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Ultralight anisotropic foams from layered aligned carbon nanotube sheets

Shaghayegh Faraji、Kelly L. Stano、Özkan Yıldız 等 6 位作者2015-01-01Nanoscale

In this work, we present large scale, ultralight aligned carbon nanotube (CNT) structures which have densities an order of magnitude lower than CNT arrays, have tunable properties and exhibit resiliency after compression. By stacking aligned sheets of carbon nanotubes and then infiltrating with a pyrolytic carbon (PyC…

Carbon Nanotubes in CompositesSupercapacitor Materials and FabricationFiber-reinforced polymer composites

Homogenously hexagonal prismatic AgBiS 2 nanocrystals: controlled synthesis and application in quantum dot-sensitized solar cells

Na Liang、Wenlong Chen、Fang Dai 等 12 位作者2015-01-01CrystEngComm

Homogenously hexagonal prismatic AgBiS2 nanocrystals with sizes of about 7.6 nm have been synthesized by the selective absorption of oleylamine and anisotropic growth in a mixed solvent system. Quantum dot-sensitized solar cells with the as-prepared AgBiS2 nanocrystals as counterelectrode materials showed a conversion…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Morphological tuning via structural modulations in AIE luminogens with the minimum number of possible variables and their use in live cell imaging

Roop Shikha Singh、Rakesh Kumar Gupta、Rajendra Prasad Paitandi 等 7 位作者2015-01-01Chemical Communications

With intent to fine tune the morphological and photophysical properties, three novel AIE luminogens (BQ1-BQ3) based on quinoline-BODIPY have been synthesized. A judicious choice of substituents (-H, -CH3, -OCH3) in these systems led to nanoballs in BQ1 and BQ2, while in BQ3 it led to reticulated nanofibers with divers…

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Oral delivery of a platinum anticancer drug using lipid assisted polymeric nanoparticles

Qinqin Cheng、Hongdong Shi、Hai Huang 等 6 位作者2015-01-01Chemical Communications

Self-assembled cholesterol-asplatin-incorporated nanoparticles (SCANs) were prepared for oral delivery of a Pt(IV) prodrug. SCANs exhibit high gastrointestinal stability, sustained drug release and enhanced cell uptake. The oral bioavailability of SCANs was 4.32-fold higher than that of free Pt(IV) prodrugs. The oral…

Nanoparticle-Based Drug DeliveryMetal complexes synthesis and propertiesRNA Interference and Gene Delivery

In situ production of silver nanoparticles on an aldehyde-equipped conjugated porous polymer and subsequent heterogeneous reduction of aromatic nitro groups at room temperature

Jie Liu、Jieshun Cui、Filipe Vilela 等 7 位作者2015-01-01Chemical Communications

In a metal-free procedure, chelating thiol groups and an electrophile react to assemble a robust, conjugated porous polymer with pendant aldehyde functionalities. These groups are able to reduce Ag(i) ions to generate, in situ, Ag(0) nanoparticles evenly dispersed in the polymer matrix. The Ag(0)-polymer composite ena…

Advanced Photocatalysis TechniquesCovalent Organic Framework ApplicationsNanomaterials for catalytic reactions

Influence of addition of vapor grown carbon fibers on mechanical, thermal and biodegradation properties of lignin nanoparticle filled bio-poly(trimethylene terephthalate) hybrid nanocomposites

Arun Gupta、Smita Mohanty、S. K. Nayak2015-01-01RSC Advances

Bio-poly(trimethylene terephthalate) (bio-PTT) hybrid nanocomposites constituting 1.5 wt% of lignin nanoparticles (LNP) and variable wt% of vapor-grown carbon fibers (VGCF) were prepared using melt extrusion followed by a microinjection molding technique.

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesLignin and Wood Chemistry

Metal assisted anodic etching of silicon

Chang Quan Lai、Wen Zheng、W. K. Choi 等 4 位作者2015-01-01Nanoscale

Metal assisted anodic etching (MAAE) of Si in HF, without H2O2, is demonstrated. Si wafers were coated with Au films, and the Au films were patterned with an array of holes. A Pt mesh was used as the cathode while the anodic contact was made through either the patterned Au film or the back side of the Si wafer. Experi…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

A highly sensitive fluorescent sensor based on small molecules doped in electrospun nanofibers: detection of explosives as well as color modulation

Wei Xue、Yang Zhang、Juanjuan Duan 等 10 位作者2015-01-01Journal of Materials Chemistry C

A new type of highly sensitive low-cost sensor towards nitro-compounds based on PEO/MePyCz composite nanofibers is reported. The composite nanomaterials may also be applied in nano-optoelectronics devices, light-emitting diodes or biological sensors.

Organic Electronics and PhotovoltaicsConducting polymers and applicationsLuminescence and Fluorescent Materials

Influence of external magnetic field and magnetic-site dilution on the magnetic dynamics of a one-dimensional Tb( iii )–radical complex

Lei-Lei Li、Shuang Liu、Li Han 等 5 位作者2015-01-01Chemical Communications

A new Tb(III)-radical chain complex was synthesized and characterized, which exhibited two separate relaxation processes. The influence of external magnetic field and magnetic-site dilution on the magnetic dynamics of a one-dimensional Tb(III)-radical complex was studied.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Direct formation of large-scale multi-layered germanene on Si substrate

Hsu‐Sheng Tsai、Yuze Chen、Henry Medina 等 8 位作者2015-01-01Physical Chemistry Chemical Physics

Germanene layers with lonsdaleite structure has been synthesized from a SiGe thin film for the first time using a N2 plasma-assisted process in this investigation. Multi-layered germanene can be directly observed, and the derived lattice parameters are nearly consistent with the theoretical results. Furthermore, large…

Graphene research and applications2D Materials and ApplicationsTopological Materials and Phenomena

Enhanced thermoelectric power factor of Re-substituted higher manganese silicides with small islands of MnSi secondary phase

Xi Chen、Jianshi Zhou、John B. Goodenough 等 4 位作者2015-01-01Journal of Materials Chemistry C

A rhenium-substituted HMS sample with small islands of MnSi secondary phase has been prepared by the quenching method. Such unique microstructure leads to an enhanced thermoelectric power factor (PF) as compared to the samples prepared by other methods.

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsSemiconductor materials and interfaces

Simple synthesis of Prussian blue analogues in room temperature ionic liquid solution and their catalytic application in epoxidation of styrene

Qianqian Wang、Ning Wang、Sifa He 等 6 位作者2015-01-01Dalton Transactions

In this article, a new application of the room temperature ionic liquid, tetramethylammonium tetrafluoroborate, is described. This ionic liquid is used as a stabilizing agent and the reaction medium for the synthesis of CoFe Prussian blue analogue nanoparticles using N,N-dimethyl formamide as a complexing agent. The a…

Ionic liquids properties and applicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions