Materials Literature
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Solubility guidelines enable the use of high molar mass block copolymers and ABC triblock terpolymers for the coassembly of titania nanostructures.
Cellulose/AgNP biocomposites were synthesized using SPP and assessed for their antimicrobial activity against several human pathogens.
Four Ru(II)/Ir(III) metalloligands have been designed and synthesized from polypyridine and bibenzimidazole (BiBzIm) organic ligands, which show strong visible light absorption via metal-to-ligand charge transfer (MLCT) transitions. Nd/Yb(III) complexes were further assembled from these Ru(II)/Ir(III) metalloligands,…
CaO:Bi phosphor powders were successfully synthesized by the sol–gel combustion method. Both blue and orange emission were obtained with CL excitation, Bi 2+ in the BiO clusters was responsible to the orange emission under electron beam excitation.
This study reports a new pH sensor based on BSA-capped copper nanoclusters. The proposed pH sensor provides better sensitivity and a wider ranging pH response compared with other metal nanoclusters reported in the literature.
GQDs have a remarkable sensitization effect on the photocurrent of ZNRA, which is due to the interfacial charge transfer.
We have studied how cellulose nanocrystals (CNC) self-assemble into liquid crystalline phases in shrinking, isolated droplets. By adjusting the water dissolution rate of an aqueous CNC droplet immersed in a binary toluene-ethanol mixture we can control the final morphology of the consolidated microbead. At low ethanol…
The corrosion inhibition performance of 1-decyl-3-methylimidazolium chloride (DMICL) on mild steel was investigated in a carbon dioxide-saturated NaCl solution at pH 3.8 and 6.8.
Although the notion of mechanical noise is expected to play a key role in the non-linear rheology of athermally sheared amorphous systems, its characterization has so far remained elusive. Here, we show using molecular dynamic simulations that in spite of the presence of strong spatio-temporal correlations in the syst…
CdTe QDs caused the formation of transgenerational toxicity in nematodes. The intestinal barrier may play a crucial role in combatting the transgenerational toxicity of CdTe QDs.
In recent years, silver nanoparticles (AgNPs) have attracted significant attention owing to their unique physicochemical, optical, conductive and antimicrobial properties. One of the properties of AgNPs which is crucial for all applications is their stability. In the present study we unravel a mechanism through which…
The static and dynamic magnetic properties of a pentacoordinate [Co(phen)(DMSO)Cl2] compound (phen = 1,10'-phenanthroline, DMSO = dimethyl sulfoxide) were thoroughly studied by experimental (SQUID magnetometry and HF-EPR spectroscopy) and theoretical methods (DFT and CASSCF calculations). It has been found from temper…
A novel phosphate RbZnPO4 has been developed for the first time and the characteristic crystal structure of RbZnPO4 has been investigated in detail, based on the Fourier transform infrared reflection spectra and the structure refinement of X-ray diffraction data. After doping with Eu(3+),RbZnPO4:Eu(3+) shows distincti…
The poling efficiency enhancement of tethered binary dipolar chromophores significantly improves the performance of organic electro-optic materials for optical modulation.
The 8-hydroxyquinoline (8-HQ) molecule is an efficient corrosion inhibitor for aluminum and is also used in organic electronic devices. In this paper, the adsorption modes of 8-HQ and its derivatives (tautomer, dehydrogenated and hydrogenated species) on the Al(111) surface are characterized using dispersion corrected…
Mesoporous silica nanoparticles functionalised with aggregation-induced emission (AIE) luminogen via a carbon-nitrogen double bond are fabricated into films by a dip-coating method. The as-made films can serve as efficient fluorescent sensors for the naked-eye detection of volatile acid gases by colour and emission ch…
Facile construction of fluorescent polymeric aggregates with various morphologies was realized by self-assembly of supramolecular amphiphilic graft copolymers.
Porous carbons were synthesised using hydrochars from low cost precursors. Electrochemical behaviour is influenced by synthesis conditions and precursors used.
Controlling alloy nanoparticles with atomic monodispersity is challenging, and the recently revealed anti-galvanic reduction (AGR) provides a unique solution to this challenge. Herein we demonstrate that AGR is ion-precursor and ion-dose dependent, which offers novel strategies to tune the composition, structure and p…
The local destruction and deformation characteristics of a concrete target impacted by a rigid projectile were analyzed, and the similarity laws for local damage effects in the concrete target were studied utilizing the rigid-plastic, internal friction, and modified hydrodynamic models. For a thin target, the impact f…