloidal nanocrystal quantum dots (NQDs) of narrow band gap materials are of substantial general interest because of their unparalleled potential as infrared fluorophores. While PbSe NQDs are a promising class of infrared-active nanocrystals due to high emission quantum yields and a wide useful spectral range, typica…
Abstract A promising new dimension in the field of biotechnology is the use of microorganisms for the production of inorganic nanoscale particles. The interest in nanotechnology is provoked by the unique properties of nanostructured materials and their potential fields of application ranging from medicine to electroni…
We examine the stability of the valence bond solid (VBS) phase against the Dzyaloshinskii-Moriya (DM) interaction in the bipartite lattice. Despite the VBS is vulnerable against the antiferromagnetic interaction, for example in the Q-J model proposed by Sandvik, where the quantum phase transition occurs at $J^*/Q = 0.…
We report synthesis of phase pure multiferroic YMnO3 thin films on sapphire (0001) with conducting ZnGaO buffer contact layer. Films were prepared by using pulsed laser deposition technique and characterized using x-ray diffraction, scanning electron microscopy, energy dispersive absorption spectroscopy, and magnetic…
Recently it has been shown by the present author [H. Hasegawa, Phys. Rev. E (in press): arXiv:0904.2399] that the interpolation approximation (IA) to the generalized Bose-Einstein and Femi-Dirac distributions yields results in agreement with the exact ones within the $O(q-1)$ and in high- and low-temperature limits, w…
The temperature dependences of magnetization, electrical transport, and thermal transport properties of antiperovskite compound SnCMn3 have been investigated systematically. A positive magnetoresistance (∼11%) is observed around the ferrimagnetic-paramagnetic transition (TC∼280 K) in the field of 50 kOe, which can be…
We present the role of Pd ensembles in the selective direct synthesis of H 2 O 2 from H 2 and O 2 on a PdAu alloy surface based on periodic density functional theory calculations. Our calculations demonstrate that H 2 O 2 formation is strongly affected by the spatial arrangement of Pd and Au surface atoms. In particul…
The inner-shell single and double ionization spectra of the organic molecule para-aminophenol are calculated using many-body Green's function methods. The inner-shell double ionization spectrum displays more pronounced sensitivity to the chemical environment and to electronic many-body effects than does the inner-shel…
Many reports have been published about the biogenesis of silver nanoparticles using several plant extracts such as Pelargonium graveolens (P.graveolens- geranium) and Azadirachta indica (neem) but the capacity of their natural reducing constituents to form silver nanoparticles has not yet been studied. In this researc…
A broad range of nanomedicines is being developed to improve drug delivery for CNS disorders. The structure of the blood-brain barrier (BBB), the presence of efflux pumps and the expression of metabolic enzymes pose hurdles for drug-brain entry. Nanoformulations can circumvent the BBB to improve CNS-directed drug deli…
A simple method of synthesizing K2GeF6:Mn4+ red phosphor has been demonstrated by wet chemical etching of Ge shots in HF/KMnO4 mixed solution. The x-ray diffraction pattern suggests that the synthesized phosphor has the trigonal structure (space group=D3d3–P3¯m1). The optical properties of K2GeF6:Mn4+ are investigated…
As shape memory alloys (SMAs) gain popularity as high energy density actuators, one characteristic that becomes particularly important is the thermomechanical transformation fatigue life, in addition to maximum transformation strain and stability of actuation cycles. In this paper, a novel test frame design and testin…
Cellulose is one of the most abundant component of biomass in nature and the basic feedstock in paper and pulp industries. Cellulose fibres are relatively strong; have breaking strengths of up to 1 GN/m2 (10,000 MPa). Traditionally extracted from plant tissue (trees, cotton, etc.) cellulose can also be produced, using…
Dysprosium doped ZnO–B2O3–P2O5 (ZBP) glasses were prepared by a conventional melt quenching technique in order to study the luminescent properties and their utility for white light emitting diodes (LEDs). X-ray diffraction spectra revealed the amorphous nature of the glass sample. The present glasses were characterize…
A microscopic approach is presented for calculating general properties of interacting Brownian particles under steady shearing. We start from exact expressions for shear-dependent steady-state averages, such as correlation and structure functions, in the form of generalized Green-Kubo relations. To these we apply appr…
β-Al 2 x Ga 2-2 x O 3 alloy thin films were successfully grown on (100)-oriented β-Ga 2 O 3 single-crystal substrates by plasma-assisted molecular beam epitaxy. The films were grown almost coherently and maintained the β-phase up to an Al content of x =0.61. Below an Al content of about x =0.4, step-flow growth was ac…
Wound healing is a dynamic interactive process that involves a sequence of molecular and cellular events. Recent advances in cellular and molecular biology have greatly expanded our understanding of the biological process involved in wound repair and tissue regeneration. From plasma extravasation, with coagulation and…
The adsorption/desorption of NO x on commercial Ce x Zr 1− x O 2 solid solutions ( x = 1, 0.85, 0.69, 0.5, 0.21, 0.1, and 0) is reported in this paper. In the first part, the characterization of the ceria-zirconia is carried out by N 2 adsorption at 77 K, TEM, Raman, XRD, and DRIFTS in order to establish relationships…
Carbon-supported palladium, gold, and bimetallic Pd−Au nanocatalysts with different compositions were synthesized by a “water-in-oil” microemulsion method. Their catalytic activity toward borohydride electrooxidation was evaluated in alkaline medium. Physical and electrochemical methods where applied to characterize t…
Polyimide (PI) and PI nanocomposite fibers containing different amounts of multiwalled carbon nanotubes (MWNTs) were produced for the first time by electrospinning. The membranes prepared were composed of highly aligned nanofibers and showed significant enhancement in mechanical properties, compared with the membranes…