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Facile and efficient exfoliation of inorganic layered materials using liquid alkali metal alloys

Hongbin Feng、Zhongbo Hu、Xiangfeng Liu2015-01-01Chemical Communications

A facile and efficient exfoliation process has been reported to produce single- and few-layer nanosheets of MoS2, WS2 and BN using liquid alloys of alkali metals at room temperature. The colloidal dispersions of MoS2 and WS2 layers were highly stable over several months, which allowed us to easily prepare films of MoS…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Vertically and compactly rolled-up reduced graphene oxide film/epoxy composites: a two-stage reduction method for graphene-based thermal interfacial materials

Dong Han、Yunhong Zhao、Yafei Zhang 等 4 位作者2015-01-01RSC Advances

Schematic of the fabrication procedure of thermal-reduced vertically aligned reduced graphene oxide (TR-VArGO)/epoxy composite. This efficient and simple method includes two reduction stages to fabricate a thermal-reduced VArGO (TR-VArGO)/epoxy composite.

Graphene research and applicationsThermal properties of materialsFiber-reinforced polymer composites

Strong emission of 2,4,6-triphenylpyridine-functionalized polytyrosine and hydrogen-bonding interactions with poly(4-vinylpyridine)

Mohamed Gamal Mohamed、Fang-Hsien Lu、Jin‐Long Hong 等 4 位作者2015-01-01Polymer Chemistry

The emission intensity of Pyridine-PTyr decreased after blending with P4VP and underwent a hypsochromic shift from 536 to 489 nm due to the release of the restricted intramolecular rotation of the triphenyl pyridine unit in the center of the polymer.

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Graphene oxide-assisted preparation of poly(vinyl alcohol)/carbon nanotube/reduced graphene oxide nanofibers with high carbon content by electrospinning technology

Yao Song、Yanbao Li、Zhi-Hang Zhou 等 4 位作者2015-01-01RSC Advances

Electrospun PVA/RGO/MWCNT nanofibers with high carbon content prepared via a well-dispersed MWCNT/PVA solution with a assistance of GO have a relatively high electrical conductivity.

Graphene research and applicationsSupercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical Applications

Singlet–triplet annihilation in single LHCII complexes

J. Michael Gruber、Jevgenij Chmeliov、Tjaart P. J. Krüger 等 5 位作者2015-01-01Physical Chemistry Chemical Physics

In light harvesting complex II (LHCII) of higher plants and green algae, carotenoids (Cars) have an important function to quench chlorophyll (Chl) triplet states and therefore avoid the production of harmful singlet oxygen. The resulting Car triplet states lead to a non-linear self-quenching mechanism called singlet-t…

Lanthanide and Transition Metal ComplexesAdvanced NMR Techniques and ApplicationsAtomic and Subatomic Physics Research

Group 1 and group 2 metal complexes supported by a bidentate bulky iminopyrrolyl ligand: synthesis, structural diversity, and ε-caprolactone polymerization study

Ravi K. Kottalanka、Adimulam Harinath、Supriya Rej 等 4 位作者2015-01-01Dalton Transactions

We report here a series of alkali and alkaline earth metal complexes, each with a bulky iminopyrrolyl ligand [2-(Ph3CN=CH)C4H3NH] (1-H) moiety in their coordination sphere, synthesized using either alkane elimination or silylamine elimination methods or the salt metathesis route. The lithium salt of molecular composit…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Structure–barrier property relationship of biodegradable poly(butylene succinate) and poly[(butylene succinate)-co-(butylene adipate)] nanocomposites: influence of the rigid amorphous fraction

Sébastien Charlon、Stéphane Marais、Éric Dargent 等 6 位作者2015-01-01Physical Chemistry Chemical Physics

Composites composed of polyesters, poly(butylene succinate) (PBS) or poly[(butylene succinate)-co-(butylene adipate)] (PBSA), and 5 wt% of montmorillonite (CNa) or organo-modified montmorillonite (C30B) were melt-processed and transformed into films by either compression-molding or extrusion-calendering. XRD, rheologi…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Catalytically engineered reduced graphene oxide/ZnO hybrid nanocomposites for the adsorption, photoactivity and selective oil pick-up from aqueous media

K. B. Babitha、J. Jani Matilda、Alaa Mohamed 等 4 位作者2015-01-01RSC Advances

Microwave mediated in situ growth of nanocrystalline ZnO on rGO nanosheets is achieved using APTMS as the crosslinking agent. The deposition of hydrophobic ZnO/Si@rGO on a simple cotton textile results in the selective adsorption of oil from aqueous media.

Graphene research and applicationsZnO doping and propertiesGas Sensing Nanomaterials and Sensors

Development of rare-earth-free phosphors for eco-energy lighting based LEDs

Rachod Boonsin、Geneviève Chadeyron、Jean‐Philippe Roblin 等 5 位作者2015-01-01Journal of Materials Chemistry C

Several phosphors without rare-earth elements were synthesized by a simple and practical method.

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsAmmonia Synthesis and Nitrogen Reduction

Experimental Investigation of the Properties of Electrospun Nanofibers for Potential Medical Application

Anhui Wang、Chao Xu、Chuanwei Zhang 等 5 位作者2015-01-01Journal of Nanomaterials

Polymer based nanofibers using ethylene‐co‐vinyl alcohol (EVOH) were fabricated by electrospinning technology. The nanofibers were studied for potential use as dressing materials for skin wounds treatment. Properties closely related to the clinical requirements for wound dressing were investigated, including the fluid…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation

Porous PCL/Chitosan and nHA/PCL/Chitosan scaffolds for tissue engineering applications: fabrication and evaluation

Rashid Mad Jin、Naznin Sultana、Sayang Baba 等 5 位作者2015-01-01Journal of Nanomaterials

Two semicrystalline polymers were blended to fabricate porous scaffolds for tissue engineering applications. Scaffolds containing polycaprolactone (PCL)/chitosan and nanohydroxyapatite (nHA) incorporated nHA/PCL/chitosan were produced using the freeze-drying technique. A model drug, tetracycline hydrochloride (tetracy…

Bone Tissue Engineering MaterialsNanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical Applications

Biocomposite of Cassava Starch Reinforced with Cellulose Pulp Fibers Modified with Deposition of Silica (SiO 2 ) Nanoparticles

Joabel Raabe、Alessandra de Souza Fonseca、Lina Bufalino 等 8 位作者2015-01-01Journal of Nanomaterials

Eucalyptus pulp cellulose fibers were modified by the sol‐gel process for SiO 2 superficial deposition and used as reinforcement of thermoplastic starch (TPS). Cassava starch, glycerol, and water were added at the proportion of 60/26/14, respectively. For composites, 5% and 10% (by weight) of modified and unmodified p…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Dynamics of suspensions of hydrodynamically structured particles: analytic theory and applications to experiments

Jonas Riest、Thomas Eckert、Walter Richtering 等 4 位作者2015-01-01Soft Matter

We present an easy-to-use analytic toolbox for the calculation of short-time transport properties of concentrated suspensions of spherical colloidal particles with internal hydrodynamic structure, and direct interactions described by a hard-core or soft Hertz pair potential. The considered dynamic properties include s…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsElectrostatics and Colloid Interactions

Preparation and Characterization of Transparent Conductive SnO2-F Thin Film Deposited by Spray Pyrolysis: Relationship between Loading Level and Some Physical Properties

Supriyono Supriyono、Hedi Surahman、Yuni Krisyuningsih Krisnandi 等 4 位作者2015-01-01Procedia Environmental Sciences

Relationship between loading level and some physical properties of the SnO2-F film has been investigated. SnO2-F thin films were prepared by spray pyrolysis technique using modified respiratory therapist nebulizer at substrate temperature in the range of 400-520̊C. A stannous chloride solution was used as precursor an…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Lanthanide-based Single Molecule Magnets

Min Ren、Li‐Min Zheng2015-01-01化学学报

Single-molecular magnets (SMMs) that display magnetic bistability and slow relaxation process have unique potential in ultrahigh-density memory components and spintronic devices. Lanthanide-based SMMs (Ln-SMMs) have sparked increasing interest recently due to the large magnetic moments and large magnetic anisotropy. A…

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesAdvanced NMR Techniques and Applications

Analysis of optoelectronic properties and development of new persistent phosphor in Ce3+-doped garnet ceramics

Jumpei Ueda2015-01-01Journal of the Ceramic Society of Japan

Ce3+-doped garnet materials have attracted a great deal of attention in w-LEDs and scintillators applications because of their various optical properties. In 2011, we reported intense photocurrent by blue light excitation in Y3Al5−xGaxO12 (Yttrium Aluminum Gallium Garnet, YAGG):Ce3+ phosphors with high Ga content. Wit…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsRadiation Detection and Scintillator Technologies