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Calorimetric evidence for a mobile surface layer in ultrathin polymeric films: poly(2-vinyl pyridine)

Sherif Madkour、Huajie Yin、Marieke Füllbrandt 等 4 位作者2015-01-01Soft Matter

Specific heat spectroscopy was used to study the dynamic glass transition of ultrathin poly(2-vinyl pyridine) films (thicknesses: 405-10 nm). The amplitude and the phase angle of the differential voltage were obtained as a measure of the complex heat capacity. In a traditional data analysis, the dynamic glass transiti…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Ultradrawing and Ultimate Tenacity Properties of Ultrahigh Molecular Weight Polyethylene Composite Fibers Filled with Nanosilica Particles with Varying Specific Surface Areas

Jen‐Taut Yeh、Chuen‐Kai Wang、Lu-Kai Huang 等 5 位作者2015-01-01Journal of Nanomaterials

Original and/or functionalized nanosilica particles with a quoted specific surface area of 100, 300, and 600 m2/g, respectively, were used to investigate the influence of specific surface areas of nanosilica particles on ultradrawing and ultimate tensile properties of ultrahigh molecular weight polyethylene (UHMWPE),…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Sunlight-activated graphene-heterostructure transparent cathodes: enabling high-performance n-graphene/p-Si Schottky junction photovoltaics

Po‐Hsun Ho、Wei-chen Lee、Yi‐Ting Liou 等 13 位作者2015-01-01Energy & Environmental Science

A record-high efficiency (>10%) was achieved for an n-graphene/p-Si Schottky junction solar cell by using the “sunlight-activated” graphene/TiO x transparent cathode.

Graphene research and applicationsSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Unique surface modified aramid fibers with improved flame retardancy, tensile properties, surface activity and UV-resistance through in situ formation of hyperbranched polysiloxane–Ce 0.8 Ca 0.2 O 1.8 hybrids

Xiaoling Zhu、Li Yuan、Guozheng Liang 等 4 位作者2015-01-01Journal of Materials Chemistry A

Unique aramid fibers with hyperbranched polysiloxane–Ce 0.8 Ca 0.2 O 1.8 hybridized coating were prepared, which have outstanding flame retardancy, tensile properties, surface activity and UV-resistance owing to the nature and synergistic effect of hybrids.

Flame retardant materials and propertiesFiber-reinforced polymer compositesSynthesis and properties of polymers

Seedless synthesis of gold nanorods using dopamine as a reducing agent

Anton V. Liopo、Shaowei Wang、Paul J. Derry 等 5 位作者2015-01-01RSC Advances

The first example of seedless synthesis of gold nanorods using dopamine as a reducing agent is described in this work.

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Imaging the lipid bilayer of giant unilamellar vesicles using red-to-blue light upconversion

Sven H. C. Askes、Néstor López Mora、Rolf Harkes 等 8 位作者2015-01-01Chemical Communications

Red-to-blue triplet-triplet annihilation upconversion was obtained in giant unilamellar vesicles. The upconverted light was homogeneously distributed across the membrane and could be utilized for the imaging of individual giant vesicles in three dimensions. These results show the great potential of TTA-UC for imaging…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsPhotoreceptor and optogenetics research

Lanthanide complexes with 2-(tosylamino)benzylidene-N-benzoylhydrazone, which exhibit high NIR emission

Valentina V. Utochnikova、Anton Kovalenko、А. С. Бурлов 等 8 位作者2015-01-01Dalton Transactions

New NIR emitting materials were found among the lanthanide complexes with 2-(tosylamino)benzylidene-N-benzoylhydrazone. Complexes of Nd(3+), Er(3+) and Yb(3+), as well as Eu(3+), Gd(3+) and Lu(3+), were synthesized for the first time. Owing to the absence of vibration quenching the ytterbium complex was found to exhib…

Organic Light-Emitting Diodes ResearchMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Bifunctional Ce 1−x Eu x O 2 (0 ≤ x ≤ 0.3) nanoparticles for photoluminescence and photocatalyst applications: an X-ray absorption spectroscopy study

Aditya Sharma、Mayora Varshney、Jaehun Park 等 6 位作者2015-01-01Physical Chemistry Chemical Physics

Ce1-xEuxO2 (0 ≤x≤ 0.3) nanoparticles (NPs) were synthesized by the chemical precipitation method. The microstructures and morphology were characterized by synchrotron X-ray diffraction and high resolution transmission electron microscopy. X-ray absorption near edge structure (XANES) spectra at the Eu M5,4-edge and ato…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsCatalytic Processes in Materials Science

Electrodeposition of ultrathin nickel–cobalt double hydroxide nanosheets on nickel foam as high-performance supercapacitor electrodes

Junheng Xing、Shaoyan Wu、K. Y. Simon Ng2015-01-01RSC Advances

The present work demonstrates a facile, one-step electrodeposition approach for the preparation of ultrathin Ni–Co double hydroxide (DH) nanosheets on Ni foam as supercapacitor electrodes.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Heterogeneous core/shell fluoride nanocrystals with enhanced upconversion photoluminescence for in vivo bioimaging

Shuwei Hao、Liming Yang、Hailong Qiu 等 6 位作者2015-01-01Nanoscale

We report on heterogeneous core/shell CaF2:Yb(3+)/Ho(3+)@NaGdF4 nanocrystals of 17 nm with efficient upconversion (UC) photoluminescence (PL) for in vivo bioimaging. Monodisperse core/shell nanostructures were synthesized using a seed-mediated growth process involving two quite different approaches of liquid-solid-sol…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Architectured design of superparamagnetic Fe 3 O 4 nanoparticles for application as MRI contrast agents: mastering size and magnetism for enhanced relaxivity

Clara Pereira、André M. Pereira、Mariana Rocha 等 5 位作者2015-01-01Journal of Materials Chemistry B

enhancement cannot only be achieved by an increase of particle/cluster size, but also through the precise control of the surface magnetic properties while constraining the nanomaterial dimensions. These achievements open up new perspectives on the mastered design of magnetic nanoprobes, overcoming the limitations rela…

Nanoparticle-Based Drug DeliveryLanthanide and Transition Metal ComplexesIron oxide chemistry and applications

Quantifying the formation of chiral luminescent lanthanide assemblies in an aqueous medium through chiroptical spectroscopy and generation of luminescent hydrogels

Samuel J. Bradberry、Aramballi J. Savyasachi、Robert D. Peacock 等 4 位作者2015-01-01Faraday Discussions

Herein we present the synthesis and the photophysical evaluation of water-soluble chiral ligands (2·(R,R) and 2·(S,S)) and their application in the formation of lanthanide directed self-assembled structures. These pyridine-2,6-dicarboxylic amide based ligands, possessing two naphthalene moieties as sensitising antenna…

Molecular Sensors and Ion DetectionMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Folate-conjugated nanodiamond for tumor-targeted drug delivery

Yu Dong、Ruixia Cao、Yingqi Li 等 6 位作者2015-01-01RSC Advances

Relying on the role of folate and folate receptors, NPFD nanoparticles tend to selectively discriminate tumor cells from normal cells and enter the cells by clathrin-dependent and receptor-mediated endocytosis.

Nanoparticle-Based Drug DeliveryDiamond and Carbon-based Materials ResearchPeptidase Inhibition and Analysis

One-pot tandem reactions for the preparation of esterified cellulose nanocrystals with 4-dimethylaminopyridine as a catalyst

Qilin Lu、Xian-yan Li、Lirong Tang 等 5 位作者2015-01-01RSC Advances

Esterified cellulose nanocrystals were manufactured via one-pot tandem reactions with DMAP as a catalyst. During the process cellulose nanocrystallization and acetylation occurred simultaneously.

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Fabrication of cationized gelatin nanofibers by electrospinning for tissue regeneration

K. Jalaja、Deboki Naskar、Subhas C. Kundu 等 4 位作者2015-01-01RSC Advances

A green fabrication approach has been developed to produce biocompatible and non-cytotoxic cationically modified gelatin nanofibers with enhanced biological performance.

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine