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Fast, high-yield synthesis of amphiphilic Ag nanoclusters and the sensing of Hg 2+ in environmental samples

Nan Xia、Jie Yang、Zhikun Wu2015-01-01Nanoscale

We report the high-yield (74%) synthesis of Ag30(Capt)18 (abbreviated as Ag30) in a very time-saving fashion (half an hour). The cluster composition was determined by high-resolution mass spectrometry combined with TG analysis, and the structure was probed by 1D and 2D NMR. Interestingly, the nanoclusters can dissolve…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Self-assembled sorbitol-derived supramolecular hydrogels for the controlled encapsulation and release of active pharmaceutical ingredients

Edward J. Howe、Babatunde O. Okesola、David K. Smith2015-01-01Chemical Communications

A simple supramolecular hydrogel based on 1,3:2,4-di(4-acylhydrazide)benzylidene sorbitol (DBS-CONHNH2), is able to extract acid-functionalised anti-inflammatory drugs via directed interactions with the self-assembled gel nanofibres. Two-component hydrogel-drug hybrid materials can be easily formed by mixing and exhib…

Hydrogels: synthesis, properties, applicationsGlycosylation and Glycoproteins ResearchSupramolecular Self-Assembly in Materials

Pickering high internal phase emulsion-based hydroxyapatite–poly(ε-caprolactone) nanocomposite scaffolds

Yang Hu、Huichang Gao、Zhengshan Du 等 6 位作者2015-01-01Journal of Materials Chemistry B

Biocompatible, biodegradable and bioactive nanocomposite (NC) scaffolds with well-defined interconnected porous structures have attracted increasing attention in bone tissue engineering. In this work, we develop a facile method to fabricate poly(l-lactic acid)-modified hydroxyapatite (g-HAp)-poly(ε-caprolactone) (PCL)…

Proteins in Food SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Template- and surfactant-free synthesis of ultrathin CeO 2 nanowires in a mixed solvent and their superior adsorption capability for water treatment

Xiaofang Yu、Jianwei Liu、Huai‐Ping Cong 等 9 位作者2015-01-01Chemical Science

nanowires can adsorb Congo red selectively from a mixed solution composed of several dyes. Successful access to high quality ultrathin nanowires will make it possible for their potential application in catalysis and other fields.

ZnO doping and propertiesCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Investigation of Chitosan-PVA Composite Films and Their Adsorption Properties

Lewis S. Casey、Lee D. Wilson2015-01-01Journal of Geoscience and Environment Protection

Viscous aqueous solutions of chitosan and polyvinyl alcohol (PVA) were blended to enhance miscibility and avoid polymer phase separation. The mixtures were drop-casted and air dried to yield composite film materials that were characterized by equilibrium water uptake, physical stability in aqueous solution, and therma…

Nanocomposite Films for Food PackagingConducting polymers and applicationsPolymer Surface Interaction Studies

Solvent-free heteropolyacid-catalyzed glycerol ketalization at room temperature

Márcio José da Silva、Armanda Aparecida Júlio、F. C. S. Dorigetto2015-01-01RSC Advances

In this work, we assessed the activity of H 3 PW 12 O 40 heteropolyacid on glycerol ketalization with different ketones at room temperature and in the absence of an auxiliary solvent.

Catalysis for Biomass ConversionPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Coumarin–BODIPY hybrids by heteroatom linkage: versatile, tunable and photostable dye lasers for UV irradiation

Ixone Esnal、Gonzalo Durán‐Sampedro、Antonia R. Agarrabeitia 等 10 位作者2015-01-01Physical Chemistry Chemical Physics

Linking amino and hydroxycoumarins to BODIPYs through the amino or hydroxyl group lets the easy construction of unprecedented photostable coumarin-BODIPY hybrids with broadened and enhanced absorption in the UV spectral region, and outstanding wavelength-tunable laser action within the green-to-red spectral region (∼5…

Nanoplatforms for cancer theranosticsPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Graphene oxide as a corrosion-inhibitive coating on magnesium alloys

Zhaozhong Qiu、Rui Wang、Jinzhu Wu 等 6 位作者2015-01-01RSC Advances

A graphene oxide film was formed on the PEO coatings of magnesium alloys via an electrostatic self-assembly method, which functioned as a physical separation with inhibiting effects between the protected metal and reactants.

Supercapacitor Materials and FabricationCorrosion Behavior and InhibitionMagnesium Alloys: Properties and Applications

Antibacterial properties of Ag–TiO 2 composite sol–gel coatings

Emőke Albert、Pierre‐Antoine Albouy、A. Ayral 等 12 位作者2015-01-01RSC Advances

This study reveals the connection between the silver-doping method, the resulting nature and amount of the silver dopant together with the structural properties and the long-term antibacterial activity of composite coatings.

TiO2 Photocatalysis and Solar CellsNanoparticles: synthesis and applicationsAdvanced Nanomaterials in Catalysis

Green and economical synthesis of nitrogen-doped carbon dots from vegetables for sensing and imaging applications

Xiaoqing Niu、Guosheng Liu、Luyao Li 等 6 位作者2015-01-01RSC Advances

A green, simple and low-cost approach was present to obtain N-doped C-dots using vegetables as the sole carbon source through facile one-pot hydrothermal treatment. The C-dots can serve as a suitable sensing platform for detection of Cu 2+ .

Advanced biosensing and bioanalysis techniquesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Size-controlled synthesis of water-dispersible superparamagnetic Fe 3 O 4 nanoclusters and their magnetic responsiveness

Wentao Wang、Bingtao Tang、Benzhi Ju 等 4 位作者2015-01-01RSC Advances

Highly water-dispersible and size-controllable superparamagnetic Fe 3 O 4 nanoclusters were synthesized by using sodium citrate with a mixed-solvent system, these nanoclusters can be used for color display and hyperthermia in biomedical applications.

Nanoparticle-Based Drug DeliveryMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Enzymatic synthesis and post-functionalization of two-dimensional crystalline cellulose oligomers with surface-reactive groups

Yusuke Yataka、Toshiki Sawada、Takeshi Serizawa2015-01-01Chemical Communications

Two-dimensional (2D) nanomaterials have gained considerable attention due to their unique structural and physicochemical properties. Herein, we synthesized 2D crystalline cellulose oligomers with surface-reactive azide groups through enzymatic reactions and covalently post-functionalized them with 1-ethynyl pyrene thr…

Advanced Cellulose Research StudiesSupramolecular Self-Assembly in MaterialsPickering emulsions and particle stabilization

Real-time, non-invasive monitoring of hydrogel degradation using LiYF 4 :Yb 3+ /Tm 3+ NIR-to-NIR upconverting nanoparticles

Ghulam Jalani、Rafik Naccache、Derek H. Rosenzweig 等 7 位作者2015-01-01Nanoscale

To design a biodegradable hydrogel as cell support, one should know its in vivo degradation rate. A technique commonly used to track gel degradation is fluorescence spectroscopy. However, the fluorescence from conventional fluorophores quickly decays, and the fluorophores are often moderately cytotoxic. Most important…

Luminescence Properties of Advanced MaterialsSpine and Intervertebral Disc PathologyOptical Imaging and Spectroscopy Techniques

Recent advances in gold nanoparticle-based bioengineering applications

Eun‐Young Kim、Dinesh Kumar、Gilson Khang 等 4 位作者2015-01-01Journal of Materials Chemistry B

Plasmonic nanoparticle based nanotechnology plays a pivotal role in the recent advances in biomedical applications. Along with biocompatibility and robust surface chemistry, the tunable optical properties of the visible and near-infrared regions of gold nanoparticles have attracted significant attention for a wide ran…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranosticsAdvanced Nanomaterials in Catalysis

Pd–Ag/SiO 2 bimetallic catalysts prepared by galvanic displacement for selective hydrogenation of acetylene in excess ethylene

Yunya Zhang、Weijian Diao、John R. Monnier 等 4 位作者2015-01-01Catalysis Science & Technology

A series of bimetallic Pd–Ag/SiO 2 catalysts with Ag enriched on the surface were prepared by galvanic displacement. The bimetallic effect for these catalysts on acetylene hydrogenation was discussed.

Catalytic Processes in Materials ScienceCatalysis for Biomass ConversionCatalysis and Oxidation Reactions

Fusion and planarization of bisBODIPY: a new family of photostable near infrared dyes

Changjiang Yu、Lijuan Jiao、Tingting Li 等 9 位作者2015-01-01Chemical Communications

We have synthesized a new family of directly-fused bisBODIPY BBP 1 through a key FeCl3-mediated intramolecular oxidative cyclodehydrogenation reaction and its derivatives 2 and 3 from the Knoevenagel reaction. These dyes display effective expansion of π-conjugation over the two BODIPYs due to their locked coplanar con…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials