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On the development of a facile approach based on the use of ionic liquids: preparation of PLLA (sc-PLA)/high surface area nano-graphite systems

Lorenza Gardella、Davide Furfaro、Maurizio Galimberti 等 4 位作者2015-01-01Green Chemistry

A method to prepare composite systems based on polylactide and high surface area nano-graphite has been developed, consisting of the application of ionic liquids as dispersing/exfoliating agents for nanofillers.

biodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing TechnologiesCarbon dioxide utilization in catalysis

A “turn-on” silver nanocluster based fluorescent sensor for folate receptor detection and cancer cell imaging under visual analysis

Hong Jiang、Gang Xu、Yimin Sun 等 8 位作者2015-01-01Chemical Communications

A novel terminal protection based label-free and "turn-on" fluorescent sensor for detection of folate receptors (FRs) and HeLa cells is developed by fluorescence resonance energy transfer (FRET) between single-walled carbon nanotubes (SWCNTs) and silver nanoclusters (AgNCs). Multilevel visual analysis (m(2)VA) was fir…

Advanced biosensing and bioanalysis techniquesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

A new approach in the synthesis of La 1−x Gd x FeO 3 perovskite nanoparticles – structural and magnetic characterization

Rafał J. Wiglusz、Karolina Kordek-Khalil、M. Małecka 等 8 位作者2015-01-01Dalton Transactions

A series of highly crystalline orthoferrite nanoparticles (type La(1-x)Gd(x)FeO3, where x = 0 to 1) were prepared using the self-combustion method. Extensive studies including X-ray diffraction, Rietveld refinement and Fourier transform infrared spectroscopy as well as Raman spectroscopy confirmed the orthorhombic spa…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Tuning the Schottky barrier height of the Pd–MoS 2 contact by different strains

Biao Liu、Lijuan Wu、Yu‐Qing Zhao 等 5 位作者2015-01-01Physical Chemistry Chemical Physics

The structures and electronic properties of the Pd-MoS2 contact are investigated using density functional calculations under different strains. The height of Schottky barrier for the Pd-MoS2 contact can be tuned by different strains. Our results show that the contact nature is of n-type Schottky barrier and the barrie…

2D Materials and ApplicationsMXene and MAX Phase MaterialsFerroelectric and Negative Capacitance Devices

Near-infrared down-conversion and energy transfer mechanism in Yb 3+ -doped Ba 2 LaV 3 O 11 phosphors

Jin Zhao、Chongfeng Guo、Ting Li 等 5 位作者2015-01-01Physical Chemistry Chemical Physics

Yb(3+)-doped Ba2LaV3O11 vanadate phosphors with near-infrared (NIR) emission are synthesized via the sol-gel method. The phase purity and structure of samples are characterized by X-ray diffraction (XRD). The electronic structure of the self-activated phosphor host Ba2LaV3O11 is estimated by density functional theory…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsTransition Metal Oxide Nanomaterials

Synthesis, characterization, and photocatalytic activity of Au–ZnO nanopyramids

Oshadha Ranasingha、Congjun Wang、Paul R. Ohodnicki 等 6 位作者2015-01-01Journal of Materials Chemistry A

ZnO nanopyramids have been grown on top of Au nanoparticle seeds creating a unique heterostructured system for photocatalytic applications.

ZnO doping and propertiesCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

A novel self-assembled targeted nanoparticle platform based on carboxymethylcellulose co-delivery of anticancer drugs

Lin Dai、Kefeng Liu、Chuanling Si 等 6 位作者2015-01-01Journal of Materials Chemistry B

Single-drug therapy for cancer is greatly hampered by its non-specific delivery to the target tissue, limited efficacies, poor tolerability, and resistance profiles. In order to overcome these limitations, we developed a new targeted nanoparticle platform for co-delivery of two different anticancer drugs. A conjugate…

Nanoparticle-Based Drug DeliveryAdvanced Drug Delivery SystemsGraphene and Nanomaterials Applications

Ab initio strain engineering of graphene: opening bandgaps up to 1 eV

Nicolas Kerszberg、Phanish Suryanarayana2015-01-01RSC Advances

We employ electronic structure calculations based on Density Functional Theory (DFT) to strain engineer graphene's bandgap.

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Critical assessment of the nature and properties of Fe( ii ) triazole-based spin-crossover nanoparticles

Carlos Bartual‐Murgui、Eva Natividad、Olivier Roubeau2015-01-01Journal of Materials Chemistry C

Nanoparticles of the compound [Fe(Htrz) 2 trz]BF 4 are shown to have a rod shape. Their size is found to control the width of the thermal hysteresis displayed in the spin crossover of this material, while the removal of surfactant results systematically in a reduction of the hysteresis width, by up to 16 K, both effec…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Illustrating the formation of metal nanoparticles with a growth concept based on colloidal stability

Maria Wuithschick、Steffen Witte、Frieder Kettemann 等 5 位作者2015-01-01Physical Chemistry Chemical Physics

A large number of scientific contributions is dedicated to syntheses, characterization and applications of metal nanoparticles. In contrast, only few studies on their formation mechanisms have been reported. In general, concepts to describe particle growth processes are rare. Commonly used models are not able to expla…

Gold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactionsLaser-Ablation Synthesis of Nanoparticles

Dye-sensitized polyoxometalate for visible-light-driven photoelectrochemical cells

Junkuo Gao、Jianwei Miao、Yongxin Li 等 8 位作者2015-01-01Dalton Transactions

A simple and facile one-step method for the synthesis of an organic dye-functionalized polyoxometalate (POM) hybrid with visible-light photo-response was reported. The POM hybrid was fully characterized via single crystal XRD, powder XRD, FTIR and elemental analysis. The reaction of the organic dye with inorganic salt…

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsAdvanced Nanomaterials in Catalysis

Accelerating the healing of superhydrophobicity through photothermogenesis

Yanhua Liu、Xiaowei Pei、Zhilu Liu 等 6 位作者2015-01-01Journal of Materials Chemistry A

Self-healing superhydrophobic fabric was fabricated by a mussel-inspired method using PDA@ODA–Fe 3 O 4 nanocapsules. Fast healing of superhydrophobicity can be realized in 40 s under NIR irradiation due to photothermal effect of Fe 3 O 4 nanoparticles.

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsSolar-Powered Water Purification Methods

Directed Interactions of Block Copolypept(o)ides with Mannose‐binding Receptors: PeptoMicelles Targeted to Cells of the Innate Immune System

Philipp Heller、Nicole Mohr、Alexander Birke 等 7 位作者2015-01-01Macromolecular Bioscience

Core-shell structures based on polypept(o)ides combine stealth-like properties of the corona material polysarcosine with adjustable functionalities of the polypeptidic core. Mannose-bearing block copolypept(o)ides (PSar-block-PGlu(OBn)) have been synthesized using 11-amino-3,6,9-trioxa-undecyl-2,3,4,6-tetra-O-acetyl-O…

Advanced biosensing and bioanalysis techniquesPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Control of the photoluminescence properties of single-walled carbon nanotubes by alkylation and subsequent thermal treatment

Yutaka Maeda、Yuya Takehana、Michio Yamada 等 5 位作者2015-01-01Chemical Communications

Dibutylated single-walled carbon nanotubes (Bu-SWNTs-Bu) with varying degrees of functionalization were prepared by two-step reductive alkylation and subsequent thermal treatment. A new photoluminescence peak at around 1240 nm was observed and increased drastically after the thermal treatment. The results indicate tha…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications