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Polyoxometalate-based organic–inorganic hybrid compounds containing transition metal mixed-organic-ligand complexes of N-containing and pyridinecarboxylate ligands

De‐Chuan Zhao、Yang‐Yang Hu、Hong Ding 等 8 位作者2015-01-01Dalton Transactions

Five new organic–inorganic hybrid compounds based on the Keggin-type polyoxoanion [SiW12O40]4−, namely [Cu3(2,2′-bpy)3(inic)(μ2-OH)(H2O)][SiW12O40]·2H2O (1), [Cu6(phen)6(μ3-Cl)2(μ2-Cl)2Cl2(inic)2][SiW12O40]·6H2O (2), [Cu2(hnic)(2,2′-bpy)2Cl]2[H2SiW12O40] (3), [Cu2(nic)(phen)2Cl2]2[SiW12O40] (4) and [Cu2(pic)(2,2′-bpy)…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Simultaneous broadband near-infrared emission and magnetic properties of single phase Ni 2+ -doped β-Ga 2 O 3 nanocrystals via mediated phase-controlled synthesis

Suiying Ye、Yuanhao Zhang、Huilin He 等 5 位作者2015-01-01Journal of Materials Chemistry C

Broadband near-infrared emission and ferromagnetic properties were detected in single phase Ni 2+ -doped β-Ga 2 O 3 nanocrystals, which is meaningful for its application in high-accuracy communications, bio-labels, etc.

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Aqueous self-assembly of a charged BODIPY amphiphile via nucleation–growth mechanism

L. Yang、Gang Fan、Xiang‐Kui Ren 等 6 位作者2015-01-01Physical Chemistry Chemical Physics

A new amphiphilic boron-dipyrromethene (BODIPY) dye 1 with a hydrophobic wedge at the meso-position and two hydrophilic cationic moieties at boron was synthesized. Temperature- and concentration-dependent UV/Vis spectroscopic studies in water were conducted to explore the self-assembly process of the dye. Detailed ana…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Gold nanoparticle–ultrananocrystalline diamond hybrid structured materials for high-performance optoelectronic device applications

Kamatchi Jothiramalingam Sankaran、Srinivasu Kunuku、B. Sundaravel 等 8 位作者2015-01-01Nanoscale

Hybridization of gold nanoparticles in the ultrananocrystalline diamond materials improves the electrical conductivity of the materials to a high level of 230 (Ω cm)(-1) with a sheet carrier concentration of 8.9 × 10(20) cm(-2). These hybrid materials show enhanced electron field emission (EFE) properties, viz. a low…

Catalytic Processes in Materials ScienceDiamond and Carbon-based Materials ResearchLaser-Ablation Synthesis of Nanoparticles

Far-red/near-infrared fluorescent conjugated polymer nanoparticles with size-dependent chirality and cell imaging applications

Chunhui Dai、Dongliang Yang、Wenjie Zhang 等 6 位作者2015-01-01Polymer Chemistry

We prepared a series of novel chiral far-red/near-infrared fluorescent CPNs with different nanoparticle sizes, which show size-dependent chirality and are successfully employed for cell imaging.

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Nanodiamonds from coal under ambient conditions

Jun Xiao、P. Liu、Guokun Yang2015-01-01Nanoscale

Coal is the most abundant energy resource, but it is only useful for producing energy via combustion due to its structural characteristics. However, coal is also inexpensive and is the most plentiful and readily available carbon source material for the production of nanodiamonds compared with the most widely used soli…

Diamond and Carbon-based Materials ResearchLaser-induced spectroscopy and plasmaLaser-Ablation Synthesis of Nanoparticles

Deep-cryogenic-treatment-induced phase transformation in the Al-Zn-Mg-Cu alloy

Chunmei Li、Nanpu Cheng、Zhiqian Chen 等 5 位作者2015-01-01International Journal of Minerals Metallurgy and Materials

Abstract An aluminum alloy (Al-Zn-Mg-Cu) subjected to deep cryogenic treatment (DCT) was systematically investigated. The results show that a DCT-induced phase transformation varies the microstructures and affects the mechanical properties of the Al alloy. Both Guinier-Preston (GP) zones and a metastable η′ phase were…

Aluminum Alloy Microstructure PropertiesAluminum Alloys Composites PropertiesMetal Alloys Wear and Properties

Commercial potato protein concentrate as a novel source for thermoformed bio-based plastic films with unusual polymerisation and tensile properties

William R. Newson、Faiza Rasheed、Ramune Kuktaite 等 7 位作者2015-01-01RSC Advances

Films thermoformed from commercial potato protein concentrate exhibited a constant Young's modulus and increasing strain at break with increasing processing temperature, in contrast to the usually observed behaviour for protein-based materials.

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesAdditive Manufacturing and 3D Printing Technologies

Effect of CaZrO 3 on phase structure and electrical properties of KNN-based lead-free ceramics

Yang Zhang、Lingyu Li、Wangfeng Bai 等 6 位作者2015-01-01RSC Advances

(1 − x )[0.93(K 0.5 Na 0.5 )NbO 3 –0.07LiNbO 3 ]– x CaZrO 3 (KNN–LN– x CZ) lead-free piezoelectric ceramics have been prepared by the conventional solid state reaction method and investigated to differentiate the effects of polymorphic phase transition.

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

A facile approach to fabricate halloysite/metal nanocomposites with preformed and in situ synthesized metal nanoparticles: a comparative study of their enhanced catalytic activity

Sankar Das、Subhra Jana2015-01-01Dalton Transactions

A widespread study has been carried out by the researcher during the last few decades to improve the properties and performance of halloysite-based inorganic-organic hybrid nanocomposites (NCs) because of their excellent structural features and characteristic properties. Here, we report the fabrication of halloysite/m…

Clay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

High solid-state luminescence in propeller-shaped AIE-active pyridine–ketoiminate–boron complexes

Yanping Wu、Zhenyu Li、Qingsong Liu 等 8 位作者2015-01-01Organic & Biomolecular Chemistry

Two pyridine-ketoiminate-based organoboron complexes (2 and 3) were developed. 2 and 3 showed very weak emission in low-viscosity organic solvents because of the intramolecular rotation induced non-radiative process. Their emission can be dramatically enhanced by the increase in solvent viscosity or by molecular aggre…

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistry

Bio-functionalized dense-silica nanoparticles for MR/NIRF imaging of CD146 in gastric cancer

Pu Wang、Yazhuo Qu、Chuan Li 等 9 位作者2015-01-01International Journal of Nanomedicine

PURPOSE: Nano dense-silica (dSiO2) has many advantages such as adjustable core-shell structure, multiple drug delivery, and controllable release behavior. Improving the gastric tumor-specific targeting efficiency based on the development of various strategies is crucial for anti-cancer drug delivery systems. METHODS:…

Nanoparticle-Based Drug DeliveryCancer Cells and MetastasisNanoplatforms for cancer theranostics

Supercharged green fluorescent proteins as bimodal reporter genes for CEST MRI and optical imaging

Amnon Bar‐Shir、Yajie Liang、Kannie W. Y. Chan 等 5 位作者2015-01-01Chemical Communications

Superpositively charged mutants of green fluorescent protein (GFP) demonstrated a dramatically improved chemical exchange saturation transfer (CEST) MRI contrast compared to their wild type counterparts. The mutants +36 GFP and +48 GFP were successfully expressed in mammalian cells and retained part of their fluoresce…

Advanced Fluorescence Microscopy TechniquesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Electrochemical Dealloying of Bimetallic ORR Nanoparticle Catalysts at Constant Electrode Potentials

Stefan Rudi、Lin Gan、Chunhua Cui 等 5 位作者2015-01-01Journal of The Electrochemical Society

Dealloyed, that is, selectively leached Pt-based oxygen reduction reaction (ORR) nanoparticle catalysts have demonstrated previously unachieved initial reactivity and performance durability in single cell of PEM fuel cells. Dealloying is typically achieved using free corrosion in acid or electrochemical cycling. Here,…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationNanoporous metals and alloys