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The B 32 cluster has the most stable bowl structure with a remarkable heptagonal hole

Truong Ba Tai、Minh Tho Nguyen2015-01-01Chemical Communications

The neutral B32 exhibits an aromatic bowl structure containing one heptagonal hole, while two anionic species, one having a bowl structure and the other a quasi-planar structure, are almost degenerate in energy. These findings not only give more insight into the structural features of boron clusters, but also present…

Fullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials ResearchBoron Compounds in Chemistry

One-step hydrothermal synthesis of nano zinc carbonate and its use as a promising substitute for antimony trioxide in flame retardant flexible poly(vinyl chloride)

Ye‐Tang Pan、De‐Yi Wang2015-01-01RSC Advances

Nano-scale zinc carbonate synthesized by novel one-step hydrothermal method presented a promising to substitute antimony trioxide in flame retardant flexible poly(vinyl chloride).

Flame retardant materials and propertiesCarbon dioxide utilization in catalysisSilicone and Siloxane Chemistry

PLGA-PLL-PEG-Tf-based targeted nanoparticles drug delivery system enhance antitumor efficacy via intrinsic apoptosis pathway

Bao-An Chen、Wen Bao、Ran Liu 等 9 位作者2015-01-01International Journal of Nanomedicine

Chemotherapy offers a systemic cancer treatment; however, it is limited in clinical administration due to its serious side effects. In cancer medicine, the use of nanoparticles (NPs) drug delivery system (DDS) can sustainedly release anticancer drug at the specific site and reduce the incidence of toxicity in normal t…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Electronic structure and electrode properties of tetracyanoquinodimethane (TCNQ): a surface science investigation of lithium intercalation into TCNQ

Ruben Precht、René Hausbrand、Wolfram Jaegermann2015-01-01Physical Chemistry Chemical Physics

Organic materials are of interest as ion battery cathode materials because they offer advantages over inorganic cathodes such as abundant resources and a low ecological footprint. However, they suffer from slow kinetics and a comparatively low potential. In this paper, we have investigated alkali induced changes in th…

Advanced Memory and Neural ComputingOrganic and Molecular Conductors ResearchElectronic and Structural Properties of Oxides

Highly efficient, coking-resistant SOFCs for energy conversion using biogas fuels

Jianjun Ma、Cairong Jiang、Paul A. Connor 等 5 位作者2015-01-01Journal of Materials Chemistry A

A well-designed cell structure and selected components makes it possible to obtain excellent performance combined good durability using biogas fuel.

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

High carrier mobility of few-layer PbX (X = S, Se, Te)

Xibo Li、Pan Guo、Yanning Zhang 等 6 位作者2015-01-01Journal of Materials Chemistry C

Two-dimensional materials with a higher carrier mobility are promising materials for applications in nanoelectronics and photocatalysis.

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and Devices

Redox-sensitive hyaluronic acid–paclitaxel conjugate micelles with high physical drug loading for efficient tumor therapy

Tingjie Yin、Jing Wang、Lifang Yin 等 6 位作者2015-01-01Polymer Chemistry

Characterization of targeted redox-sensitive micelles self-assembled from polymer–drug conjugates exhibiting conspicuous drug loading capabilities, selective cellular uptake, rapid intracellular disassembly and drug release is presented.

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsDendrimers and Hyperbranched Polymers

Remarkable oxygen barrier films based on a layered double hydroxide/chitosan hierarchical structure

Ting Pan、Simin Xu、Yibo Dou 等 8 位作者2015-01-01Journal of Materials Chemistry A

Organic–inorganic hybrid films are fabricated via an alternate assembly of a chitosan (CTS) polymer and hierarchical layered double hydroxide (H-LDH), which exhibit tremendous oxygen barrier properties with high stability as well as long-term maintenance.

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Selective and sensitive SERS sensor for detection of Hg 2+ in environmental water base on rhodamine-bonded and amino group functionalized SiO 2 -coated Au–Ag core–shell nanorods

Pinyi Ma、Fanghui Liang、Quanping Diao 等 8 位作者2015-01-01RSC Advances

A novel SERS sensor for trace detection of Hg 2+ using R6G-derive Schiff base bonded Au@Ag@SiO 2 –NH 2 NRs was designed. The LOD is 0.33 pmol L −1 .

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Sensors and Ion DetectionNanocluster Synthesis and Applications

A new heterogeneous photocatalyst based on Wells–Dawson polyoxometalate and nickel coordination compounds: synthesis, structure and property

Lei Zhang、Bingqian Shan、Hongxun Yang 等 7 位作者2015-01-01RSC Advances

A new heterogeneous photocatalyst based on Wells–Dawson polyoxotungstates and nickel coordination compounds exhibits two broad band centered at 513 nm and 770 nm, extending induced light to visible region.

Advanced Photocatalysis TechniquesPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

One-pot synthesis and biological imaging application of an amphiphilic fluorescent copolymer via a combination of RAFT polymerization and Schiff base reaction

Zengfang Huang、Xiqi Zhang、Xiaoyong Zhang 等 9 位作者2015-01-01Polymer Chemistry

A novel one-pot strategy for the fabrication of AIE-based FONs was developed via a combination of RAFT polymerization and Schiff base reaction for the first time.

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Preparation of imidazolium-type ionic liquids containing silsesquioxane frameworks and their thermal and ion-conductive properties

Takuhiro Ishii、Toshiaki Enoki、Tomonobu Mizumo 等 5 位作者2015-01-01RSC Advances

Imidazolium-type ionic liquids containing a random-structured (Im-Random-SQ-IL) and a cage-like (Im-Cage-SQ-IL) oligosilsesquioxanes were successfully prepared by hydrolytic condensation of MTICl in TFSI solutions in water and water/methanol solution, respectively.

Ionic liquids properties and applicationsPolyoxometalates: Synthesis and ApplicationsSilicone and Siloxane Chemistry

Surface-growth-mode-induced strain effects on the metal–insulator transition in epitaxial vanadium dioxide thin films

Mengmeng Yang、Yuanjun Yang、Bin Hong 等 10 位作者2015-01-01RSC Advances

The surface growth mode can induce the anomalous compressive strain in thicker VO 2 /Al 2 O 3 epitaxial films, which can't be explained by conventional epitaxial lattice-mismatch. Strain may be an effective tool for manipulating MIT of the VO 2 films.

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Fabrication of three dimensional (3D) hierarchical Ag/WO 3 flower-like catalyst materials for the selective oxidation of m-xylene to isophthalic acid

Shankha S. Acharyya、Shilpi Ghosh、Rajaram Bal2015-01-01Chemical Communications

A three dimensional (3D) hierarchical silver supported tungsten oxide flower-like microsphere catalyst has been fabricated using a cationic surfactant CTAB. It was found that the crystal-splitting mechanism plays a key role in the formation of this flower-like structure. This catalyst was proved to be highly effective…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCopper-based nanomaterials and applications

Ligand-Appended BBB-Targeted Nanocarriers (LABTNs)

Ankit Jain、Sanjay Jain2015-01-01Critical Reviews in Therapeutic Drug Carrier Systems

Delivering therapeutics across the blood brain barrier (BBB) remains the rate-limiting step in brain medicine research. Three main categories of endogenous transportation at BBB that can be used for targeting brain are carrier-mediated transport, active efflux transport, and receptor-mediated transport. Various approa…

Nanoparticle-Based Drug DeliveryAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Apparent pH sensitivity of solution-gated graphene transistors

Moo Hyung Lee、Beom Joon Kim、Keun Hyung Lee 等 7 位作者2015-01-01Nanoscale

Solution-gated graphene transistors were developed recently for use in pH sensor applications. The device operation is understood to rely on the capability of hydronium and hydroxide ions in solution to change the electrical properties of graphene. However, hydronium and hydroxide ions are accompanied by other ionic s…

Graphene research and applicationsElectrochemical sensors and biosensorsAnalytical Chemistry and Sensors

Morphology effects in photoactive ZnO nanostructures: photooxidative activity of polar surfaces

Ana Iglesias‐Juez、Francesc Viñes、Oriol Lamiel-García 等 5 位作者2015-01-01Journal of Materials Chemistry A

Microscopy and spectroscopy experiments combined with density functional calculations on ZnO nanostructures with variable morphology reveal the relationship between surface-related physicochemical properties and the nanostructure photochemical response.

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films