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Shape-controllable and versatile synthesis of copper nanocrystals with amino acids as capping agents

Jincheng Yu、Fu‐Gang Zhao、Wei Shao 等 5 位作者2015-01-01Nanoscale

Thanks to their outstanding properties and a wide range of promising applications, the development of a versatile and convenient preparation method for metallic copper nanocrystals with controllable shape is of primary significance. Different from the literature that utilized a capping agent bearing only one kind of C…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Tunable synthesis of self-assembled cyclic peptide nanotubes and nanoparticles

Leming Sun、Zhen Fan、Yongzhong Wang 等 6 位作者2015-01-01Soft Matter

While tremendous efforts have been made in investigating scalable approaches for fabricating nanoparticles, less progress has been made in scalable synthesis of cyclic peptide nanoparticles and nanotubes, despite their great potential for broader biomedical applications. In this paper, tunable synthesis of self-assemb…

Advanced biosensing and bioanalysis techniquesSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Urea homogeneous nucleation mechanism is solvent dependent

Matteo Salvalaglio、Marco Mazzotti、Michele Parrinello2015-01-01Faraday Discussions

The composition of the mother phase plays a primary role in crystallization processes, affecting both crystal nucleation and growth. In this work, the influence of solvents on urea nucleation has been investigated by means of enhanced sampling molecular dynamics simulations. We find that, depending on the solvent, the…

Enzyme Structure and FunctionCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Fabrication of Mn 2 O 3 nanorods: an efficient catalyst for selective transformation of alcohols to aldehydes

Hasimur Rahaman、Radha M. Laha、Dilip K. Maiti 等 4 位作者2015-01-01RSC Advances

Self-assembled high surface area Mn 2 O 3 nanorods have been fabricated through an effective polymer–surfactant interaction and their outstanding catalytic property for the selective transformation of alcohols to aldehydes has been discovered.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisNanomaterials for catalytic reactions

Highly porous carbon microflakes derived from catkins for high-performance supercapacitors

Fangwei Ma、Jiafeng Wan、Guang Wu 等 4 位作者2015-01-01RSC Advances

Highly porous carbon microflakes (CMFs) with oxygen and nitrogen dual-doping were prepared from willow catkins by pyrolysis at 500 °C in nitrogen, followed by KOH activation and were used as a high-performance supercapacitor electrode material.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical Applications

Formic acid oxidation on platinum: a simple mechanistic study

Kathleen Schwarz、Ravishankar Sundararaman、Thomas P. Moffat 等 4 位作者2015-01-01Physical Chemistry Chemical Physics

The oxidation of small organic acids on noble metal surfaces under electrocatalytic conditions is important for the operation of fuel cells and is of scientific interest, but the basic reaction mechanisms continue to be a matter of debate. Formic acid oxidation on platinum is one of the simplest of these reactions, ye…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCO2 Reduction Techniques and Catalysts

Improving photocatalytic performance of ZnO via synergistic effects of Ag nanoparticles and graphene quantum dots

Jun Wang、Yan Li、Juan Ge 等 5 位作者2015-01-01Physical Chemistry Chemical Physics

Herein, we reported a simple and "green" method for preparing the ternary photocatalyst Ag-graphene quantum dots (GQDs)-ZnO. In this method, an aqueous solution of GQDs not only acted as a substituent for the organic solvent for preparing the ZnO precursor but was also used as a reducing agent for the in situ synthesi…

Advanced Photocatalysis TechniquesZnO doping and propertiesCarbon and Quantum Dots Applications

Time-dependent gel to gel transformation of a peptide based supramolecular gelator

Abhishek Baral、Shibaji Basak、Kingshuk Basu 等 6 位作者2015-01-01Soft Matter

A dipeptide with a long fatty acid chain at its N-terminus gives hydrogels in phosphate buffer in the pH range 7.0-8.5. The hydrogel with a gelator concentration of 0.45% (w/v) at pH 7.46 (physiological pH) provides a very good platform to study dynamic changes within a supramolecular framework as it exhibits remarkab…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Energy level modeling of lanthanide materials: review and uncertainty analysis

Jonas Joos、Dirk Poelman、Philippe F. Smet2015-01-01Physical Chemistry Chemical Physics

Energy level schemes are an essential tool for the description and interpretation of atomic spectra. During the last 40 years, several empirical methods and relationships were devised for constructing energy level schemes of lanthanide defects in wide band gap solids, culminating in the chemical shift model by Thiel a…

Luminescence Properties of Advanced MaterialsNuclear materials and radiation effectsElectronic and Structural Properties of Oxides

Au nanoflower–Ag nanoparticle assembled SERS-active substrates for sensitive MC-LR detection

Yuan Zhao、Xuan Yang、Hao Li 等 8 位作者2015-01-01Chemical Communications

Surface-enhanced Raman scattering (SERS)-active substrates assembled by two types of metallic nanoparticles (NPs) were fabricated. Aptamers driven Au nanoflower (Au NF)-Ag NP core-satellite assemblies exhibited amplified SERS signals and achieved the sensitive detection of microcystin-LR (MC-LR) in Tai lake water with…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Aqueous foams stabilized by chitin nanocrystals

Maria V. Tzoumaki、Dimitris Karefyllakis、Thomas Moschakis 等 5 位作者2015-01-01Soft Matter

The aim of the present study was to explore the potential use of chitin nanocrystals, as colloidal rod-like particles, to stabilize aqueous foams. Chitin nanocrystals (ChN) were prepared by acid hydrolysis of crude chitin and foams were generated mainly by sonicating the respective dispersions. The foamability of the…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

High speed, high temperature electrical characterization of phase change materials: metastable phases, crystallization dynamics, and resistance drift

Faruk Dirisağlık、Gökhan Bakan、Zoila Jurado 等 14 位作者2015-01-01Nanoscale

During the fast switching in Ge2Sb2Te5 phase change memory devices, both the amorphous and fcc crystalline phases remain metastable beyond the fcc and hexagonal transition temperatures respectively. In this work, the metastable electrical properties together with crystallization times and resistance drift behaviour of…

Chalcogenide Semiconductor Thin FilmsTransition Metal Oxide NanomaterialsPhase-change materials and chalcogenides

Graphene and carbon nanodots in mesoporous materials: an interactive platform for functional applications

Plinio Innocenzi、Luca Malfatti、Davide Carboni2015-01-01Nanoscale

The present review is focused on a specific class of nanocomposites obtained through integration of graphene or carbon-based nanomaterials (such as carbon nanodots) with mesoporous inorganic or hybrid materials, obtained via template assisted self-assembly. The task of integrating graphene and carbon nanodots with a s…

Graphene research and applicationsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

Optimization of the GAFF force field to describe liquid crystal molecules: the path to a dramatic improvement in transition temperature predictions

Nicola Jane Boyd、Mark R. Wilson2015-01-01Physical Chemistry Chemical Physics

The physical properties and phase transitions of thermotropic liquid crystals are highly sensitive to small changes in chemical structure. However, these changes are challenging to model, as both the phase diagram and mesophase properties obtained from fully atomistic simulations are strongly dependent on the force fi…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation